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Volumn 52, Issue 49, 2013, Pages 13016-13019

A cerium(IV)-carbon multiple bond

Author keywords

carbenes; cerium; density functional theory; lanthanides; multiple bonding

Indexed keywords

BONDING INTERACTIONS; CARBENE COMPLEXES; CARBENES; DECOMPOSITION REACTION; ELECTRON PAIR; MULTIPLE BONDING; MULTIPLE BONDS; ONE-ELECTRON OXIDATION;

EID: 84888633690     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201306984     Document Type: Article
Times cited : (91)

References (50)
  • 4
    • 0346610043 scopus 로고    scopus 로고
    • These ligands can be referred to as methanediides, carbenes, or nucleophilic carbenes, and blur the traditional classifications of Fischer carbenes and Schrock alkylidenes; see R. G. Cavell, R. P. K. Babu, K. Aparna, J. Organomet. Chem. 2001, 617, 158
    • (2001) J. Organomet. Chem. , vol.617 , pp. 158
    • Cavell, R.G.1    Babu, R.P.K.2    Aparna, K.3
  • 9
    • 78650332060 scopus 로고    scopus 로고
    • Herein we use the term carbene, as this is consistent with the experimental spectroscopic and reactivity data and the theoretical bonding model of a formal two-fold multiple bonding interaction involving two electron pairs between the cerium and carbon centers.
    • D. J. Mindiola, J. Scott, Nat. Chem. 2011, 3, 15. Herein we use the term carbene, as this is consistent with the experimental spectroscopic and reactivity data and the theoretical bonding model of a formal two-fold multiple bonding interaction involving two electron pairs between the cerium and carbon centers.
    • (2011) Nat. Chem. , vol.3 , pp. 15
    • Mindiola, D.J.1    Scott, J.2
  • 50
    • 27644437191 scopus 로고    scopus 로고
    • I dimer in which a quintuple bonding interaction does not necessarily result in a bond order of five.
    • I dimer in which a quintuple bonding interaction does not necessarily result in a bond order of five:, T. Nguyen, A. D. Sutton, M. Brynda, J. C. Fettinger, G. J. Long, P. P. Power, Science 2005, 310, 844.
    • (2005) Science , vol.310 , pp. 844
    • Nguyen, T.1    Sutton, A.D.2    Brynda, M.3    Fettinger, J.C.4    Long, G.J.5    Power, P.P.6


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.