Triamidoamine-uranium(IV)-stabilized terminal parent phosphide and phosphinidene complexes

Angewandte Chemie - International Edition

Volumn 53, Issue 17, 2014, Pages 4484-4488

  Gardner, Benedict M ^a   Balázs, Gábor ^b   Scheer, Manfred ^b   Tuna, Floriana ^c   McInnes, Eric J L ^c   McMaster, Jonathan ^a   Lewis, William ^a   Blake, Alexander J ^a   Liddle, Stephen T ^a  

^a UNIVERSITY OF NOTTINGHAM   (United Kingdom)

^b UNIVERSITY OF REGENSBURG   (Germany)

^c UNIVERSITY OF MANCHESTER   (United Kingdom)

Author keywords

density functional calculations; multiple bonds; phosphides; phosphinidene; uranium

Indexed keywords

CROWN ETHERS; DENSITY FUNCTIONAL THEORY; ETHERS; PHOSPHORUS COMPOUNDS;

BENZO-15-CROWN-5; DFT CALCULATION; MAYER BOND ORDERS; MULTIPLE BONDS; PHOSPHIDES; PHOSPHINIDENES;

URANIUM;

EID: 84899020747     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201400798     Document Type: Article

References (82)

1. H. Aktaş, J. C. Slootweg, K. Lammertsma, Angew. Chem. 2010, 122, 2148
2. Angew. Chem. Int. Ed. 2010, 49, 2102
3. R. Waterman, Dalton Trans. 2009, 18
4. B. P. Johnson, G. Balázs, M. Scheer, Coord. Chem. Rev. 2006, 250, 1178
5. C. C. Cummins, Angew. Chem. 2006, 118, 876
6. Angew. Chem. Int. Ed. 2006, 45, 862
7. F. García, M. L. Stead, D. S. Wright, J. Omet. Chem. 2006, 691, 1673
8. F. Mathey, Angew. Chem. 2003, 115, 1616
9. Angew. Chem. Int. Ed. 2003, 42, 1578
10. K. Lammertsma, M. J. M. Vlaar, Eur. J. Org. Chem. 2002, 1127
11. F. Mathey, N. H. T. Huy, A. Marinetti, Helv. Chim. Acta 2001, 84, 2938
12. A. D. Hopkins, J. A. Wood, D. S. Wright, Coord. Chem. Rev. 2001, 216-217, 155
13. M. Scheer, Coord. Chem. Rev. 1997, 163, 271
14. A. H. Cowley, Acc. Chem. Res. 1997, 30, 445
15. A. H. Cowley, Acc. Chem. Res. 1988, 21, 81
16. F. Mathey, Angew. Chem. 1987, 99, 285
17. Angew. Chem. Int. Ed. Engl. 1987, 26, 275
18. G. Huttner, K. Evertz, Acc. Chem. Res. 1986, 19, 406.
19. P. B. Hitchcock, M. F. Lappert, W. P. Leung, J. Chem. Soc. Chem. Commun. 1987, 1282
20. R. Bohra, P. B. Hitchcock, M. F. Lappert, W. P. Leung, Polyhedron 1989, 8, 1884.
21. Selected examples
22. R. Waterman, T. D. Tilley, Chem. Sci. 2011, 2, 1320
23. G. Zhao, F. Basuli, U. J. Kilgore, H. Fan, H. Aneetha, J. C. Huffman, G. Wu, D. J. Mindiola, J. Am. Chem. Soc. 2006, 128, 13575
24. B. C. Bailey, J. C. Huffman, D. J. Mindiola, W. Weng, O. V. Ozerov, Organometallics 2005, 24, 1390
25. F. Basuli, J. Tomaszewski, J. C. Huffman, D. J. Mindiola, J. Am. Chem. Soc. 2003, 125, 10170
26. J. B. Bonanno, P. T. Wolczanski, E. B. Lobkovsky, J. Am. Chem. Soc. 1994, 116, 11159
27. Z. Hou, T. L. Breen, D. W. Stephan, Organometallics 1993, 12, 3158
