Fabrication of macroporous foam and microspheres of polystyrene by Pickering emulsion polymerization

Colloid and Polymer Science

Volumn 292, Issue 1, 2014, Pages 115-122

  Li, Xiaona ^a   Zhu, Chunli ^a   Wei, Yanze ^a   Lu, Zaijun ^a  

^a SHANDONG UNIVERSITY   (China)

Author keywords

Macroporous polystyrene foam; Pickering emulsions; Polystyrene microspheres

Indexed keywords

EMULSIFICATION; EMULSION POLYMERIZATION; MICROSPHERES; OSTWALD RIPENING; PH; STYRENE;

HIGH INTERNAL PHASE EMULSIONS; MACROPOROUS FOAMS; O/W PICKERING EMULSIONS; PICKERING EMULSION POLYMERIZATIONS; PICKERING EMULSIONS; POLYSTYRENE FOAMS; POLYSTYRENE MICRO-SPHERE; SURFACTANT-FREE EMULSION POLYMERIZATION;

POLYSTYRENES;

EMULSIFYING AGENT; MICROSPHERE; OIL; POLY(STYRENE CO METHACRYLIC ACID); POLYSTYRENE; UNCLASSIFIED DRUG; WATER;

ARTICLE; CONDUCTANCE; EMULSION; FOAM; HYDROPHILICITY; NANOFABRICATION; PH; PHASE SEPARATION; PICKERING EMULSION; POLYMERIZATION; PRIORITY JOURNAL; SYNTHESIS; WETTABILITY;

EID: 84891828875     PISSN: 0303402X     EISSN: 14351536     Source Type: Journal    
DOI: 10.1007/s00396-013-3058-y     Document Type: Article

References (64)

