TEM analysis of the internal structures and mineralogy of Asian dust particles and the implications for optical modeling

Atmospheric Chemistry and Physics

Volumn 14, Issue 14, 2014, Pages 7233-7254

  Jeong, G Y ^a   Nousiainen, T ^b  

^a Andong National University   (South Korea)

^b FINNISH METEOROLOGICAL INSTITUTE   (Finland)

Author keywords

[No Author keywords available]

Indexed keywords

AEROSOL; DUST; LIGHT SCATTERING; MINERALOGY; MODELING; TRANSMISSION ELECTRON MICROSCOPY;

EID: 84904438580     PISSN: 16807316     EISSN: 16807324     Source Type: Journal    
DOI: 10.5194/acp-14-7233-2014     Document Type: Article

References (67)

1. Adler, G., Koop, T., Haspel, C., Taraniuk, I., Moise, T., Koren, I., Heiblum, R. H., and Rudich, Y.: Formation of highly porous aerosol particles by atmospheric freeze-drying in ice clouds, P. Natl. Acad. Sci. USA, 110, 20414-20419, 2013.
2. Anderson, J. R., Buseck, P. R., Patterson, T. L., and Arimoto, R.: Characterization of the Bermuda tropospheric aerosol by combined individual-particle and bulk-aerosol analysis, Atmos. Environ., 30, 319-338, 1996.
3. Balkanski, Y., Schulz, M., Claquin, T., and Guibert, S.: Reevaluation of Mineral aerosol radiative forcings suggests a better agreement with satellite and AERONET data, Atmos. Chem. Phys., 7, 81-95, doi:10.5194/acp-7-81-2007, 2007.
4. Bedidi, A. and Cervelle, B.: Light scattering by spherical particles with hematite and goethitelike optical properties: effect of water impregnation, J. Geophy. Res., 98, 11941-11952, 1993.
5. Cardona, M. and Harbeke, G.: Optical properties and band structure of wurtzite-type crystals and rutile, Phys. Rev., 137, A1467-A1476, 1965.
6. Chen, G., Ziemba, L. D., Chu, D. A., Thornhill, K. L., Schuster, G. L., Winstead, E. L., Diskin, G. S., Ferrare, R. A., Burton, S. P., Ismail, S., Kooi, S. A., Omar, A. H., Slusher, D. L., Kleb, M. M., Reid, J. S., Twohy, C. H., Zhang, H., and Anderson, B. E.: Observations of Saharan dust microphysical and optical properties from the Eastern Atlantic during NAMMA airborne field campaign, Atmos. Chem. Phys., 11, 723-740, doi:10.5194/acp- 11-723-2011, 2011.
7. Chou, C., Formenti, P., Maille, M., Ausset, P., Helas, G., Harrison, M., and Osborne, S.: Size distribution, shape, and composition of mineral dust aerosols collected during the African Monsoon Multidisciplinary Analysis Special Observation Period 0: Dust and Biomass-Burning Experiment field campaign in Niger, January 2006, J. Geophy. Res., 113, D00C10, doi:10.1029/2008JD009897, 2008.
8. Chudnovsky, A., Ben-Dor, E., Kostinski, A. B., and Koren, I.: Mineral content analysis of atmospheric dust using hyperspectral information from space, Geophys. Res. Lett., 36, L15811, doi:10.1029/2009GL037922, 2009.
9. Chylek, P., Videen, G., Geldart, D. J. W., Dobbie, J. S., and Tso, H. C. W.: Effective medium approximations for heterogeneous particles, in: Light Scattering by Nonspherical Particles, edited by: Mishchenko, M. I., Hovenier, J. W., Travis, L. D., Academic Press, printed in the USA, 273-308, 2000.
10. Conny, J. M.: Internal composition of atmospheric dust particles from focused ion-beam scanning electeron microscopy, Environ. Sci. Technol., 47, 8575-8581, 2013.
