Long-Lived Trifluoromethanide Anion: A Key Intermediate in Nucleophilic Trifluoromethylations

Angewandte Chemie - International Edition

Volumn 53, Issue 43, 2014, Pages 11575-11578

  Prakash, G K Surya ^a   Wang, Fang ^a   Zhang, Zhe ^a   Haiges, Ralf ^a   Rahm, Martin ^a   Christe, Karl O ^a   Mathew, Thomas ^a   Olah, George A ^a  

^a UNIVERSITY OF SOUTHERN CALIFORNIA   (United States)

Author keywords

carbanions; fluorine; NMR spectroscopy; reaction mechanisms; reactive intermediates

Indexed keywords

CROWN ETHERS; FLUORINE; IONS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; QUANTUM THEORY; TEMPERATURE;

CARBANIONS; ELECTROPHILIC SUBSTRATE; NUCLEOPHILIC TRIFLUOROMETHYLATION; QUANTUM-MECHANICAL CALCULATION; REACTION CHEMISTRY; REACTION MECHANISM; REACTIVE INTERMEDIATE; VARIABLE-TEMPERATURE NMR;

REACTION INTERMEDIATES;

ANION; FLUORINE;

CHEMISTRY; METHYLATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

ANIONS; FLUORINE; MAGNETIC RESONANCE SPECTROSCOPY; METHYLATION;

EID: 84908077614     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201406505     Document Type: Article

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