28. C. C. Cummins, R. R. Schrock, W. M. Davis, Angew. Chem. 1993, 105, 758
29. Angew. Chem. Int. Ed. Engl. 1993, 32, 756
30. A. H. Cowley, B. Pellerin, J. L. Atwood, S. G. Bott, J. Am. Chem. Soc. 1990, 112, 6734.
31. X. Li, S. I. Weissman, T. S. Lin, P. P. Gaspar, J. Am. Chem. Soc. 1994, 116, 7899
32. P. F. Zittel, W. C. Lineberger, J. Chem. Phys. 1976, 65, 1236.
33. 2 structurally characterized complexes.
34. A triamidoamine tantalum-phosphinidene phenyl complex undergoes cleavage of the P-phenyl bond to afford a TaPLi linkage, but although this could be quenched with carbon- and silicon-based electrophiles, attempts to prepare the parent TaPH linkage were not successful:, J. S. Freundlich, R. R. Schrock, W. M. Davis, J. Am. Chem. Soc. 1996, 118, 3643.
35. Formation of a NbPH linkage is mentioned in a reactivity study of a niobium phosphine complex but the only structurally characterized complex in that report is a bridging phosphinidiide complex exhibiting a Nb-P(H)-Nb core:, K. F. Hirsekorn, A. S. Veige, P. T. Wolczanski, J. Am. Chem. Soc. 2006, 128, 2192.
36. A. W. Ehlers, E. J. Baerends, K. Lammertsma, J. Am. Chem. Soc. 2002, 124, 2831.
37. J. J. Harrison, B. E. Williamson, J. Phys. Chem. A 2005, 109, 1343
38. G. Bucher, M. L. G. Borst, A. W. Ehlers, K. Lammertsma, S. Ceola, M. Huber, D. Grote, W. Sander, Angew. Chem. 2005, 117, 3353
39. Angew. Chem. Int. Ed. 2005, 44, 3289
40. J. Glatthaar, G. Maier, Angew. Chem. 2004, 116, 1314
41. Angew. Chem. Int. Ed. 2004, 43, 1294.
42. K. Hansen, T. Szilvási, B. Blom, E. Irran, M. Driess, Chem. Eur. J. 2014, 20, 1947
43. K. Hansen, T. Szilvási, B. Blom, S. Inoue, J. Epping, M. Driess, J. Am. Chem. Soc. 2013, 135, 11795
44. Y. Wang, Y. Xie, M. Y. Abraham, R. J. Gilliard,? Jr., P. Wei, H. F. Schaefer ? III, P. v. R. Schleyer, G. H. Robinson, Organometallics 2010, 29, 4778
45. M. Driess, S. Block, M. Brym, M. T. Gamer, Angew. Chem. 2006, 118, 2351
46. Angew. Chem. Int. Ed. 2006, 45, 2293
47. K. Issleib, E. Leissring, M. Riemer, H. Oehme, Z. Chem. 1983, 23, 99.
48. D. S. J. Arney, R. C. Schnabel, B. C. Scott, C. J. Burns, J. Am. Chem. Soc. 1996, 118, 6780.
49. A bridging phosphinidiide with a U-P(H)-U core has been reported:, M. R. Duttera, V. W. Day, T. J. Marks, J. Am. Chem. Soc. 1984, 106, 2907.
50. 2 groups bound to metal centers.
51. 2- units, the term phosphanediide could be invoked. However, in the present context we prefer phosphinidene to emphasize the ene multiple bond nature of a terminal UPH linkage, and use phosphinidiide to refer to bridging M-P(H)-M species.
52. D. M. King, F. Tuna, E. J. L. McInnes, J. McMaster, W. Lewis, A. J. Blake, S. T. Liddle, Nat. Chem. 2013, 5, 482
