Bismuth polyanions in solution: Synthesis and structural characterization of (2,2,2-crypt-A)2Bi4 (A = K, Rb) and the formation of the laves phases ABi2 (A = K, Rb, Cs) from solution

Zeitschrift fur Anorganische und Allgemeine Chemie

Volumn 628, Issue 11, 2002, Pages 2537-2541

  Kuznetsov, Alexei N ^a   Fässler, Thomas F ^a,b  

^a MOSCOW STATE UNIVERSITY   (Russian Federation)

^b DARMSTADT UNIVERSITY OF TECHNOLOGY   (Germany)

Author keywords

Bismuth polyanions; Clusters; Crystal structure; Laves phases; Zintl ions

Indexed keywords

ALKALI METAL; BISMUTH; CATION; ETHYLENEDIAMINE; N,N DIMETHYLFORMAMIDE; POLYANION;

ARTICLE; CHEMICAL ANALYSIS; CRYSTAL; DISSOLUTION; ISOLATION PROCEDURE; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0036034049     PISSN: 00442313     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3749(200211)628:11<2537::AID-ZAAC2537>3.0.CO;2-A     Document Type: Article

References (30)

1. B. Krebs, M. Mummert, C. J. Brendel, J. Less-Common Met. 1986, 116, 159.
2. S. Ulvenlund, K. Ståhl, L. Bengtsson-Kloo, Inorg. Chem. 1996, 35, 223.
3. B. Krebs, M. Hucke, C. J. Brendel, Angew. Chem. Int. Ed. Engl. 1982, 21, 445.
4. J. Beck, C. J. Brendel, L. Bengtsson-Kloo, B. Krebs, M. Mummert, A. Stankowski, S. Ulvenlund, Chem. Ber. 1996, 129, 1219.
5. A. Hershaft, J. D. Corbett, Inorg. Chem. 1963, 2, 979.
6. R. M. Friedman, J. D. Corbett, Inorg. Chem. 1973, 12, 1134.
7. A. N. Kuznetsov, A. V. Shevelkov, S. I. Trojanov, B. A. Popovkin, Russ. J. of Inorg. Chem. 1996, 41, 920. Translated from Zh. Neorg. Khim. 1996, 41, 958.
8. A. N. Kuznetsov, A. V. Shevelkov, S. I. Trojanov, B. A. Popovkin, Russ. J. of Inorg. Chem. 1996, 41, 920. Translated from Zh. Neorg. Khim. 1996, 41, 958.
9. A. N. Kuznetsov, A. V. Shevelkov, B. A. Popovkin, Russ. J. of Coord. Chem. 1998, 24, 861. Translated from Koord. Khim. 1998, 24, 919.
10. A. N. Kuznetsov, A. V. Shevelkov, B. A. Popovkin, Russ. J. of Coord. Chem. 1998, 24, 861. Translated from Koord. Khim. 1998, 24, 919.
11. H. Benda, A. Simon, W. Bauhofer, Z. Anorg. Allg. Chem. 1978, 438, 53.
12. M. Ruck, Z. Anorg. Allg. Chem. 1998, 624, 521.
13. N. J. Bjerrum, R. C. Boston, G. P. Smith, Inorg. Chem. 1967, 6,1162.
14. N. J. Bjerrum, G. P. Smith, Inorg. Chem. 1967, 6, 1968.
15. S. Ulvenlund, A. Wheatley, L. A. Bengtsson, J. Chem. Soc., Chem. Commun. 1995, 59.
16. A. N. Kuznetsov, B. A. Popovkin, W. Henderson, M. J. Taylor, L. Bengtsson-Kloo J. Chem. Soc., Dalton Trans. 2000, 1777.
17. A. Cisar, J. D. Corbett, Inorg. Chem. 1977, 16, 2482.
18. R. P. Elliott, Constitution of Binary Alloys, First Supplement, McGraw-Hill, New York, N. Y., 1965, 185.
19. F. Gascoin, S. C. Sevov, Inorg. Chem. 2001, 40, 5177.
20. F. Gascoin, S. C. Sevov, J. Am. Chem. Soc.2000, 122, 10251.
21. L. Xu, S. Bobev, J. El-Bahraoui, S. C. Sevov, J. Am. Chem. Soc. 2000, 122, 1838.
22. E. Zintl, J. Goubeau, W. Dullenkopf, Z. Phys. Chem., Abt. A 1931, 154, 1.
23. E. Zintl, W. Dullenkopf, Z. Phys. Chem., Abt. B 1932, 16, 183.
24. L. Xu, A. Ugrinov, S. C. Sevov, J. Am. Chem. Soc. 2001, 123, 4091.
25. S. C. Critchlow, J. D. Corbett, Inorg. Chem. 1984, 23, 770.
26. N. Korber, M. Reil, J. Chem Soc., Chem. Commun. 2002, 84.
27. W. van der Lugt, in Chemistry, Structure, and Bonding of Zintl Phases and Ions (Ed.: S. M. Kauzlarich), VCH Publishers, Inc., Weinheim, 1996, 183.
28. 2,2,2-crypt=4,7,13,16,21,24,-hexaoxa- 1,10-diazabicyclo[8.8.8]hexacosane.
29. 18-crown-6=1,4,7,10,13,16-hexaoxacyclooctadecane.
30. G. M. Sheldrick, SHELX-97, Program package for crystal structure solution and refinement, Univ. Göttingen 1997.