11. Dabrowska, D. D., Muñoz, O., Moreno, F., Nousiainen, T., and Zubko, E.: Effect of the orientation of the optic axis on simulated scattering matrix elements of small birefringent particles, Opt. Lett., 37, 3252-3254, 2012.
12. Derimian, Y., Karnieli, A., Kaufman, Y. J., Andreae, M. O., Andreae, T. W., Dubovik, O., Maenhaut, W., and Koren, I.: The role of iron and black carbon in aerosol light absorption, Atmos. Chem. Phys., 8, 3623-3637, doi:10.5194/acp-8-3623-2008,2008.
13. Díaz-Hernández, J. L. and Párraga, J.: The nature and tropospheric formation of iberulite: Pinkish mineral microspherulites, Geochim. Cosmochim. Ac., 72, 3883-3906, 2008.
14. Draine, B. T. and Flatau, P. J.: Discrete-dipole approximation for scattering calculations, J. Opt. Soc. Am. A, 11, 1491-1499, 1994.
15. Dubovik, O. and King, M. D.: A flexible inversion algorithm for retrieval of aerosol optical properties from sun and sky radiance measurements, J. Geophys. Res., 105, 20673-20696, 2000.
16. Dubovik, O., Sinyuk, A., Lapyonok, T., Holben, B. N., Mishchenko, M., Yang, P., Eck, T. F., Volten, H., Munoz, O., Veihelmann, B., van der Zande, W. J., Leon, J. F., Sorokin, M., and Slutsker, I.: Application of spheroid models to account for aerosol particle nonsphericity in remote sensing of desert dust, J. Geophys. Res.- Atmos., 111, D11208, doi:10.1029/2005JD006619, 2006.
17. Falkovich, A. H., Ganor, E., Levin, Z., Formenti, P., and Rudich, Y.: Chemical and mineralogical analysis of individual mineral dust particles, J. Geophys. Res.-Atmos., 106, 18029-18036, 2001.
18. Formenti, P., Schütz, L., Balkanski, Y., Desboeufs, K., Ebert, M., Kandler, K., Petzold, A., Scheuvens, D., Weinbruch, S., and Zhang, D.: Recent progress in understanding physical and chemical properties of African and Asian mineral dust, Atmos. Chem. Phys., 11, 8231-8256, doi:10.5194/acp-11-8231-2011, 2011.
19. Forster, P., Ramaswamy, V., Artaxo, P., Berntsen, T., Betts, R., Fahey, D. W., Haywood, J., Lean, J., Lowe, D. C., Myhre, G., Nganga, J., Prinn, R., Raga, G., Schulz, M., and Van Dorland, R.: Changes in Atmospheric Constituents and in Radiative Forcing, in: Climate Change 2007: The Physical Science Basis, Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change, edited by Solomon, S., Qin, D., Manning, M., Chen, Z., Marquis, M., Averyt, K. B., Tignor, M., and Miller, H. L., Cambridge University Press, printed in United Kingdom, 2007.
20. Gao, Y., Anderson, J. R., and Hua, X.: Dust characteristics over the North Pacific observed through shipboard measurements during the ACE-Asia experiment, Atmos. Environ., 41, 7907-7922, 2007.
21. Harrison, S. P., Kohfeld, K. E., Roelandt, C., and Claquin, T.: The role of dust in climate changes today, at the last glacial maximum and in the future, Earth-Sci. Rev., 54, 43-80, 2001.
22. Haywood, J. M., Francis, P, Osborne, S. R., Glew, M., Loeb, N., Highwood, E., Tanré, D., Myhre, G., Formenti, P., and Hirst, E.: Radiative properties and direct radiative effect of Saharan dust measured by the C-130 aircraft during SHADE. 1. Solar spectrum, J. Geophys. Res. 108, 8577, doi:10.1029/2002JD002687, 2003.
