Silver(I)-catalyzed reaction between pyrazole and propargyl acetates: Stereoselective synthesis of the scorpionate ligands (E)-allyl-gem-dipyrazoles (ADPs)

Journal of Organic Chemistry

Volumn 78, Issue 23, 2013, Pages 11824-11834

  Bhanuchandra, M ^a   Kuram, Malleswara Rao ^a   Sahoo, Akhila K ^a  

^a UNIVERSITY OF HYDERABAD   (India)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYZED REACTIONS; CROSS-COUPLINGS; PROPARGYL ACETATES; PROTECTING GROUP; REACTION CONDITIONS; SCORPIONATE LIGAND; STEREOSELECTIVE SYNTHESIS; SUZUKI-MIYAURA;

PALLADIUM COMPOUNDS; SILVER COMPOUNDS; STEREOCHEMISTRY; STEREOSELECTIVITY;

LIGANDS;

1 [ 3 (4 FLUOROPHENYL)PROP 1 ENE 1,3 DIYL]BIS(1H PYRAZOLE); 1 PHENYL 2 ( 1H PYRAZOL 1 YL)ALLYL ACETATE; 1' ( 3 P TOLYLPROP 1 ENE 1,3 DIYL)BIS(1H PYRAZOLE); 1' ( 3 PHENYLPROP 2 ENE 1,1 DIYL)BIS( 1H PYRAZOLE); 1' (3 PHENYLPROP 1 ENE 1,3 DIYL)BIS(1H PYRAZOLE); 1' [ 3 ( 3 METHOXYPHENYL)PROP 1 ENE 1,3 DIYL]BIS(1H PYRAZOLE); 1' [ 3 ( 3 METHOXYPHENYL)PROP 2 ENE 1,1 DIYL]BIS(1H PYRAZOLE); 1' [ 3 ( 3 PHENOXYPHENYL)PROP 1 ENE 1,3 DIYL]BIS(1H PYRAZOLE); 1' [ 3 ( 3 PHENOXYPHENYL)PROP 2 ENE 1,1 DIYL]BIS(1H PYRAZOLE); 1' [ 3 ( 4 CHLOROPHENYL)PROP 1 ENE 1,3 DIYL]BIS(1H PYRAZOLE); 1' [ 3 ( 4 CHLOROPHENYL)PROP 2 ENE 1,1 DIYL]BIS(1H PYRAZOLE); 1' [ 3 ( 4 FLUOROPHENYL)PROP 2 ENE 1,1 DIYL]BIS(1H PYRAZOLE); 1' [ 3 P TOLYLPROP 2 ENE 1,1 DIYL]BIS(1H PYRAZOLE); ACETIC ACID DERIVATIVE; ALLYL GEM DIPYRAZOLE; ANTIINFLAMMATORY AGENT; CHLOROBENZENE; PALLADIUM COMPLEX; PROPARGYL ACETATE; PYRAZOLE DERIVATIVE; SILVER; UNCLASSIFIED DRUG;

ANTIINFLAMMATORY ACTIVITY; ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; DRUG SYNTHESIS; FLUORINE NUCLEAR MAGNETIC RESONANCE; GAS CHROMATOGRAPHY; LIQUID CHROMATOGRAPHY; MASS SPECTROMETRY; PROTON NUCLEAR MAGNETIC RESONANCE; SUZUKI REACTION; X RAY CRYSTALLOGRAPHY;

ACETATES; ALKYNES; CATALYSIS; LIGANDS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; PYRAZOLES; SILVER; STEREOISOMERISM;

EID: 84890188514     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo401867e     Document Type: Article

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