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Volumn 16, Issue 36, 2014, Pages 19643-19653

Vibrational dynamics and solvatochromism of the label SCN in various solvents and hemoglobin by time dependent IR and 2D-IR spectroscopy

Author keywords

[No Author keywords available]

Indexed keywords

HEMOGLOBIN; SOLVENT; THIOCYANATE; THIOCYANIC ACID DERIVATIVE;

EID: 84906534310     PISSN: 14639076     EISSN: None     Source Type: Journal    
DOI: 10.1039/c4cp01498g     Document Type: Article
Times cited : (103)

References (72)
  • 34
  • 53
    • 77953865084 scopus 로고    scopus 로고
    • The treatment frequently used for electronic transitions Springer, Boston, US
    • The treatment frequently used for electronic transitions (J. R. Lakowicz, Principles of Fluorescence Spectroscopy, Springer, Boston, US, 3rd edn, 2006
    • (2006) Principles of Fluorescence Spectroscopy
    • Lakowicz, J.R.1
  • 54
    • 85035206163 scopus 로고    scopus 로고
    • See equation 6.11) takes the change in electronic solvent polarization into account which is caused by the change of the solute’s dipole moment due to excitation. Therefore, the index of refraction of the solvent enters the respective equation. In the current study on vibrational excitations this is not the case, because the vibrational excitation’s influence on the solvent is considered negligible. Our equation incorporates the index of refraction of the solute to obtain the actual dipole moment of the solute in the solvent from the dipole moment’s gas phase value (see ref. 51)
    • and see equation 6.11) takes the change in electronic solvent polarization into account which is caused by the change of the solute’s dipole moment due to excitation. Therefore, the index of refraction of the solvent enters the respective equation. In the current study on vibrational excitations this is not the case, because the vibrational excitation’s influence on the solvent is considered negligible. Our equation incorporates the index of refraction of the solute to obtain the actual dipole moment of the solute in the solvent from the dipole moment’s gas phase value (see ref. 51)


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.