Highly enantioselective dearomatizing formal [3+3] cycloaddition reactions of N-acyliminopyridinium ylides with electrophilic enol carbene intermediates

Angewandte Chemie - International Edition

Volumn 52, Issue 48, 2013, Pages 12664-12668

  Xu, Xinfang ^a   Zavalij, Peter Y ^a   Doyle, Michael P ^a  

^a Bldg 142   (United States)

Author keywords

asymmetric catalysis; cycloaddition; diazo compounds; enantioselectivity; heterocycles

Indexed keywords

ASYMMETRIC CATALYSIS; CARBENES; CYCLOADDITION REACTION; DIAZO COMPOUNDS; DINITROGEN; ENANTIOSELECTIVE; HETEROCYCLES; HIGH YIELD;

CYCLOADDITION; ENANTIOSELECTIVITY; METAL EXTRUSION;

ORGANIC COMPOUNDS;

CARBENE; DIAZONIUM COMPOUND; DRUG DERIVATIVE; IMINE; METHANE; PYRIDAZINE DERIVATIVE; PYRIDINIUM DERIVATIVE;

ACYLATION; ARTICLE; ASYMMETRIC CATALYSIS; CATALYSIS; CHEMISTRY; CYCLOADDITION; DIAZO COMPOUNDS; ENANTIOSELECTIVITY; HETEROCYCLES; STEREOISOMERISM; SYNTHESIS;

ASYMMETRIC CATALYSIS; CYCLOADDITION; DIAZO COMPOUNDS; ENANTIOSELECTIVITY; HETEROCYCLES;

ACYLATION; CATALYSIS; CYCLOADDITION REACTION; DIAZONIUM COMPOUNDS; IMINES; METHANE; PYRIDAZINES; PYRIDINIUM COMPOUNDS; STEREOISOMERISM;

EID: 84887882521     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201305539     Document Type: Article

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