Pickering emulsion polymerization: Preparation of polystyrene/nano-SiO2 composite microspheres with core-shell structure

Powder Technology

Volumn 190, Issue 3, 2009, Pages 393-400

  Zhang, K ^a   Wu, W ^a   Meng, H ^a   Guo, K ^a   Chen, J F ^a  

^a BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY   (China)

Author keywords

Composites; Nano SiO2; Pickering emulsion; Polystyrene

Indexed keywords

COMPOSITE MICROSPHERES; COMPOSITES; CORE-SHELL STRUCTURES; DOUBLE BONDS; FOURIER TRANSFORMATION INFRARED SPECTRUM; NANO-SIO2; PARTICLE CONCENTRATIONS; PARTICLE DISPERSIONS; PH-VALUES; PICKERING EMULSION; POLYSTYRENE; SCANNING ELECTRONS; SEM; SYNTHETIC CONDITIONS; TEM; TRANSMISSION ELECTRONS; X-RAY PHOTOELECTRON SPECTROSCOPIES;

AUGER ELECTRON SPECTROSCOPY; CARBON FIBER REINFORCED PLASTICS; ELECTRON MICROSCOPY; EMULSIFICATION; EMULSION POLYMERIZATION; FOURIER ANALYSIS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; FOURIER TRANSFORMS; GRAVIMETRIC ANALYSIS; INFRARED SPECTROSCOPY; MICROSPHERES; PHOTOELECTRON SPECTROSCOPY; POLYMERIZATION; POLYMERS; POLYSTYRENES; SCANNING ELECTRON MICROSCOPY; SILANES; SILICON COMPOUNDS; SPECTRUM ANALYSIS; THERMOGRAVIMETRIC ANALYSIS; TRANSMISSION ELECTRON MICROSCOPY;

X RAY PHOTOELECTRON SPECTROSCOPY;

EID: 60249098383     PISSN: 00325910     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.powtec.2008.08.022     Document Type: Article

References (29)

1. 2/PMMA nanocomposites. Langmuir 21 (2005) 6048-6053
2. Lee J., Hong C.K., Choe S., and Shima S.E. Synthesis of polystyrene/silica composite particles by soap-free emulsion polymerization using positively charged colloidal silica. J. Colloid Interface Sci. 310 (2007) 112-120
3. Wang T., Wang M., Zhang Z., Ge X., and Fang Y. Preparation of core (PBA/layered silicate)-shell (PS) structured complex via γ-ray radiation seeded emulsion polymerization. Mater. Lett. (2006) 2544-2548
4. 2 particles via blending method. Colloids Surf. A: Physicochem. Eng. Aspects 259 (2005) 63-69
5. Pickering S. Emulsions. J. Chem. Soc. 91 (1907) 2001-2021
6. Binks B.P., and Lumsdon S.O. Influence of particle wettability on the type and stability of surfactant-free emulsions. Langmuir 16 (2000) 8622-8631
7. Sullivan A.P., and Kilpatrick P.K. The effects of inorganic solid particles on water and crude oil emulsion stability. Ind. Eng. Chem. Res. 41 (2002) 3389-3404
8. Kahn J.G., Schmitt V., Binks B.P., and Calderon F.L. A new method to prepare monodisperse pickering emulsions. Langmuir 18 (2002) 2515-2518
9. S.A.F. Bon, S. Cauvin, P.J. Colver, Colloidosomes as micron-sized polymerisation vessels to create supracolloidal interpenetrating polymer network reinforced capsules, Soft Matter 3 (2007) 194-199.
10. Bon S.A.F., and Chen T. Pickering stabilization as a tool in the fabrication of complex nanopatterned silica microcapsules. Langmuir 23 (2007) 9527-9530
11. Shen S.L., Wu W., Guo K., Meng H., and Chen J.F. A novel process to synthesize magnetic hollow silica microspheres. Colloids Surf. A: Physicochem. Eng. Aspects 311 (2007) 99-105
12. Binks B.P., and Lumsdon S.O. Transitional phase inversion of solid-stabilized emulsions using particle mixtures. Langmuir 16 (2000) 3748-3756
13. Binks B.P., and Lumsdon S.O. Catastrophic phase inversion of water-in-oil emulsions stabilized by hydrophobic silica. Langmuir 16 (2000) 2539-2547
14. Binks B.P., Philip J., and Rodrigues J.A. Inversion of silica-stabilized emulsions induced by particle concentration. Langmuir 21 (2005) 3296-3302
15. Binks B.P., and Fletcher P.D.I. Particles adsorbed at the oil-water interface: A theoretical comparison between spheres of uniform wettability and "Janus" particles. Langmuir 17 (2001) 4708-4710
16. Binks B.P., and Lumsdon S.O. Pickering emulsions stabilized by monodisperse latex particles: Effects of particle size. Langmuir 17 (2001) 4540-4547
17. Binks B.P., and Rodrigues J.A. Types of phase inversion of silica particle stabilized emulsions containing triglyceride oil. Langmuir 19 (2003) 4905-4912
18. Tiarks F., Landfester K., and Antonietti M. Silica nanoparticles as surfactants and fillers for latexes made by miniemulsion polymerization. Langmuir 17 (2001) 5775-5780
19. Bon S.A.F., and Colver P.J. Pickering miniemulsion polymerization using laponite clay as a stabilizer. Langmuir 23 (2007) 8316-8322
20. Voorn D.J., Ming W., and van Herk A.M. Polymer-clay nanocomposite latex particles by inverse pickering emulsion polymerization stabilized with hydrophobic montmorillonite platelets. Macromolecules 39 (2006) 2137-2143
21. He Y. Preparation of polyaniline/nano-ZnO composites via a novel Pickering emulsion route. Powder Technol. 147 (2004) 59-63
22. Levine S., Bowen B.D., and Partridge S.J. Stabilization of emulsions by fine particles. I. Partitioning of particles between continuous phase and oil/water interface. Colloids Surf. A 38 (1989) 325-343
23. Yang F., Niu Q., Lan Q., and Sun D. Effect of dispersion pH on the formation and stability of Pickering emulsions stabilized by layered double hydroxides particles. J. Colloid Interface Sci. 306 (2007) 285-295
24. 2 and its structure and tribological properties. Appl. Surf. Sci. 252 (2006) 7856-7861
25. Deng Z., Chen M., Gu G., and Wu L. A facile method to fabricate ZnO hollow spheres and their photocatalytic property. J. Phys. Chem. B 112 (2008) 16-22
26. Deng Z., Chen M., Zhou S., You B., and Wu L. A novel method for the fabrication of monodisperse hollow silica spheres. Langmuir 22 (2006) 6403-6407
27. Cheng X., Chen M., Wu L., and Gu G. Novel and facile method for the preparation of monodispersed titania hollow spheres. Langmuir 22 (2006) 3858-3863
28. Ma G., and Li J. Compromise between dominant polymerization mechanisms in preparation of polymer microspheres. Chem. Eng. Sci. 59 (2004) 1711-1721
29. Reincke F., Hickey S.G., Kegel W.K., and Vanmaekelbergh D. Spontaneous assembly of a monolayer of charged gold nanocrystals at the water/oil interface. Angew. Chem. Int. Ed. 43 (2004) 458-462