53. D. M. King, F. Tuna, E. J. L. McInnes, J. McMaster, W. Lewis, A. J. Blake, S. T. Liddle, Science 2012, 337, 717.
54. Full details can be found in the Supporting Information.
55. B. M. Gardner, W. Lewis, A. J. Blake, S. T. Liddle, Inorg. Chem. 2011, 50, 9631
56. B. M. Gardner, J. McMaster, W. Lewis, A. J. Blake, S. T. Liddle, J. Am. Chem. Soc. 2009, 131, 10388.
57. P. Pyykkö, M. Atsumi, Chem. Eur. J. 2009, 15, 186.
58. S. W. Hall, J. C. Huffman, M. M. Miller, L. R. Avens, C. J. Burns, A. P. Sattelberger, D. S. J. Arney, A. F. England, Organometallics 1993, 12, 752.
59. J. C. Peters, A. L. Odom, C. C. Cummins, Chem. Commun. 1997, 1995.
60. P. Pyykkö, M. Atsumi, Chem. Eur. J. 2009, 15, 12770.
61. J. C. Berthet, M. Ephritikhine, Coord. Chem. Rev. 1998, 178-180, 83.
62. D. P. Mills, F. Moro, J. McMaster, J. van?Slageren, W. Lewis, A. J. Blake, S. T. Liddle, Nat. Chem. 2011, 3, 454.
63. B. M. Gardner, J. C. Stewart, A. L. Davis, J. McMaster, W. Lewis, A. J. Blake, S. T. Liddle, Proc. Natl. Acad. Sci. USA 2012, 109, 9265
64. B. M. Gardner, D. Patel, W. Lewis, A. J. Blake, S. T. Liddle, Angew. Chem. 2011, 123, 10624
65. Angew. Chem. Int. Ed. 2011, 50, 10440
66. B. M. Gardner, D. Patel, A. D. Cornish, J. McMaster, W. Lewis, A. J. Blake, S. T. Liddle, Chem. Eur. J. 2011, 17, 11266
67. B. M. Gardner, J. McMaster, F. Moro, W. Lewis, A. J. Blake, S. T. Liddle, Chem. Eur. J. 2011, 17, 6909
68. S. T. Liddle, J. McMaster, D. P. Mills, A. J. Blake, C. Jones, W. D. Woodul, Angew. Chem. 2009, 121, 1097
69. Angew. Chem. Int. Ed. 2009, 48, 1077
70. B. M. Gardner, J. McMaster, W. Lewis, S. T. Liddle, Chem. Commun. 2009, 2851.
71. O. J. Cooper, D. P. Mills, J. McMaster, F. Tuna, E. J. L. McInnes, W. Lewis, A. J. Blake, S. T. Liddle, Chem. Eur. J. 2013, 19, 7071
72. D. P. Mills, O. J. Cooper, F. Tuna, E. J. L. McInnes, E. S. Davies, J. McMaster, F. Moro, W. Lewis, A. J. Blake, S. T. Liddle, J. Am. Chem. Soc. 2012, 134, 10047
73. O. J. Cooper, D. P. Mills, J. McMaster, F. Moro, E. S. Davies, W. Lewis, A. J. Blake, S. T. Liddle, Angew. Chem. 2011, 123, 2431
74. Angew. Chem. Int. Ed. 2011, 50, 2383.
75. R. F. W. Bader, T. S. Slee, D. Cremer, E. Kraka, J. Am. Chem. Soc. 1983, 105, 5061.
76. M. Gregson, E. Lu, J. McMaster, W. Lewis, A. J. Blake, S. T. Liddle, Angew. Chem. 2013, 125, 13254
77. Angew. Chem. Int. Ed. 2013, 52, 13016.
78. 3] has been characterized in matrix isolation experiments and computationally
79. D. M. King, S. T. Liddle, Coord. Chem. Rev. 2014, 266-267, 2
80. B. Vlaisavljevich, L. Gagliardi, Inorg. Chem. 2010, 49, 9230
81. L. Andrews, X. Wang, R. Lindh, B. O. Roos, C. J. Marsden, Angew. Chem. 2008, 120, 5446
82. Angew. Chem. Int. Ed. 2008, 47, 5366.