Unusual 14-electron fragments [Pd(η3-Bi3-xPb x)](x+1)- as pseudo lead atoms in closo-[Pd@Pd 2Pb10Bi6]4-

Angewandte Chemie - International Edition

Volumn 52, Issue 51, 2013, Pages 13544-13548

  Ababei, Rodica ^a   Massa, Werner ^a   Harms, Klaus ^a   Xie, Xiulan ^a   Weigend, Florian ^b   Dehnen, Stefanie ^a  

^a PHILIPPS UNIVERSITY MARBURG   (Germany)

^b KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

Author keywords

207Pb NMR spectroscopy; intermetalloid clusters; isolobal analogy; perturbational treatment; X ray diffraction

Indexed keywords

ELECTRON NUMBER; INTERMETALLOID CLUSTERS; ISOLOBAL ANALOGY; LEAD ATOM; PERTURBATIONAL TREATMENT; WADE-MINGOS RULES;

LEAD; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; X RAY DIFFRACTION;

PALLADIUM COMPOUNDS;

EID: 84890543579     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201307795     Document Type: Article

References (81)

1. J. D. Corbett, Angew. Chem. 2000, 112, 682
2. Angew. Chem. Int. Ed. 2000, 39, 670
3. T. F. Fässler, S. D. Hoffmann, Angew. Chem. 2004, 116, 6400
4. Angew. Chem. Int. Ed. 2004, 43, 6242
5. S. C. Sevov, J. M. Goicoechea, Organometallics 2006, 25, 5678
6. S. Scharfe, F. Kraus, S. Stegmaier, T. F. Fässler, Angew. Chem. 2011, 123, 3712
7. Angew. Chem. Int. Ed. 2011, 50, 3630
8. T. F. Fässler, Zintl Ions, Principles and Recent Developments, Springer, Berlin, 2011, p. 91.
9. M. J. Moses, J. C. Fettinger, B. W. Eichhorn, Science 2003, 300, 778.
10. S. Stegmaier, T. F. Fässler, J. Am. Chem. Soc. 2011, 133, 19758.
11. J. M. Goicoechea, M. W. Hull, S. C. Sevov, J. Am. Chem. Soc. 2007, 129, 7885.
12. B. Zhou, M. S. Denning, L. D. Kays, J. M. Goicoechea, J. Am. Chem. Soc. 2009, 131, 2802
13. J.-Q. Wang, S. Stegmaier, T. F. Fässler, Angew. Chem. 2009, 121, 2032
14. Angew. Chem. Int. Ed. 2009, 48, 1998.
15. F. Li, A. Munos-Castro, S. C. Sevov, Angew. Chem. 2012, 124, 8709
16. Angew. Chem. Int. Ed. 2012, 51, 8581.
17. T. F. Fässler, Coord. Chem. Rev. 2001, 215, 347.
18. H.-G. von Schnering, W. Hönle, Chem. Rev. 1988, 88, 243.
19. L. Xu, S. Bobev, J. El-Bahraoui, S. C. Sevov, J. Am. Chem. Soc. 2000, 122, 1838.
20. M. Waibel, F. Kraus, S. Scharfe, B. Wahl, T. F. Fässler, Angew. Chem. 2010, 122, 6761
21. Angew. Chem. Int. Ed. 2010, 49, 6611
22. M. Waibel, T. Henneberger, L.-A. Jantke, T. F. Fässler, Chem. Commun. 2012, 48, 8676
23. S. Stegmaier, M. Waibel, A. Henze, L.-A. Jantke, A. J. Karttunen, T. F. Fässler, J. Am. Chem. Soc. 2012, 134, 14450.
24. F. Lips, I. Schellenberg, R. Pöttgen, S. Dehnen, Chem. Eur. J. 2009, 15, 12968.
25. S. C. Critchlow, J. D. Corbett, Inorg. Chem. 1982, 21, 3286
26. F. Lips, M. Raupach, W. Massa, S. Dehnen, Z. Anorg. Allg. Chem. 2011, 637, 859
27. U. Friedrich, M. Neumeier, C. Koch, N. Korber, Chem. Commun. 2012, 48, 10544.
28. L. Xu, S. C. Sevov, Inorg. Chem. 2000, 39, 5383.
29. F. Lips, S. Dehnen, Angew. Chem. 2009, 121, 6557
30. Angew. Chem. Int. Ed. 2009, 48, 6435.
31. F. Lips, S. Dehnen, Angew. Chem. 2011, 123, 986
32. Angew. Chem. Int. Ed. 2011, 50, 955.
33. F. Lips, R. Clérac, S. Dehnen, Angew. Chem. 2011, 123, 991
34. Angew. Chem. Int. Ed. 2011, 50, 960
35. F. Lips, M. Hołyńska, R. Clérac, U. Linne, I. Schellenberg, R. Pöttgen, F. Weigend, S. Dehnen, J. Am. Chem. Soc. 2012, 134, 1181.
