Concise total synthesis of (±)-actinophyllic acid

Tetrahedron

Volumn 70, Issue 27-28, 2014, Pages 4094-4104

  Granger, Brett A ^a   Jewett, Ivan T ^a   Butler, Jeffrey D ^a   Martin, Stephen F ^a  

^a University of Texas at Austin   (United States)

Author keywords

Cascade reaction; Iminium ion; Mannich type reaction; Total synthesis

Indexed keywords

1,3 BIS(BENZYLOXY) 2 (1H INDOL 2 YL)PROPAN 2 YL ACETATE; 2 ALLYL 7 (TERT BUTYL) 6,6 BIS[(BENZYLOXY) METHYL] 12 [(TRIMETHYLSILYL)OXY] 3,4,5,6 TETRAHYDRO 1H 5,1 ETHANOAZOCINO[4,3 B]INDOLE 2,7 DICARBOXYLATE; 2 ALLYL 7 (TERT BUTYL) 6,6 BIS[(BENZYLOXY)METHYL] 12 HYDROXY 3,4,5,6 TETRAHYDRO 1H 5,1 ETHANOAZOCINO[4,3 B]INDOLE 2,7 DICARBOXYLATE; 2 ALLYL 7 (TERT BUTYL) 6,6 BIS[(BENZYLOXY)METHYL] 12 OXO 3,4,5,6 TETRAHYDRO 1H 1,5 ETHANOAZOCINO[4,3 B]INDOLE 2,7 DICARBOXYLATE; 6,6 BIS[(BENZYLOXY)METHYL] 2,3,4,5,6,7 HEXAHYDRO 1H 5,1 ETHANOAZOCINO[4,3 B]INDOL 12 OL; 8 (HYDROXYMETHYL) 2,3,5,6,7,8,9,13C OCTAHYDRO 1H 1,7,8 (EPIMETHANETRIYLOXY METHANO)PYRROLO[10,20:1,2]AZOCINO[4,3 B]INDOL 16 OL; ACTINOPHYLLIC ACID; ALLYL 5 OXO 2,3,4,5 TETRAHYDRO 1H AZEPINE 1 CARBOXYLATE; ALLYL 5 [(TRIISOPROPYLSILYL)OXY] 2,3 DIHYDRO 1H AZEPINE 1 CARBOXYLATE; ALLYL 6,6 BIS[(BENZYLOXY)METHYL] 12 HYDROXY 1,3,4,5,6,7 HEXAHYDRO 2H 5,1 ETHANOAZOCINO[4,3 B]INDOLE 2 CARBOXYLATE; ALLYL 6,6 BIS[(BENZYLOXY)METHYL] 12 [(TRIISOPROPYLSILYL)OXY] 1,3,4,5,6,7 HEXAHYDRO 2H 1,5 ETHENOAZOCINO[4,3 B]INDOLE 2 CARBOXYLATE; ALLYL 6,6 BIS[(BENZYLOXY)METHYL] 12 [(TRIMETHYLSILYL)OXY] 1,3,4,5,6,7 HEXAHYDRO 2H 5,1 ETHANOAZOCINO[4,3 B]INDOLE 2 CARBOXYLATE; ALLYL BIS[(BENZYLOXY)METHYL] 12 OXO 1,3,4,5,6,7 HEXAHYDRO 2H 1,5 ETHANOAZOCINO[4,3 B]INDOLE 2 CARBOXYLATE; BENZYL 5 OXO 2,3,4,5 TETRAHYDRO 1H AZEPINE 1 CARBOXYLATE; BENZYL 6,6 BIS[(BENZYLOXY)METHYL] 12 [(TRIISOPROPYLSILYL)OXY] 1,3,4,5,6,7 HEXAHYDRO 2H 1,5 ETHENOAZOCINO[4,3 B]INDOLE 2 CARBOXYLATE; INDOLE ALKALOID; METHYL 5 OXO 2,3,4,5 TETRAHYDRO 1H AZEPINE 1 CARBOXYLATE; METHYL 6,6 BIS[(BENZYLOXY)METHYL] 12 [(TRIISOPROPYLSILYL)OXY] 3,4,5,6 TETRAHYDRO 1H 1,5 ETHENOAZOCINO[4,3 B]INDOLE 2 (7H)CARBOXYLATE; TERT BUTYL 6,6 BIS[(BENZYLOXY)METHYL] 12 HYDROXY 1,2,3,4,5,6 HEXAHYDRO 7H 5,1 ETHANOAZOCINO[4,3 B]INDOLE 7 CARBOXYLATE; TERT BUTYL 6,6 BIS[(BENZYLOXY)METHYL] 12 OXO 1,2,3,4,5,6 HEXAHYDRO 7H 1,5 ETHANOAZOCINO[4,3 B]INDOLE 7 CARBOXYLATE; TERT BUTYL 6,6 BIS[(BENZYLOXY)METHYL] 2 (2 CHLOROETHYL) 12 HYDROXY 1,2,3,4,5,6 HEXAHYDRO 7H 5,1 ETHANOAZOCINO[4,3 B]INDOLE 7 CARBOXYLATE; TERT BUTYL 6,6 BIS[(BENZYLOXY)METHYL] 2 (2 CHLOROETHYL) 12 OXO 1,2,3,4,5,6 HEXAHYDRO 7H 1,5 ETHANOAZOCINO[4,3 B]INDOLE 7 CARBOXYLATE; TERT BUTYL 8,8 BIS[(BENZYLOXY) METHYL] 14 OXO 1,2,3,5,6,7,8,13C OCTAHYDRO 9H 1,7 METHANO PYRROLO[10,20:1,2]AZOCINO[4,3 B]INDOLE 9 CARBOXYLATE; TERT BUTYL 8,8 BIS[(BENZYLOXY)METHYL] 14 OXO 1,2,3,5,6,7,8,13C-OCTAHYDRO 9H 1,7 METHANOPYRROLO[10,20:1,2]AZOCINO[4,3 B]INDOLE 9 CARBOXYLATE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; DRUG SYNTHESIS; PRIORITY JOURNAL;

EID: 84901304346     PISSN: 00404020     EISSN: 14645416     Source Type: Journal    
DOI: 10.1016/j.tet.2014.03.034     Document Type: Article

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