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0343609011
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note
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Crypt = 4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane.
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26
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0342303966
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note
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- drich) and crypt (Kryptofix 222, 98%, Acros) were used as received, and the toluene (99.5+%, Fisher) was dried and kept over sodium. All operations of the dissolution and crystallization were performed in a helium-filled glovebox.
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note
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2-, i.e., 1 × 1 + 3 × 3 + 2 = 12.
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32
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0343173517
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note
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2) were handled with the SHELXTL V5.1 package. The data were corrected for absorption using a lamina model with the aid of seven ψ-scans at different θ-angles (min/max transmission = 0.1699/0.7360). Qualitative microprobe elemental analysis (energy-dispersive X-ray analysis for elements heavier than oxygen) performed on the same crystal showed Bi and K only.
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(b) Allen, F. H.; Kennard, O.; Watson, D. G.; Brammer, L.; Orpen, A. G.; Taylor, R. J. Chem. Soc., Perkin Trans. II 1987, S1.
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0003438540
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Cornell University Press: New York
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n are the lengths of bonds with bond order l and n, respectively, and C ≈ 0.6. The length of a single Bi-Bi bond according to Pauling is 3.02 Å, and therefore n = 2.01 for a distance of 2.8377 Å.
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0343979470
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note
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The magnetization of more than 30 mg of 1 sealed in a quartz lube was measured at a filed of 3 T over the range 4-290 K on a Quantum Design MPMS SQUID magnetometer. It showed diamagnetic, temperature-independent behavior. For the EPR measurements a few large crystals of 1 were ground to fine powder that was then sealed in a quartz tube, and later the same powder was redissolved in ethylenediamine, placed in a tube, and measured again. Spectra were recorded at 8, 80, 120, and 295 K. There was no signal from either the solid or the solution.
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41
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0001527554
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