S-((Phenylsulfonyl)difluoromethyl)thiophenium salts: Carbon-selective electrophilic difluoromethylation of β-ketoesters, β-diketones, and dicyanoalkylidenes

Angewandte Chemie - International Edition

Volumn 53, Issue 7, 2014, Pages 1827-1831

  Wang, Xin ^a   Liu, Guokai ^a   Xu, Xiu Hua ^a   Shibeta, Naoyuki ^a   Tokunaga, Etsuko ^a   Shibata, Norio ^a  

^a NAGOYA INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

enantioselectivity; fluorine; regioselectivity; sulfur; synthetic methods

Indexed keywords

1 ,8-DIAZABICYCLO[5.4.0]UNDEC-7-ENE; CARBON NUCLEOPHILES; ENANTIOSELECTIVE; INTRAMOLECULAR CYCLIZATIONS; KETO ESTER; MILD REACTION CONDITIONS; SYNTHETIC METHODS; TRIFLIC ACIDS;

CARBON; CATALYSIS; CYCLIZATION; ENANTIOSELECTIVITY; FLUORINE; KETONES; NUCLEOPHILES; REGIOSELECTIVITY; SULFUR;

SALTS;

ESTER; FLUORINATED HYDROCARBON; FLUORINE; KETONE; SULFUR; THIOPHENE DERIVATIVE;

ARTICLE; CHEMISTRY; CYCLIZATION; ENANTIOSELECTIVITY; METHYLATION; REGIOSELECTIVITY; STEREOISOMERISM; SYNTHETIC METHODS;

ENANTIOSELECTIVITY; FLUORINE; REGIOSELECTIVITY; SULFUR; SYNTHETIC METHODS;

CYCLIZATION; ESTERS; HYDROCARBONS, FLUORINATED; KETONES; METHYLATION; STEREOISOMERISM; THIOPHENES;

EID: 84893605872     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201309875     Document Type: Article

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