A novel chromium trioxide catalyzed oxidation of primary alcohols to the carboxylic acids

Tetrahedron Letters

Volumn 39, Issue 30, 1998, Pages 5323-5326

  Zhao, Mangzhu ^a   Li, Jing ^a   Song, Zhiguo ^a   Desmond, Richard ^a   Tschaen, David M ^a   Grabowski, Edward J J ^a   Reider, Paul J ^a  

^a MERCK RESEARCH LABORATORIES   (United States)

Author keywords

Alcohols; Catalysis; Chromium; Oxidation

Indexed keywords

ALCOHOL; CARBOXYLIC ACID; CHROMIUM;

ARTICLE; CATALYSIS; CHIRALITY; NUCLEAR MAGNETIC RESONANCE; OXIDATION; QUANTITATIVE DIAGNOSIS; RACEMIC MIXTURE; STOICHIOMETRY;

EID: 0032560829     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(98)00987-3     Document Type: Article

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17. 3) δ: 7.44 (d, J=8.7 Hz, 1H), 6.78 (d, J=3.1 Hz, 1H), 6.66 (dd, J=8.7, 3.1 Hz, 1H), 3.75 (s, 3H), 3.13 (dd, J=13.1, 6.8 Hz, 1H), 2.98-2.84 (m, 1H), 2.77 (dd, J=13.1, 7.4 Hz, 1H), 1.23 (d, J=6.9 Hz, 3H).
18. 3) δ 172.04, 169.48, 137.52, 128.73, 126.16, 94.66, 77.05, 64.34, 34.52, 29.91, 23.45, 17.28.
19. 4 mobile phase (0.80 mL/min); UV detection at 220 nm; Retention times: D-phenylalanine, 9.3 min; L-phenylalanine, 11.6 min.