[Me3Si(CF3)F]- and [Me3Si(CF3)2]-: Reactive intermediates in fluoride-initiated trifluoromethylation with Me3SiCF3 - An NMR study

Angewandte Chemie - International Edition

Volumn 38, Issue 15, 1999, Pages 2252-2253

  Maggiarosa, Nicola ^a   Tyrra, Wieland ^a   Naumann, Dieter ^a   Kirij, Natalya V ^b   Yagupolskii, Yurij L ^b  

^a UNIVERSITY OF COLOGNE   (Germany)

^b INSTITUTE OF ORGANIC CHEMISTRY   (Ukraine)

Author keywords

Fluorine; Intermediates; NMR spectroscopy; Silicon; Trifluoromethylations

Indexed keywords

ANION; FLUORIDE; SILICATE;

ARTICLE; INFRARED SPECTROSCOPY; METHYLATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS;

EID: 0033517083     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19990802)38:15<2252::AID-ANIE2252>3.0.CO;2-Z     Document Type: Article

References (9)

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3. D. J. Adams, J. H. Clark, L. B. Hansen, V. C. Sanders, S. J. Tavener, J. Fluorine Chem. 1998, 92, 123-125.
4. W. Tyrra, D. Naumann, N. V. Kirij, A. A. Kolomeitsev, Yu. L. Yagupolskii, J. Chem. Soc. Dalton Trans. 1999, 657-658.
5. 1J(F,C) = 354 Hz); N. Maggiarosa, W. Tyrra, D. Naumann, N. V. Kirij, Yu. L. Yagupolskii, unpublished results.
6. 13C);
7. 13C);
8. 13C);
9. 19F).