36. F. Lips, R. Clérac, S. Dehnen, J. Am. Chem. Soc. 2011, 133, 14168.
37. B. Weinert, F. Weigend, S. Dehnen, Chem. Eur. J. 2012, 18, 13589.
38. R. Ababei, J. Heine, M. Hołyńska, G. Thiele, B. Weinert, X. Xie, F. Weigend, S. Dehnen, Chem. Commun. 2012, 48, 11295.
39. F. Weigend, C. Schrodt, R. Ahlrichs, J. Chem. Phys. 2004, 121, 10380
40. F. Weigend, C. Schrodt, Chem. Eur. J. 2005, 11, 3559.
41. A. D. Becke, Phys. Rev. A 1988, 38, 3098
42. J. P. Perdew, Phys. Rev. B 1986, 33, 8822.
43. F. Weigend, A. Baldes, J. Chem. Phys. 2010, 133, 174102.
44. A. Klamt, G. J. Schürmann, Chem. Soc. Perkin Trans. 1 1993, 5, 799.
45. TURBOMOLE V6.4 2012, a development of University of Karlsruhe and Forschungszentrum Karlsruhe GmbH, 1989-2007, TURBOMOLE GmbH, since 2007; available from http://www.turbomole.com.
46. J.-Q. Wang, S. Stegmaier, B. Wahl, T. F. Fässler, Chem. Eur. J. 2010, 16, 1793
47. E. N. Esenturk, J. Fettinger, B. Eichhorn, J. Am. Chem. Soc. 2006, 128, 9178
48. E. N. Esenturk, J. Fettinger, Y.-F. Lam, B. Eichhorn, Angew. Chem. 2004, 116, 2184
49. Angew. Chem. Int. Ed. 2004, 43, 2132.
50. K. Wade, Adv. Inorg. Chem. Radiochem. 1976, 18, 1
51. D. M. P. Mingos, Nature Phys. Sci. 1972, 236, 99
52. D. M. P. Mingos, Acc. Chem. Res. 1984, 17, 311.
53. J. M. Goicoechea, S. C. Sevov, Angew. Chem. 2006, 118, 5271
54. Angew. Chem. Int. Ed. 2006, 45, 5147
55. B. Wahl, L. Kloo, M. Ruck, Angew. Chem. 2008, 120, 3996
56. Angew. Chem. Int. Ed. 2008, 47, 3932.
57. L. Yong, S. D. Hoffman, T. F. Fässler, Eur. J. Inorg. Chem. 2005, 3663
58. J. Campbell, H. P. A. Mercier, H. Franke, D. P. Santry, D. A. Dixon, G. J. Schrobilgen, Inorg. Chem. 2002, 41, 86
59. B. W. Eichhorn, R. C. Haushalter, J. Chem. Soc. Chem. Commun. 1990, 937.
60. E. N. Esenturk, J. Fettinger, B. Eichhorn, Chem. Commun. 2005, 247
61. S. Scharfe, T. F. Fässler, S. Stegmaier, S. D. Hoffmann, K. Ruhland, Chem. Eur. J. 2008, 14, 4479.
62. N. Kuznetsov, T. F. Fässler, Z. Anorg. Chem. 2002, 628, 2537
63. A. Cisar, J. D. Corbett, Inorg. Chem. 1977, 16, 2482.
64. M. Ruck, V. Dubenskyy, T. Söhnel, Angew. Chem. 2003, 115, 3086
65. Angew. Chem. Int. Ed. 2003, 42, 2978
66. V. Dubenskyy, M. Ruck, Z. Anorg. Allg. Chem. 2004, 630, 2458
67. B. Wahl, M. Erbe, A. Gerisch, L. Kloo, M. Ruck, Z. Anorg. Chem. 2009, 635, 743.
68. J. M. Goicoechea, S. C. Sevov, J. Am. Chem. Soc. 2005, 127, 7676.
69. J. M. Goicoechea, S. C. Sevov, Angew. Chem. 2005, 117, 4094
70. Angew. Chem. Int. Ed. 2005, 44, 4026.
71. R. M. Friedman, J. D. Corbett, Inorg. Chem. 1973, 12, 1134
72. H. von Benda, A. Simon, W. Bauhofer, Z. Anorg. Allg. Chem. 1978, 438, 53
73. M. Ruck, Z. Anorg. Allg. Chem. 1998, 624, 521.
74. R. F. W. Bader, Acc. Chem. Res. 1985, 18, 9.
75. G. M. Sheldrick, Acta Crystallogr. Sect. A 2008, 64, 112.
76. B. Metz, H. Stoll, M. Dolg, J. Chem. Phys. 2000, 113, 2563
77. K. A. Peterson, D. Figgen, M. Dolg, H. Stoll, J. Chem. Phys. 2007, 126, 124101.
78. F. Weigend, Phys. Chem. Chem. Phys. 2006, 8, 1057.
79. M. K. Armbruster, F. Weigend, C. van Wüllen, W. Klopper, Phys. Chem. Chem. Phys. 2008, 10, 1748
80. A. Baldes, F. Weigend, Mol. Phys. 2013, DOI:.
81. J. Rodriguez, A. Köster, P. W. Ayers, A. Santo-Valle, A. Vela, G. Merino, J. Comput. Chem. 2008, 29, 1082.