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Volumn 16, Issue 6, 2010, Pages 1793-1798

Step-by-step synthesis of the endohedral stannaspherene [Ir@Sn 12]3- via the capped cluster anion [Sn9Ir(cod)] 3-

Author keywords

Cluster compounds; Intermetalloids; Polyhedrons; Synthesis design; Zintl anions

Indexed keywords

CLUSTER ANIONS; CLUSTER COMPOUNDS; ELEVATED TEMPERATURE; ENDOHEDRALS; ETHYLENEDIAMINE (EN); INTERMEDIATE PRODUCT; ION CLUSTER; METAL ATOMS; POINT SYMMETRY; SINGLE-CRYSTAL STRUCTURE; SPHERICAL CLUSTERS; STEP-BY-STEP; SYNTHESIS DESIGN; TRIPHENYL PHOSPHINES;

EID: 75749156175     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200902815     Document Type: Article
Times cited : (112)

References (107)
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    • note
    • Selected bond lengths [Å] and angles [̊]: Ir(1)-C(1) 2.16(1), Ir(1)C(2) 2.132(9), Ir(1)-C(5) 2.167(8), Ir(l)-C(6) 2.155(9), Ir(l)-Sn(6) 2.7772(6), Ir(l)-Sn(7) 2.7605(7), Ir(I)-Sn(8) 2.7700(7), Ir(l)-Sn(9) 2.7637(6), Sn(l)-Sn(2) 2.9530(9), Sn(2)-Sn(3) 3.2035(9), Sn(3)Sn(4) 3.1185(8), Sn(5)-Sn(6) 3.0068(8), Sn(6)-Sn(7) 3.0591(8), Sn(7)-Sn(8) 3.1012(8), Sn(8)-Sn(9) 3.1129(8); C(l)-Ir(l)-C(2) 37.8(3), C(5)-Ir(l)-C(6) 38.5(4), Sn(7)-Ir(I)-Sn(8) 68.22(2), Sn(7)Ir(l)-Sn(9) 103.26(2), Sn(8)-Ir(l)-Sn(9) 68.46(2).
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    • Selected bond lengths [A] and angles [°]: Ir(1)-Sn(1) 2.9414(5), Ir(l)-Sn(2) 2.9229(6), Ir(l)-Sn(3) 2.8828(5), Ir(l)-Sn(4) 2.9363(6), Ir(l)-Sn(5) 2.9356(5), Ir(l)-Sn(6) 2.9115(6), Sn(l)-Sn(2) 3.1004(9), Sn(l)-Sn(3) 3.0429(7), Sn(l)-Sn(4) 3.0715(9), Sn(l)-Sn(5) 3.0636(8), Sn(l)-Sn(6) 3.0658(8), Sn(2)-Sn(3) 3.0609(9), Sn(2)Sn(6) 3.0250(8), Sn(3)-Sn(4) 3.0632(9), Sn(4)-Sn(5) 3.0596(8), Sn(5)-Sn(6) 3.0954(9); Sn(3)-Ir(l)-Sn(2) 63.63(2), Sn(2)-Ir(l)-Sn(6) 62.46(2), Sn(2)-Ir(l)-Sn(l) 63.83(2), Sn(6)-Ir(l)-Sn(l) 63.17(2), Sn(3)-Sn(l)-Sn(2) 59.76(2), Sn(6)-Sn(l)-Sn(2) 58.76(2), Sn(2)-Sn(3)Sn(4) 109.23(2), Sn(6)-Sn(2)-Sn(3) 107.25(3)
    • Selected bond lengths [A] and angles [°]: Ir(1)-Sn(1) 2.9414(5), Ir(l)-Sn(2) 2.9229(6), Ir(l)-Sn(3) 2.8828(5), Ir(l)-Sn(4) 2.9363(6), Ir(l)-Sn(5) 2.9356(5), Ir(l)-Sn(6) 2.9115(6), Sn(l)-Sn(2) 3.1004(9), Sn(l)-Sn(3) 3.0429(7), Sn(l)-Sn(4) 3.0715(9), Sn(l)-Sn(5) 3.0636(8), Sn(l)-Sn(6) 3.0658(8), Sn(2)-Sn(3) 3.0609(9), Sn(2)Sn(6) 3.0250(8), Sn(3)-Sn(4) 3.0632(9), Sn(4)-Sn(5) 3.0596(8), Sn(5)-Sn(6) 3.0954(9); Sn(3)-Ir(l)-Sn(2) 63.63(2), Sn(2)-Ir(l)-Sn(6) 62.46(2), Sn(2)-Ir(l)-Sn(l) 63.83(2), Sn(6)-Ir(l)-Sn(l) 63.17(2), Sn(3)-Sn(l)-Sn(2) 59.76(2), Sn(6)-Sn(l)-Sn(2) 58.76(2), Sn(2)-Sn(3)Sn(4) 109.23(2), Sn(6)-Sn(2)-Sn(3) 107.25(3).
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