Electrochemically tunable thermal conductivity of lithium cobalt oxide

Nature Communications

Volumn 5, Issue , 2014, Pages

  Cho, Jiung ^a   Losego, Mark D ^b   Zhang, Hui Gang ^a   Kim, Honggyu ^a   Zuo, Jianmin ^a   Petrov, Ivan ^a   Cahill, David G ^a,c   Braun, Paul V ^a  

^a United States of America   (United States)

^b North Carolina State University   (United States)

^c KYUSHU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL COMPOUND; LITHIUM COBALT OXIDE; UNCLASSIFIED DRUG;

ELECTROCHEMICAL METHOD; OXIDATION; OXIDE; THERMAL CONDUCTIVITY;

ARTICLE; ELECTRICAL EQUIPMENT; ELECTROCHEMISTRY; ENERGY; HIGH TEMPERATURE; LITHIATION; MEASUREMENT; OXIDATION; THERMAL CONDUCTIVITY; YOUNG MODULUS;

EID: 84901918844     PISSN: None     EISSN: 20411723     Source Type: Journal    
DOI: 10.1038/ncomms5035     Document Type: Article

References (37)

1. Cahill, D. G. et al. Nanoscale thermal transport. J. Appl. Phys. 93, 793-818 (2003).
2. Toberer, E. S., Baranowski, L. L. & Dames, C. Advances in thermal conductivity. Annu. Rev. Mater. Res. 42, 179-209 (2012).
3. Dhara, S. et al. Tunable thermal conductivity in defect engineered nanowires at low temperatures. Phys. Rev. B 84, 121307(R) (2011).
4. Kulkarni, A. J. & Zhou, M. Tunable thermal response of ZnO nanowires. Nanotechnology 18, 435706 (2007).
5. Oh, D. W., Ko, C., Ramanathan, S. & Cahill, D. G. Thermal conductivity and dynamic heat capacity across the metal-insulator transition in thin film VO2. Appl. Phys. Lett. 96, 151906 (2010).
6. Ju, Y. S. & Goodson, K. E. Phonon scattering in silicon films with thickness of order 100nm. Appl. Phys. Lett. 74, 3005-3007 (1999). (Pubitemid 129561556)
7. Lee, S. M., Cahill, D. G. & Venkatasubramanian, R. Thermal conductivity of Si-Ge superlattices. Appl. Phys. Lett. 70, 2957-2959 (1997). (Pubitemid 127643713)
8. Venkatasubramanian, R., Siivola, E., Colpitts, T. & O'Quinn, B. Thin-film thermoelectric devices with high room-temperature figures of merit. Nature 413, 597-602 (2001). (Pubitemid 32964053)
9. Hippalgaonkar, K. et al. Fabrication of microdevices with integrated nanowires for investigating low-dimensional phonon transport. Nano Lett. 10, 4341-4348 (2010).
10. Li, D. Y. et al. Thermal conductivity of individual silicon nanowires. Appl. Phys. Lett. 83, 2934-2936 (2003).
11. Hochbaum, A. I. et al. Enhanced thermoelectric performance of rough silicon nanowires. Nature 451, 163-167 (2008).
12. Boukai, A. I. et al. Silicon nanowires as efficient thermoelectric materials. Nature 451, 168-171 (2008).
13. Wang, Z. J., Alaniz, J. E., Jang, W. Y., Garay, J. E. & Dames, C. Thermal conductivity of nanocrystalline silicon: importance of grain size and frequencydependent mean free paths. Nano Lett. 11, 2206-2213 (2011).
14. Chiritescu, C. et al. Ultralow thermal conductivity in disordered, layered WSe2 crystals. Science 315, 351-353 (2007). (Pubitemid 46175510)
15. Costescu, R. M., Cahill, D. G., Fabreguette, F. H., Sechrist, Z. A. & George, S. M. Ultra-low thermal conductivity in W/Al2O3 nanolaminates. Science 303, 989-990 (2004). (Pubitemid 38209697)
16. Losego, M. D., Blitz, I. P., Vaia, R. A., Cahill, D. G. & Braun, P. V. Ultralow thermal conductivity in organoclay nanolaminates synthesized via simple selfassembly. Nano Lett. 13, 2215-2219 (2013).
17. Blyr, A. et al. Self-discharge of LiMn2O4/C Li-ion cells in their discharged state-Understanding by means of three-electrode measurements. J. Electrochem. Soc. 145, 194-209 (1998). (Pubitemid 128586975)
