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Volumn 50, Issue 4, 2011, Pages 955-959

Neither electron-precise nor in accordance with wade-mingos rules: The ternary cluster anion [Ni2Sn7Bi5]3-

Author keywords

density functional calculations; intermetalloid clusters; mass spectrometry; structure elucidation; Zintl anions

Indexed keywords

CLUSTER ANIONS; DENSITY-FUNCTIONAL CALCULATIONS; DFT CALCULATION; ENDOHEDRALS; INTERMETALLOID CLUSTERS; METAL ATOMS; STRUCTURE ELUCIDATION; WADE-MINGOS RULES; ZINTL ANIONS;

EID: 78751528877     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201005496     Document Type: Article
Times cited : (52)

References (66)
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    • note
    • ESI-MS investigations that were performed at earlier states of the reaction indicate different relative amounts of the detectable fragments and further fragments to appear. We ascribe these findings to complicated equilibria that appear during the reaction. Therefore, comprehensive analyses on the formation process are currently being undertaken using ESI mass spectrometry in combination with theoretical studies; these will be subject of another publication dedicated exclusively to this point.
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    • It was not possible to assign all of the observed peaks to reasonable species, as some of them contain fragments of solvent and/or cryptand molecules along with cluster atoms; however, the isotopic pattern enables the assignment of the number of Sn atoms, indicating two Sn atoms for the highest paek at m/z 916.9034, for example
    • It was not possible to assign all of the observed peaks to reasonable species, as some of them contain fragments of solvent and/or cryptand molecules along with cluster atoms; however, the isotopic pattern enables the assignment of the number of Sn atoms, indicating two Sn atoms for the highest paek at m/z 916.9034, for example.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.