Rhodium-catalyzed asymmetric hydrogenation of unprotected NH imines assisted by a thiourea

Angewandte Chemie - International Edition

Volumn 53, Issue 32, 2014, Pages 8467-8470

  Zhao, Qingyang ^a   Wen, Jialin ^b   Tan, Renchang ^b   Huang, Kexuan ^b   Metola, Pedro ^c   Wang, Rui ^a   Anslyn, Eric V ^c   Zhang, Xumu ^b  

^a LANZHOU UNIVERSITY   (China)

^b RUTGERS UNIVERSITY   (United States)

^c University of Texas at Austin   (United States)

Author keywords

asymmetric catalysis; hydrogenation; ion pairs; reaction mechanisms; rhodium

Indexed keywords

CATALYSIS; CHLORINE COMPOUNDS; EXPERIMENTS; HYDROGEN BONDS; NITROGEN COMPOUNDS; PHOSPHORUS COMPOUNDS; RHODIUM; THIOUREAS;

ASYMMETRIC CATALYSIS; ASYMMETRIC HYDROGENATION; CHIRAL AMINES; CONTROL EXPERIMENTS; HYDROGEN BONDING INTERACTIONS; ION PAIRS; REACTION MECHANISM; RHODIUM-CATALYZED;

HYDROGENATION;

IMINE; RHODIUM; THIOUREA;

CATALYSIS; CHEMISTRY; HYDROGENATION; STEREOISOMERISM;

CATALYSIS; HYDROGENATION; IMINES; RHODIUM; STEREOISOMERISM; THIOUREA;

EID: 84905496379     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201404570     Document Type: Article

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