23. Haywood, J. M., Allan, R. P., Culverwell, I., Slingo, T., Milton, S., Edwards, J., and Clerbaux, N.: Can desert dust explain the outgoing longwave radiation anomaly over the Sahara during July 2003?, J. Geophys. Res., 110, D05105, doi:10.1029/2004JD005232, 2005.
24. Haywood, J. M., Johnson, B. T., Osborne, S. R., Baran, A. J., Brooks, M., Milton, S. F., Mulcahy, J., Walters, D., Allan, R. P., Klaver, A., Formenti, P., Brindley, H. E., Christopher, S., and Gupta, P.: Motivation, rationale and key results from the GERBILS Saharan dust measurement campaign, Q. J. Roy. Meteor. Soc., 137, 1106-1116, 2011.
25. Ishitani, T., Umemura, K., Ohnishi, T., Yaguchi, T., and Kamino, T.: Improvements in performance of focused ion beam crosssectioning: aspects of ion-sample interaction, J. Electron Microsc., 53, 443-449, 2004
26. Jeong, G. Y.: Bulk and single-particle mineralogy of Asian dust and a comparison with its source soils, J. Geophys. Res.-Atmos., 113, D02208, doi:10.1029/2007JD008606, 2008.
27. Jeong, G. Y. and Kim, S. J.: Boxwork fabric of halloysite-rich kaolin formed by weathering of anorthosite in Sancheong area, Korea, Clay. Clay Miner., 41, 56-65, 1993.
28. Jeong, G. Y., Cheong, C.-S., and Kim, J.: Rb-Sr and K-Ar systems of biotite in surface environments regulated by weathering processes with implications for isotopic dating and hydrological cycles of Sr isotopes, Geochim. Cosmochim. Ac., 70, 4734-4739, 2006.
29. Jeong, G. Y., Kim, J. Y., Seo, J., Kim, G. M., Jin, H. C., and Chun, Y.: Long-range transport of giant particles in Asian dust identified by physical, mineralogical, and meteorological analysis, Atmos. Chem. Phys., 14, 505-521, doi:10.5194/acp-14-505-2014, 2014.
30. Kato, N. I.: Reducing focused ion beam damage to transmission electron microscopy samples, J. Electron Microsc., 53, 451-458, 2004.
31. Kandler, K., Benker, N., Bundke, U., Cuevas, E., Ebert, M., Knippertz, P., Rodríguez, S., Schütz, L., andWeinbruch, S.: Chemical composition and complex refractive index of Saharan Mineral Dust at Izaña, Tenerife (Spain) derived by electron microscopy, Atmos. Environ., 41, 8058-8074, 2007.
32. Kim, S.-W., Yoon, S.-C., and Kim, J.: Columnar Asian dust particle properties observed by sun/sky radiometers from 2000 to 2006 in Korea, Atmos. Environ., 42, 492-504, 2008.
33. Kocifaj, M. and Videen, G.: Optical behavior of composite carbonaceous aerosols: DDA and EMT approaches. J. Quant. Spectrosc. Ra., 109, 1404-1416, doi:10.1016/j.jqsrt.2007.11.007, 2008.
34. Kocifaj, M., Kundracik, F., and Videen, G.: Optical properties of single mixed-phase aerosol particles, J. Quant. Spectrosc. Ra., 109, 2108-2123, doi:10.1016/j.jqsrt.2008.03.006, 2008.
35. Koven, C. D. and Fung, I.: Inferring dust composition from wavelength-dependent absorption in Aerosol Robotic Network (AERONET) data, J. Geophys. Res., 111, D14205, doi:10.1029/2005JD006678, 2006.
36. Kulkarni, P., Baron, P. A., and Willeke, K.: Aerosol Measurement - Principles, Techniques, and Applications,Wiley, printed in USA, 2011.
37. Lafon, S., Sokolik, I. N., Rajot, J. L., Caquineau, S., and Gaudichet, A.: Characterization of iron oxides in mineral dust aerosols: Implications for light absorption, J. Geophys. Res., 111, D21207, doi:10.1029/2005JD007016, 2006.
