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ESI-MS investigations that were performed at earlier states of the reaction indicate different relative amounts of the detectable fragments and further fragments to appear. We ascribe these findings to complicated equilibria that appear during the reaction. Therefore, comprehensive analyses on the formation process are currently being undertaken using ESI mass spectrometry in combination with theoretical studies; these will be subject of another publication dedicated exclusively to this point.
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It was not possible to assign all of the observed peaks to reasonable species, as some of them contain fragments of solvent and/or cryptand molecules along with cluster atoms; however, the isotopic pattern enables the assignment of the number of Sn atoms, indicating two Sn atoms for the highest paek at m/z 916.9034, for example
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It was not possible to assign all of the observed peaks to reasonable species, as some of them contain fragments of solvent and/or cryptand molecules along with cluster atoms; however, the isotopic pattern enables the assignment of the number of Sn atoms, indicating two Sn atoms for the highest paek at m/z 916.9034, for example.
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[2.2.2]crypt: 4,7,13,16,21,24-Hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane
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