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Crystal data for 3: C46.75H85GaN 6OSi3U, M, 1139.23, monoclinic space group P21/c, a, 19.9862(14, b, 13.0182(9, c, 44.033(3) Å, β, 97.329(2)°, V, 11363.0(14) Å3, Z, 8, ρcalcd, 1.332 g cm -3; MoKα radiation, λ, 0.71073 Å, μ, 3.420 mm-1, T, 150 K. 46118 reflections (14816 unique reflections, Rint, 0.0555, θ < 22.50°) were collected on a Bruker SMART APEX CCD diffractometer using narrow frames (0.3° in ω) and were corrected semiempirically for absorption (transmission 0.47-0.66, The structure was solved by direct methods and refined by full-matrix least-squares on F2 values of all data (G. M. Sheldrick, SHELXTL manual, Bruker AXS, Madison, WI, USA, 1997) to give wR2, 0.1139 and R
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