18. Cahill, D. G., Goodson, K. E. & Majumdar, A. Thermometry and thermal transport in micro/nanoscale solid-state devices and structures. J. Heat Transfer 124, 223-241 (2002). (Pubitemid 34416290)
19. Schmidt, A., Chiesa, M., Chen, X. Y. & Chen, G. An optical pump-probe technique for measuring the thermal conductivity of liquids. Rev. Sci. Instrum. 79, 064902 (2008).
20. Hart, F. X. & Bates, J. B. Lattice model calculation of the strain energy density and other properties of crystalline LiCoO2. J. Appl. Phys. 83, 7560-7566 (1998). (Pubitemid 128588679)
21. Wilson, R. B., Apgar, B. A., Martin, L. W. & Cahill, D. G. Thermoreflectance of metal transducers for optical pump-probe studies of thermal properties. Opt. Express 20, 28829-28838 (2012).
22. Jiles, D. C. & Staines, M. P. Piezo optic properties of Aluminum. Solid State Commun. 47, 37-41 (1983).
23. Jiles, D. C. & Staines, M. P. Piezo optic properties of nickel and platinum. J. Phys. Chem. Solids 45, 151-161 (1984). (Pubitemid 14550013)
24. Huxtable, S., Cahill, D. G., Fauconnier, V., White, J. O. & Zhao, J. C. Thermal conductivity imaging at micrometre-scale resolution for combinatorial studies of materials. Nat. Mater. 3, 298-301 (2004).
25. Antonelli, G. A., Perrin, B., Daly, B. C. & Cahill, D. G. Characterization of mechanical and thermal properties using ultrafast optical metrology. Mrs Bull. 31, 607-613 (2006). (Pubitemid 44324661)
26. Qiu, X. Y. et al. Electrochemical and electronic properties of LiCoO2 cathode investigated by galvanostatic cycling and EIS. Phys. Chem. Chem. Phys. 14, 2617-2630 (2012).
27. Vanelp, J. et al. Electronic-Structure of CoO, Li-Doped CoO, and LiCoO2. Phys. Rev. B 44, 6090-6103 (1991).
28. Kemp, J. P. & Cox, P. A. Electronic-structure of LiCoO2 and related materialsphotoemission-studies. J. Phys-Condens. Mat. 2, 9653-9667 (1990).
29. Menetrier, M., Saadoune, I., Levasseur, S. & Delmas, C. The insulator-metal transition upon lithium deintercalation from LiCoO2: electronic properties and Li7 NMR study. J. Mater. Chem. 9, 1135-1140 (1999).
30. Shi, S., Ouyang, C., Lei, M. & Tang, W. Effect of Mg-doping on the structural and electronic properties of LiCoO2: A first-principles investigation. J. Power Sources 171, 908-912 (2007). (Pubitemid 47369009)
31. Reimers, J. N. & Dahn, J. R. Electrochemical and in situ X-ray-diffraction studies of lithium intercalation in LixCoO2. J. Electrochem. Soc. 139, 2091-2097 (1992). (Pubitemid 23578419)
32. Cahill, D. G., Watson, S. K. & Pohl, R. O. Lower limit to the thermalconductivity of disordered crystals. Phys. Rev. B 46, 6131-6140 (1992).
33. Menetrier, M., Carlier, D., Blangero, M. & Delmas, C. On 'Really' stoichiometric LiCoO2. Electrochem. Solid State Lett. 11, A179-A182 (2008).
34. Kawaji, H. et al. Low temperature heat capacity and thermodynamic functions of LiCoO2. J. Therm. Anal. Calorim. 68, 833-839 (2002). (Pubitemid 34772170)
35. Reynier, Y. et al. Entropy of Li intercalation in LixCoO2. Phys. Rev. B 70, 174304 (2004).
36. Huang, B., Jang, Y. I., Chiang, Y. M. & Sadoway, D. R. Electrochemical evaluation of LiCoO2 synthesized by decomposition and intercalation of hydroxides for lithium-ion battery applications. J. Appl. Electrochem. 28, 1365-1369 (1998). (Pubitemid 128509470)
37. Jang, Y. I. et al. LiAlyCo1-yO2 (R(3)over-bar-m) intercalation cathode for rechargeable lithium batteries. J. Electrochem. Soc. 146, 862-868 (1999).