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Volumn 48, Issue 35, 2009, Pages 6435-6438

[Zn6Sn3Bi8]4-: Expanding the intermetalloid zintl anion concept to ternary systems

Author keywords

Cluster compounds; Density functional calculations; Structure elucidation; X ray diffraction; Zintl anions

Indexed keywords

CLUSTER COMPOUNDS; DENSITY FUNCTIONAL CALCULATIONS; DFT CALCULATION; STRUCTURE ELUCIDATION; TERNARY COMPOSITION; X RAY STRUCTURE ANALYSIS; ZINTL ANIONS;

EID: 70349932072     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200902249     Document Type: Article
Times cited : (64)

References (75)
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    • [2.2.2]crypt: 4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexaeosane
    • [2.2.2]crypt: 4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexaeosane.
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    • note
    • 2 (ail data) = 0.1451, GooF (ail data) = 1.112, max peak/hole 2.09/-1.11. For more details, see the Supporting Information. CCDC 733155 (1) and 733156 (2) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data- request/cif.
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    • [27b] that reveals that 69 % of all s and p electrons at the five external Bi atoms (Bi2-Bi6) do not contribute to the cluster bonding, which corresponds to between three (60%) and four (80%) of five electrons per Bi atom.
    • [27b] that reveals that 69 % of all s and p electrons at the five external Bi atoms (Bi2-Bi6) do not contribute to the cluster bonding, which corresponds to between three (60%) and four (80%) of five electrons per Bi atom.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.