Preparation of actinide phosphinidene complexes: Steric control of reactivity

Journal of the American Chemical Society

Volumn 118, Issue 28, 1996, Pages 6780-6781

  Arney, David S J ^a   Schnabel, R Chris ^a   Scott, Brian C ^a   Burns, Carol J ^a  

^a LOS ALAMOS NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; COMPLEXATION; PHOSPHORUS COMPOUNDS; SYNTHESIS (CHEMICAL); URANIUM COMPOUNDS;

ACTINIDE PHOSPHINIDINE COMPLEXES; REACTIVITY; STERIC CONTROL;

ORGANOMETALLICS;

ACTINIDE; METAL COMPLEX;

ARTICLE; COMPLEX FORMATION; REACTION ANALYSIS;

EID: 8944233358     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja960221y     Document Type: Article

References (47)

1. (a) Wigley, D. E. Prog. Inorg. Chem. 1994, 42, 239.
2. (b) Nugent, W. A.; Mayer, J. M. Metal-Ligand Multiple Bonds; John Wiley and Sons: New York, 1988.
3. (c) Nugent, W. A.; Haymore, B. L. Coord. Chem. Rev. 1980, 31, 123.
4. (a) Walsh, P. J.; Hollander, F. J.; Bergman, R. G. J. Am. Chem. Soc. 1988, 110, 8729.
5. (b) Cummins, C. C.; Baxter, S. M.; Wolczanski, P. T. J. Am. Chem. Soc. 1988, 110, 8731.
6. (c) Walsh, P. J.; Baranger, A. M.; Bergman, R. G. J. Am. Chem. Soc. 1992, 114, 1708.
7. (d) Baranger, A. M.; Walsh, P. J.; Bergman, R. G. J. Am. Chem. Soc. 1993, 115, 2753.
8. (e) Walsh, P. J.; Hollander, F. J.; Bergman, R. G. Organometallics 1993, 12, 3705.
9. (f) Cundari, T. R. Organometallics 1993, 12, 4971.
10. (g) Bennett, J. L.; Wolczanski, P. T. J. Am. Chem. Soc. 1994, 116, 2179.
11. (h) Meyer, K. E.; Walsh, P. J.; Bergman, R. G. J. Am. Chem. Soc. 1994, 116, 2669.
12. (a) Morrison, D. L.; Wigley, D. E. Inorg. Chem. 1995, 34, 2610.
13. (b) Morrison, D. L.; Wigley, D. E. J. Chem. Soc., Chem. Commun. 1995, 79.
14. (c) Huber, S. R.; Baldwin, T. C.; Wigley, D. E. Organometallics 1993, 12, 91.
15. (a) Arney, D. S. J.; Burns, C. J. J. Am. Chem. Soc. 1995, 117, 9448.
16. (b) Arney, D. S. J.; Burns, C. J.; Smith, D. C. J. Am. Chem. Soc. 1992, 114, 10068.
17. For discussions of bonding in phosphinidene complexes, see: (a) Mathey, F. Angew. Chem., Int. Ed. Engl. 1987, 26, 275. (b) Cowley, A. H.; Barren, A. R. Acc. Chem. Res. 1988, 21, 81.
18. For discussions of bonding in phosphinidene complexes, see: (a) Mathey, F. Angew. Chem., Int. Ed. Engl. 1987, 26, 275. (b) Cowley, A. H.; Barren, A. R. Acc. Chem. Res. 1988, 21, 81.
19. (a) Hitchcock, P. B.; Lappert, M. F.; Leung, W.-P. J. Chem. Soc., Chem. Commun. 1987, 1282.
20. (b) Bohra, P.; Hitchcock, P. B.; Lappert, M. F.; Leung, W.-P. Polyhedron 1989, 8, 1884.
21. (c) Cowley, A. H.; Pellerin, B.; Atwood, J. L.; Bott, S. G. J. Am. Chem. Soc. 1990, 112, 6734.
22. (d) Hou, Z.; Stephan. D. W. J. Am. Chem. Soc. 1992, 114, 10088.
23. (e) Hou, Z.; Breen, D. W.; Stephan, D. W. Organometallics 1993, 12, 3158.
24. (f) Cummins, C. C.; Schrock, R. R.; Davis, W. M. Angew. Chem., Int. Ed. Engl. 1993, 32, 756.
25. (g) Bonanno, J. B.; Wolczanski, P. T.; Lobkovsky, E. B. J. Am. Chem. Soc. 1994, 116, 11159.
26. Duttera, M. R.; Day, V. W.; Marks, T. J. J. Am. Chem. Soc. 1984, 106, 2907.
27. 2OU: C, 56.15; H, 7.82. Found: C, 55.50; H, 7.92.
