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Volumn 48, Issue 6, 2009, Pages 1077-1080

σ and π donation in an unsupported uranium-gallium bond

Author keywords

Actinides; Gallium; Magnetic properties; Metal metal interactions; Uranium

Indexed keywords

ACTINIDES; MAGNETIC PROPERTIES; METALS; NEUTRON DETECTORS; TRANSURANIUM ELEMENTS; URANIUM;

EID: 59049101576     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200805481     Document Type: Article
Times cited : (131)

References (51)
  • 19
    • 59049092156 scopus 로고
    • For spectroscopically characterized uranium-metal complexes, see: a
    • For spectroscopically characterized uranium-metal complexes, see: a) S. P. Nolan, M. Porchia, T. J. Marks, J. Am. Chem. Soc. 1991, 113, 1450;
    • (1991) J. Am. Chem. Soc , vol.113 , pp. 1450
    • Nolan, S.P.1    Porchia, M.2    Marks, T.J.3
  • 30
    • 0037609892 scopus 로고
    • For the THF-free complex see
    • For the THF-free complex see: P. Scott, P. B. Hitchcock, Polyhedron 1994, 13, 1651.
    • (1994) Polyhedron , vol.13 , pp. 1651
    • Scott, P.1    Hitchcock, P.B.2
  • 31
    • 59049084909 scopus 로고    scopus 로고
    • See the Supporting Information for full details
    • See the Supporting Information for full details.
  • 37
    • 59049093880 scopus 로고    scopus 로고
    • Crystal data for 3: C46.75H85GaN 6OSi3U, M, 1139.23, monoclinic space group P21/c, a, 19.9862(14, b, 13.0182(9, c, 44.033(3) Å, β, 97.329(2)°, V, 11363.0(14) Å3, Z, 8, ρcalcd, 1.332 g cm -3; MoKα radiation, λ, 0.71073 Å, μ, 3.420 mm-1, T, 150 K. 46118 reflections (14816 unique reflections, Rint, 0.0555, θ < 22.50°) were collected on a Bruker SMART APEX CCD diffractometer using narrow frames (0.3° in ω) and were corrected semiempirically for absorption (transmission 0.47-0.66, The structure was solved by direct methods and refined by full-matrix least-squares on F2 values of all data (G. M. Sheldrick, SHELXTL manual, Bruker AXS, Madison, WI, USA, 1997) to give wR2, 0.1139 and R
    • -3. CCDC 693901 1 and 693900 3 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.