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Volumn 22, Issue 20, 2003, Pages 4084-4089

Effect of chelate ring size on the rate of hydride transfer from CpRu(P-P)H (P-P = chelating diphosphine) to an iminium cation

Author keywords

[No Author keywords available]

Indexed keywords

CHELATING RING SIZE; HYDRIDE TRANSFER; IMINIUM CATION;

EID: 0142008881     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0303404     Document Type: Article
Times cited : (45)

References (59)
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    • (1999) Comprehensive Asymmetric Catalysis , vol.1 , pp. 247-265
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    • 0002697856 scopus 로고
    • Nucleophilic reactivity of transition metal hydrides
    • Dedieu, A., Ed.; VCH: New York
    • (a) Labinger, J.A. Nucleophilic Reactivity of Transition Metal Hydrides. In Transition Metal Hydrides; Dedieu, A., Ed.; VCH: New York, 1992; pp 361-379.
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    • Labinger, J.A.1
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    • note
    • The solvent molecule is severely disordered, and a suitable model cannot be constructed for the solvate. The program SQUEEZE (see van der Sluis.; Spek, A. L. Acta Crystallogr. 1990, A46, 194-201) was used to refine the solvent molecule as a diffuse contribution to overall scattering without specific atom positions; however, the empirical formula, density, and absorption coefficient reflect the full formula.
  • 33
    • 0141932275 scopus 로고    scopus 로고
    • note
    • 17 which enables it to initiate a radical chain more easily by electron transfer to the solvent.
  • 36
    • 0011454359 scopus 로고
    • Trogler, W. C. Ed.; Journal of Organometallic Chemistry Library 22; Elsevier: New York
    • (b) Brown, T.L. In Organometallic Radical Processes; Trogler, W. C. Ed.; Journal of Organometallic Chemistry Library 22; Elsevier: New York, 1990, pp 67-107, and references therein.
    • (1990) Organometallic Radical Processes , pp. 67-107
    • Brown, T.L.1
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    • note; correction, J. Am. Chem. Soc. 1990, 112, 2843
    • 2H has been reported as 65 kcal/mol, and phosphine substitution usually has a negligible effect on M-H energies. (a) Tilset, M.; Parker, V.D. J. Am. Chem. Soc. 1989, 111, 6711-6717; correction, J. Am. Chem. Soc. 1990, 112, 2843.
    • (1989) J. Am. Chem. Soc. , vol.111 , pp. 6711-6717
    • Tilset, M.1    Parker, V.D.2
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    • Acidity of hydrido transition metal complexes in solution
    • Dedieu, A., Ed.; VCH: New York
    • (b) Kristjánsdóttir, S.S.; Norton, J.R. Acidity of Hydrido Transition Metal Complexes in Solution. In Transition Metal Hydrides; Dedieu, A., Ed.; VCH: New York, 1992; pp 309-359.
    • (1992) Transition Metal Hydrides , pp. 309-359
    • Kristjánsdóttir, S.S.1    Norton, J.R.2
  • 44
    • 0141966952 scopus 로고    scopus 로고
    • note
    • -1 M, with 1% (by weight) TEMPO.
  • 46
    • 0141897850 scopus 로고    scopus 로고
    • note
    • -2 M.
  • 52
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    • note
    • 22
  • 53
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    • note
    • The aromatic ring in the backbone of the other molecule is disordered.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.