1. Ramsden W (1903) Separation of solids in the surface-layers of solutions and 'Suspensions' (Observations on surface-membranes, bubbles, emulsions, and mechanical coagulation). Preliminary Account. Proc R Soc London 72:156-164
2. Pickering SU (1907) Emulsions. J Chem Soc 91:2001-2021
3. Aveyard R, Binks BP, Clint JH (2003) Emulsions stabilised solely by colloidal particles. Adv Colloid Interface Sci 100:503-546
4. Gu ZZ, Wang D, Möhwald DH (2006) Self-assembly of microspheres at the air/water/air interface into free-standing colloidal crystal films. Soft Matter 3:68-70
5. Binks BP (2002) Particles as surfactants - similarities and differences. Curr Opin Colloid Interface Sci 7:21-41
6. Levine S, Bowen BD, Partridge SJ (1989) Stabilization of emulsions by fine particles: I Partitioning of particles between continuous phase and oil/water interface. Colloids Surf 38:325-343
7. Liu Y, Chen X, Wang R (2006) Polymer microspheres stabilized by titania nanoparticles. Mater Lett 60:3731-3734
8. Amalvy JI, Armes SP, Binks BP (2003) Use of sterically-stabilised polystyrene latex particles as a pH-responsive particulate emulsifier to prepare surfactant-free oil-in-water emulsions. Chem Commun 15:1826-1827
9. Amalvy JI, Unali GF, Li Y (2004) Synthesis of sterically stabilized polystyrene latex particles using cationic block copolymers and macromonomers and their application as stimulus-responsive particulate emulsifiers for oil-in-water emulsions. Langmuir 20:4345-4354
10. Read ES, Fujii S, Amalvy JI, Randall DP, Armes SP (2004) Effect of varying the oil phase on the behavior of pH-responsive latex-based emulsifiers: demulsification versus transitional phase inversion. Langmuir 20:7422-7429
11. Fujii S, Randall DP, Armes SP (2004) Synthesis of polystyrene/poly[2- (dimethylamino) ethyl methacrylate-stat-ethylene glycol dimethacrylate] core-shell latex particles by seeded emulsion polymerization and their application as stimulus-responsive particulate Emulsifiers for oil-in-water Emulsions. Langmuir 20:11329-11335
12. Fujii S, Cai Y, Weaver JVM, Armes SP (2005) Syntheses of shell cross-linked micelles using acidic ABC triblock copolymers and their application as pH-responsive particulate emulsifiers. J Am Chem Soc 127:7304-7305
13. Fujii S, Read ES, Binks BP, Armes SP (2005) Stimulus-responsive emulsifiers based on Nanocomposite microgel particles. Adv Mater 17:1014-1018
14. Binks BP, Rodrigues JA (2005) Inversion of emulsions stabilized solely by ionizable nanoparticles. Angew Chem Int Edit 44:441-444
15. Fujii S, Armes SP (2006) Stimulus-responsive particulate emulsifiers based on lightly cross-linked poly(4-vinylpyridine)-silica nanocomposite microgels. Langmuir 22:6818-6825
16. Ngai T, Auweter H, Behrens SH (2006) Environmental responsiveness of microgel particles and particle-stabilized emulsions. Macromolecules 39:8171-8177
17. Li J, Stöver HD (2008) Doubly pH-responsive Pickering emulsion. Langmuir 24:13237-13240
18. Tsyalkovsky V, Burtovyy R, Klep V, Lupitskyy R, Motornov M, Minko S, Luzinov I (2010) Fluorescent nanoparticles stabilized by poly(ethylene glycol) containing shell for pH-triggered tunable aggregation in aqueous environment. Langmuir 26:10684-10692
19. Richtering W (2012) Responsive emulsions stabilized by stimuli-sensitive microgels: emulsions with special non-Pickering properties. Langmuir 28:17218-17229
20. Morse AJ, Dupin D, Thompson KL, Armes SP, Ouzineb K, Mills P, Swart R (2012) Novel Pickering Emulsifiers based on pH-responsive poly(tert- butylaminoethyl methacrylate) Latexes. J Am Chem Soc 28:1733-11744
21. Mironov MA, Shulepov ID, Ponomarev VS, Bakulev VA (2013) Synthesis of polyampholyte microgels from colloidal salts of pectinic acid and their application as pH-responsive emulsifiers. Colloid Polym Sci 291:1683-1691
22. Binks BP, Murakami R, Armes SP, Fujii S (2005) Temperature-induced inversion of nanoparticle-stabilized emulsions. Angew Chem Int Edit 117:4873-4876
23. Tsuji S, Kawaguchi H (2008) Thermosensitive Pickering emulsion stabilized by poly (N-isopropylacrylamide)-carrying particles. Langmuir 24:3300-3305
24. Ngai T, Behrens SH, Auweter H (2005) Novel emulsions stabilized by pH and temperature sensitive microgels. Chem Comm 3:331-333
25. Binks BP, Murakami R, Armes SP, Fujii S (2006) Effects of pH and salt concentration on oil-in-water emulsions stabilized solely by nanocomposite microgel particles. Langmuir 22:2050-2057
26. Liu X, Yi C, Zhu Y, Yang Y, Jiang J, Cui Z, Jiang M (2010) Pickering emulsions stabilized by self-assembled colloidal particles of copolymers of P(St-alt-MAn)-co-P(VM-alt-MAn). J Colloid Interf Sci 351:315-322
27. Yang F, Liu S, Xu J, Sun D (2006) Pickering emulsions stabilized solely by layered double hydroxides particles: the effect of salt on emulsion formation and stability. J Colloid Interf Sci 302:159-169
28. Melle S, Lask M, Fuller GG (2005) Pickering emulsions with controllable stability. Langmuir 21:2158-2162
29. Velev OD, Furusawa K, Nagayama K (1996) Assembly of latex particles by using emulsion droplets as templates: 1 Microstructured hollow spheres. Langmuir 12:2374-2384
30. He Y (2004) Preparation of polyaniline/nano-ZnO composites via a novel Pickering emulsion route. Powder Technol 147:59-63
31. 2 hybrid microspheres. Macromolecules 38:6411-6417
32. 2 composite microspheres with core-shell structure. Powder Technol 190:393-400