28. Precedent exists in the literature for both reduction of uranium(IV) by phosphide ligands and intramolecular C-H activation by reactive metal phosphinidene complexes: (a) Blake, P. C.; Hey, E.; Lappert, M. F.; Atwood, J. L.; Zhang, H. J. Organomet. Chem. 1988, 353, 307. (b) Champion, D. H.; Cowley, A. H. Polyhedron 1985, 4, 1791. (c) Arif, A. M.; Cowley, A. H.; Nunn, C. M.; Pakulski, M. J. Chem. Soc., Chem. Commun. 1987, 994. See also ref 11d.
29. Precedent exists in the literature for both reduction of uranium(IV) by phosphide ligands and intramolecular C-H activation by reactive metal phosphinidene complexes: (a) Blake, P. C.; Hey, E.; Lappert, M. F.; Atwood, J. L.; Zhang, H. J. Organomet. Chem. 1988, 353, 307. (b) Champion, D. H.; Cowley, A. H. Polyhedron 1985, 4, 1791. (c) Arif, A. M.; Cowley, A. H.; Nunn, C. M.; Pakulski, M. J. Chem. Soc., Chem. Commun. 1987, 994. See also ref 11d.
30. Precedent exists in the literature for both reduction of uranium(IV) by phosphide ligands and intramolecular C-H activation by reactive metal phosphinidene complexes: (a) Blake, P. C.; Hey, E.; Lappert, M. F.; Atwood, J. L.; Zhang, H. J. Organomet. Chem. 1988, 353, 307. (b) Champion, D. H.; Cowley, A. H. Polyhedron 1985, 4, 1791. (c) Arif, A. M.; Cowley, A. H.; Nunn, C. M.; Pakulski, M. J. Chem. Soc., Chem. Commun. 1987, 994. See also ref 11d.
31. (a) Bombieri, G.; Forsellini, E.; Day, J. P.; Azeez, W. I. J. Chem. Soc., Dalton Trans. 1978, 677.
32. (b) Brennan, J. G.; Andersen, R. A.; Zalkin, A. Inorg. Chem. 1986, 25, 1761.
33. (c) Bombieri, G.; Brown, D.; Mealli, C. J. Chem. Soc., Dalton Trans. 1976, 2025.
34. (d) Alcock, N. W.; Roberts, M. M.; Brown, D. J. Chem. Soc., Dalton Trans. 1982, 25.
35. (e) Cotton, A.; Marler, D. O.; Schwotzer, W. Acta Crystallogr. 1984. C40, 1186.
36. (a) Ritchey, J. M.; Zozulin, A. J.; Wrobleski, D. A.; Ryan, R. R.; Wasserman, H. J.; Moody, D. C.; Paine, R. T. J. Am. Chem. Soc. 1985, 107, 501.
37. (b) Wrobleski, D. A.; Ryan, R. R.; Wasserman, H. J.; Salazar, K. V.; Paine, R. T.; Moody, D. C. Organomelallics 1986, 5, 90.
38. (c) Paolucci, G.; Rossetto, G.; Zanella, P.; Fischer, R. D. J. Organomet. Chem. 1985, 284, 213.
39. (d) Hall, S. W.; Huffman, J. C.; Miller, M. M.; Avens, L. R.; Burns, C. J.; Arney, D. S. J.; England, A. F.; Sattelberger, A. P. Organometallics 1993, 12, 752.
40. T. R. Cundari, personal communication.
41. (a) Fendrick, C. M.; Schertz, L. D.; Day, V. W.; Marks, T. J. Organometallics 1988, 7, 1828.
42. (b) Stern, D.; Sabat, M.; Marks, T. J. J. Am. Chem. Soc. 1990, 112, 9558.
43. (c) Jeske, G.; Schock, L. E.; Swepston, P. N.; Schumann, J.; Marks, T. J. J. Am. Chem. Soc. 1985, 107, 8103.
44. (d) Schnabel, R. C.; Burns, C. J.; Scott, B. C. Manuscript in preparation.
45. 51SiPU: C, 53.96; H, 6.79. Found: C, 54.16; H, 6.73.
46. The molecular weight of 2b was determined using a Signer-type isopiestic molecular weight apparatus (The Manipulation of Air-Sensitive Compounds, 2nd ed.; Shriver, D. F.; Drezdzon, M. A., Eds.; Wiley Interscience: New York, 1986). Weight determined: 1570 amu (expected molecular weight for dimer = 1513.75 amu).
47. 3).