38. Lenoble, J., Remer, L. A., and Tanré, D.: Introduction, in: Aerosol remote sensing, edited by: Lenoble, J., Remer, L. A., and Tanré, D., Springer, printed in USA, 1-11, 2013.
39. Lindqvist, H., Jokinen, O., Kandler, K., Scheuvens, D., and Nousiainen, T.: Single scattering by realistic, inhomogeneous mineral dust particles with stereogrammetric shapes, Atmos. Chem. Phys., 14, 143-157, doi:10.5194/acp-14- 143-2014, 2014.
40. Mayer, J., Giannuzzi, L. A., Kamino, T., and Michael, J.: TEM sample preparation and FIB-induced damage, MRS Bull., 32, 400-407, 2007.
41. McKendry, I. G., Macdonald, A. M., Leaitch,W. R., van Donkelaar, A., Zhang, Q., Duck, T., and Martin, R. V.: Trans-Pacific dust events observed at Whistler, British Columbia during INTEXB, Atmos. Chem. Phys., 8, 6297-6307, doi:10.5194/acp-8-6297- 2008, 2008.
42. Mooney, T. and Knacke, R. F.: Optical constants of chlorite and serpentine between 2.5 and 50 μm, Icarus, 64, 493-502, 1985.
43. Moosmüller, H., Engelbrecht, J. P., Skiba, M., Frey, G., Chakrabarty, R. K., and Arnott, W. P.: Single scattering albedo of fine mineral dust aerosols controlled by iron concentration, J. Geophs. Res., 117, D11210, doi:10.1029/2011JD016909, 2012.
44. Muinonen, K., Nousiainen, T., Lindqvist, H., Muñoz, O., and Videen, G.: Light scattering by Gaussian particles with internal inclusions and roughened surfaces using ray optics, J. Quant. Spectrosc. Radiat. Transfer, 110, 1628-1639, doi:10.1016/j.jqsrt.2009.03.012, 2009.
45. National Meteorological Satellite Center: http://nmsc.kma.go.kr/html/ homepage/en/main.do (last access: 10 May 2014), 2014.
46. Nousiainen, T., Muinonen, K., and Räisänen, P.: Scattering of light by large Saharan dust particles in a modified ray optics approximation, J. Geophys. Res., 108, 4025, doi:10.1029/2001JD001277, 2003.
47. Nousiainen, T.: Optical modeling of mineral dust particles: A review. J. Quant. Spectrosc. Ra., 110, 1261-1279, doi:10.1016/j.jqsrt.2009.03.002, 2009.
48. Nousiainen, T. and Kandler, K.: Light scattering by atmospheric mineral dust particles. Light Scattering Reviews, 9, in press, 2014.
49. Nousiainen, T., Zubko, E., Niemi, J. V., Kupiainen, K., Lehtinen, M., Muinonen, K., and Videen, G.: Single-scattering modeling of thin, birefringent mineral-dust flakes using the discrete-dipole approximation, J. Geophys. Res., 114, D07207, doi:10.1029/2008JD011564, 2009.
50. Nousiainen, T., Kahnert, M., and Lindqvist, H.: Can particle shape information be retrieved from light-scattering observations using spheroidal model particles?, J. Quant. Spectrosc. Ra., 112, 2213-2225, 2011a.
51. Nousiainen, T., Lindqvist, H., McFarquhar, G., and Um J.: Small irregular ice crystals in tropical cirrus, J. Atmos. Sci., 68, 2614-2627, 2011b.
52. Nousiainen, T., Zubko, E., Lindqvist, H., Kahnert, M., and Tyynelä, J.: Comparison of scattering by different nonspherical, wavelength-scale particles. J. Quant. Spectrosc. Ra., 113, 2391- 2405, doi:10.1016/j.jqsrt.2012. 03.032, 2012.
53. Okada, K., Naruse, H., Tanaka, T., Nemoto, O., Iwasaka, Y.,Wu, P.- M., Ono, A., Duce, R. A., Uematsu, M., and Merrill, J. T.: X-ray spectrometry of individual Asian dust-strom particles over the Japanese islands and the north Pacific Ocean, Atmos. Environ. A-Gen., 24, 1369-1378, 1990.