33. Dyab AKF, Al-LohedanHA, Essawy HA, Abd El-Mageed HIA,Taha F (2011) Fabrication of core/shell hybrid organic-inorganic polymer microspheres via Pickering emulsion polymerization using laponite nanoparticles. J Saudi Chem Soc doi: 10.1016/j.jscs.2011.12.008
34. Yin DZ, Du X, Zhang QY, Liu H (2013) Covalently bonded polystyrene/SiO2 microspheres via emulsion polymerisation stabilised solely by surface active Pickering stabiliser. Mater Tech: Adv Perform Mater 28:138-144
35. Dinsmore AD, Hsu MF, Nikolaides MG, Marquez M, Bausch AR, Weitz DA (2002) Colloidosomes: selectively permeable capsules composed of colloidal particles. Science 298:1006-1009
36. Bon SAF, Chen T (2007) Pickering stabilization as a tool in the fabrication of complex nanopatterned silica microcapsules. Langmuir 23:9527-9530
37. Chen W, Liu X, Liu Y, Kim H (2010) Synthesis of microcapsules with polystyrene/ZnO hybrid shell by Pickering emulsion polymerization. Colloid Polym Sci 288:1393-1399
38. Wu CH, Chiu WY, Don TM (2012) Conductive composite particles synthesized via Pickering emulsion polymerization using conductive latex of poly(3,4-ethylenedioxythiophene) (PEDOT) as stabilizer. Polymer 53:1086-1092
39. Vílchez A, Rodríguez-Abreu C, Esquena J, Menner BA (2011) Macroporous polymers obtained in highly concentrated emulsions stabilized solely with magnetic nanoparticles. Langmuir 27:13342-13352
40. Mao D, Li T, Liu H, Shao H, Li M (2013) Preparation of macroporous polyHIPE foams via radiation-induced polymerization at room temperature. Colloid Polym Sci 291:1649-1656
41. Li Z, Ngai T (2009) Macroporous polymer from core-shell particle-stabilized Pickering emulsions. Langmuir 26:5088-5092
42. Ikem VO, Menner A, Bismarck A (2008) High internal phase emulsions stabilized solely by functionalized silica particles. Angew Chem Int Ed 47:8277-8279
43. Ikem VO, Menner A, Horozov TS, Bismarck A (2010) Highly permeable macroporous polymers synthesized from Pickering medium and high internal phase emulsion templates. Adv Mater 22:3588-3592
44. Capron I, Cathala B (2013) Surfactant-free high internal phase emulsions stabilized by cellulose nanocrystals. Biomacromolecules 14:291-296
45. Cauvin S, Colver PJ, Bon SAF (2005) Pickering stabilized miniemulsion polymerization: preparation of clay armored latexes. Macromolecules 38:7887-7889
46. Voorn DJ, Ming W, Van Herk AM (2006) Polymer-clay nanocomposite latex particles by inverse pickering emulsion polymerization stabilized with hydrophobic montmorillonite platelets. Macromolecules 39:2137-2143
47. Fujii S, Okada M, Sawa H, Furuzono T, Nakamura Y (2009) Hydroxyapatite nanoparticles as particulate emulsifier: fabrication of hydroxyapatite-coated biodegradable microspheres. Langmuir 25:9759-9766
48. Duan L, Chen M, Zhou S, Wu L (2009) Synthesis and characterization of poly(N-isopropylacrylamide)/silica composite microspheres via inverse Pickering suspension polymerization. Langmuir 25:3467-3472
49. 2-covered polymer microspheres by Pickering emulsion polymerization. Colloid Surface A 367:70-75
50. Song X, Zhao Y, Wang H, Du Q (2009) Fabrication of polymer microspheres using titania as a photocatalyst and Pickering stabilizer. Langmuir 25:4443-4449
51. Yin G, Zheng Z, Wang H, Du Q (2011) Slightly surface-functionalized polystyrene microspheres prepared via Pickering emulsion polymerization using for electrophoretic displays. J Colloid Interf Sci 361:456-464
52. 3 composite particles and their magnetoresponsive characteristics. Langmuir 29:4959-4965
53. 2 nanocomposites prepared via a Pickering emulsion. J Solid State Electr 17:1435-1447
54. Chen JH, Cheng CY, Chiu WY, Lee CF, Liang NY (2008) Synthesis of ZnO/polystyrene composites particles by Pickering emulsion polymerization. Eur Polym J 44:3271-3279
55. Liu H, Wang C, Zou S, Wei Z, Tong Z (2012) Facile fabrication of polystyrene/halloysite nanotube microspheres with core-shell structure via Pickering suspension polymerization. Polym Bull 69:765-777
56. Song X, Yang Y, Liu J, Zhao H (2010) PS colloidal particles stabilized by graphene oxide. Langmuir 27:1186-1191
57. Yin G, Zheng Z, Wang H, Du Q, Zhang H (2013) Preparation of graphene oxide coated polystyrene microspheres by Pickering emulsion polymerization. J Colloid Interf Sci 394:192-198
58. Menner A, Powell R, Bismarck A (2006) Open porous polymer foams via inverse emulsion polymerization: should the definition of high internal phase (ratio) emulsions be extended? Macromolecules 39:2034-2035
59. Yuan Q, Yang L, Wang M, Wang H, Ge X, Ge X (2009) The mechanism of the formation of multihollow polymer spheres through sulfonated polystyrene particles. Langmuir 25:2729-2735
60. Li T, Liu H, Zeng L, Miao W, Wu Y (2011) Study of emulsion polymerization stabilized by amphiphilic polymer nanoparticles. Colloid Polym Sci 289:1543-1551
61. Binks BP, Rodrigues (2005) Inversion of emulsions stabilized solely by ionizable nanoparticles. Angew Chem Int Edit 44:441-444
62. Sun GQ, Li ZF, Ngai T (2010) Inversion of particle-stabilized emulsions to form high-internal-phase emulsions. Angew Chem Int Edit 49:2163-2166
63. Colver PJ, Bon SAF (2007) Cellular polymer monoliths made via Pickering high internal phase emulsions. Chem Mater 19:1537-1539
64. Whitby CP, Lotte L, Lang C (2012) Structure of concentrated oil-in-water Pickering emulsions. Soft Matter 8:7784-7789