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Volumn 133, Issue 51, 2011, Pages 20901-20913

Direct cupration of fluoroform

Author keywords

[No Author keywords available]

Indexed keywords

BOND FORMATION; CU COMPLEXES; ELECTROPHILES; FLUOROFORMS; HIGH SELECTIVITY; ORGANIC MOLECULES; PHENANTHROLINES; QUANTITATIVE YIELDS; ROOM TEMPERATURE; TRIFLUOROMETHYL GROUP;

EID: 84555188875     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja2081026     Document Type: Article
Times cited : (295)

References (87)
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    • note
    • 3 reductive elimination from Pd(IV) (17c-17e) were also recently reported. These transformations, however, are unrelated to the area of nucleophilic trifluoromethylation of aryl halides because they do not involve Pd(0) that is required for Ar-X bond activation.
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    • e-EROS Encyclopedia of Reagents for Organic Synthesis, 2001
    • Rozen, S.; Hagooly, A. e-EROS Encyclopedia of Reagents for Organic Synthesis, http://www3.interscience.wiley.com/cgi-bin/mrwhome/104554785/HOME, 2001.
    • Rozen, S.1    Hagooly, A.2
  • 50
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    • note
    • 6 displays one singlet resonance at 1.16 ppm. (25b)
  • 68
    • 84555166600 scopus 로고    scopus 로고
    • note
    • 7 solutions of CuX (X = Cl, Br, I) and t -BuOM (M = K, Na) (1:2) only one singlet from the t -BuO group was observed. Although exact structures of 1-3 in solution are unknown and might be different from the solid state ones, all three cuprates likely remain aggregated in solution. Note that t -BuOM (M = K, Na) are clusters and aggregates in the solid state and in solution (see refs 40b-40d for selected reports), exhibiting conductance in DMF that is too small for reliable measurements. (40e)
  • 73
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    • note
    • 3 products in both solutions decomposed at about the same rate.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.