54. Peacor, D. R.: Diagenesis and low-grade metamorphism of shales and slates, Rev. Mineral., 27, 335-380, 1992.
55. Pósfai, M. and Molnár, A.: Atmospheric aerosol particles: a mineralogical introduction, in: Environmental Mineralogy II, edited by: Vaughan, D. J., Wogelius, R. A., 213-293, European Mineralogical Union and the Mineralogical Society of Great Britain & Ireland, London, 213-293, 2012.
56. Räisänen, P., Haapanala, P., Chung, C. E., Kahnert, M., Makkonen, R., Tonttila, J., and Nousiainen, T.: Impact of dust particle nonsphericity on climate simulations, Q. J. Roy. Meteor. Soc., 139, 2222-2232, 2013.
57. Reid, J. S., Jonsson, H. H., Maring, H. B., Smirnov, A., Savoie, D. L., Cliff, S. S., Reid, E. A., Livingston, J. M., Meier, M. M., Dubovik, O., and Tsay, S. C.: Comparison of size and morphological measurements of coarse mode dust particles from Africa, J. Geophys. Res., 108, doi:10.1029/2002JD002485, 2003.
58. Ro, C.-U., Hwang, H., Kim, H., Chun, Y., and Van Grieken, R.: Single-particle characterization of four "Asian dust" samples collected in Korea, using low-Z particle electron probe X-ray microanalysis, Environ. Sci. Technol., 39, 1409-1419, 2005.
59. Seinfeld, J. H., Carmichael, G. R., Arimoto, R., Conant, W. C., Brechtel, F. J., Bates, T. S., Cahill, T. A., Clarke, A. D., Doherty, S. J., Flatau, P. J., Huebert, B. J., Kim, J., Markowicz, K. M., Quinn, P. K., Russell, L. M., Russell, P. B., Shimizu, A., Shinozuka, Y., Song, C. H., Tang, Y. H., Uno, I., Vogelmann, A. M., Weber, R. J., Woo, J. H., and Zhang, X. Y.: ACE-ASIA - Regional climatic and atmospheric chemical effects of Asian dust and pollution, B. Am. Meteorol. Soc., 85, 367-380, 2004.
60. Sokolik, I. N. and Toon, O. B.: Direct radiative forcing by anthropogenic airborne mineral aerosols, Nature, 381, 681-683, 1996.
61. Sokolik, I. N. and Toon, B. O.: Incorporation of mineralogical composition into models of the radiative properties of mineral aerosol from UV to IR wavelengths, J. Geophys. Res., 104, 9423-9444, 1999.
62. Sokolik, I. N., Winker, D. M., Bergametti, G., Gillette, D. A., Carmichael, G., Kaufman, Y. J., Gomes, L., Schuetz, L., and Penner, J. E.: Introduction to special section: Outstanding problems in quantifying the radiative impacts of mineral dust, J. Geophys. Res., 106, 18015-18027, 2001.
63. Srodón, J.: Nature of mixed-layer clays and mechanisms of their formation and alteration. Annu. Rev. Earth Pl. Sc., 27, 19-53, 1999.
64. Tegen, I. and Lacis, A. A.:Modeling of particle size distribution and its influence on the radiative properties of mineral dust aerosol, J. Geophys. Res., 101, 19237-19244, 1996.
65. Vilaplana, R., Moreno, F., and Molina, A: Study of the sensitivity of size-averaged scattering matrix elements of nonspherical particles to changes in shape, porosity and refractive index, J. Quant. Spectrosc. Ra., 100, 415-428, doi:10.1016/j.jqsrt.2005.11.068, 2006.
66. Weaver, C. E.: Clays, muds, and shales, Elsevier, Amsterdam, 1989.
67. Zender, C. S., Bian, H., and Newman, D.: The mineral dust entrainment and deposition (DEAD) model: description and 1990s dust climatology, J. Geophys. Res., 108, 4416, doi:10.1029/2002JD002775, 2003.