Emulsions stabilized with solid nanoparticles: Pickering emulsions

Colloids and Surfaces A: Physicochemical and Engineering Aspects

Volumn 439, Issue , 2013, Pages 23-34

  Chevalier, Yves ^a   Bolzinger, Marie Alexandrine ^a  

^a UNIVERSITÉ LYON 1   (France)

Author keywords

Drug delivery; Emulsions; Nanomaterials; Pickering emulsions; Solid nanoparticles

Indexed keywords

DRUG DELIVERY; EMULSIFICATION; EMULSIONS; NANOSTRUCTURED MATERIALS; PHYSICAL CHEMISTRY;

DROPLET SIZES; PICKERING EMULSIONS; SOLID NANOPARTICLES; TIME GAP;

NANOPARTICLES;

CAFFEINE; CHEMICAL COMPOUND; EMULSIFYING AGENT; LATEX; NANOCRYSTAL; NANOPARTICLE; POLYMER; RETINOL; SILICON DIOXIDE; SOLID NANOPARTICLE; STABILIZING AGENT; UNCLASSIFIED DRUG;

ADSORPTION; ARTICLE; DRUG DELIVERY SYSTEM; FLOW KINETICS; NANOEMULSION; PHYSICAL CHEMISTRY; PICKERING EMULSION; POLYMERIZATION; PRIORITY JOURNAL; SKIN ABSORPTION; STRATUM CORNEUM; SURFACE PROPERTY;

EID: 84887015812     PISSN: 09277757     EISSN: 18734359     Source Type: Journal    
DOI: 10.1016/j.colsurfa.2013.02.054     Document Type: Article

References (156)

1. Aveyard R., Binks B.P., Clint J.H. Emulsions stabilized solely by solid colloidal particles. Adv. Colloid Interface Sci. 2003, 100-102:503-546.
2. Binks B.P. Particles as surfactants-similarities and differences. Curr. Opin. Colloid Interface Sci. 2002, 7:21-41.
3. Binks B.P., Horozov T.S. Colloidal Particles at Liquid Interfaces 2006, Cambridge University Press.
4. Pickering S.U. Emulsions. J. Chem. Soc. 1907, 91:2001-2021.
5. Ramsden W. Separation of solids in the surface-layers of solutions and 'suspensions'. Proc. Royal Soc. London 1903, 72:156-164.
6. Newman F.R. Experiments on emulsions. J. Phys. Chem. 1914, 18:34-54.
7. Schlaepffer A.U.M. Water-in-oil emulsions. J. Chem. Soc. 1918, 113:522-526.
8. Moore W.C. Emulsification of water and of ammonium chloride solutions by means of lamp black. J. Am. Chem. Soc. 1919, 41:940-946.
9. Briggs T.R. Ind. Eng. Chem. 1921, 13:1008-1010.
10. Finkle P., Draper H.D., Hildebrand J.H. The theory of emulsification. J. Am. Chem. Soc. 1923, 45:2780-2788.
11. Scarlett A.J., Morgan W.L., Hildebrand J.H. Emulsification by solid powders. J. Phys. Chem. 1927, 31:1566-1571.
12. 4). Trans. Faraday Soc. 1954, 50:598-605.
13. Wiley R.M. Limited coalescence of oil droplets in coarse oil-in-water emulsions. J. Colloid Sci. 1954, 9:427-437.
14. Lucassen-Reynders E.H., van den Tempel M. Stabilization of water-in-oil emulsions by solid particles. J. Phys. Chem. 1963, 67:731-734.
15. Levine S., Sanford E. Stabilisation of emulsion droplets by fine powders. Can. J. Chem. Eng. 1985, 62:258-268.
16. Levine S., Bowen B.D., Partridge S.J. Stabilization of emulsions by fine particles I. Partitioning of particles between continuous phase and oil/water interface. Colloids Surf. 1989, 38:325-343.
17. Tambe D.E., Sharma M.M. Factors controlling the stability of colloid-stabilized emulsions. I. An experimental investigation. J. Colloid Interface Sci. 1993, 157:244-253.
18. Tambe D.E., Sharma M.M. The effect of colloidal particles on fluid-fluid interfacial properties and emulsion stability. Adv. Colloid Interface Sci. 1994, 52:1-63.
19. Tadros T.F., Vincent B. Encyclopedia of Emulsion Technology 1983, 1:129-285.
20. Richard D., Quéré D. Drops rolling on a tilted non-wettable solid. Europhys. Lett. 1999, 48:286-291.
21. Aussillous P., Quéré D. Liquid marbles. Nature 2001, 411:924-927.
22. Binks B.P., Murakami R. Phase inversion of particle-stabilized materials from foam to dry water. Nat. Mater. 2006, 5:865-869.
23. Degussa, Every day - everywhere, Press release n°1, 15 April 2004.
24. Rousseau D. Fat crystals and emulsion stability - a review. Food Res. Int. 2000, 33:3-14.
25. Wang J., Yang X. Synthesis of core-corona polymer hybrids with a raspberry-like structure by the heterocoagulated pyridinium reaction. Langmuir 2008, 24:3358-3364.
26. van der Waarden M. Stability of emulsions of water in mineral oils containing asphaltenes. Kolloid-Z. 1957, 156:116-122.
27. Schorling P.-C., Kessel D.G., Rahimian I. Influence of the crude oil resin/asphaltene ratio on the stability of oil/water emulsions. Colloids Surf., A 1999, 152:95-102.
28. Spiecker P.M., Gawrys K.L., Trail C.B., Kilpatrick P.K. Effects of petroleum resins on asphaltene aggregation and water-in-oil emulsion formation. Colloids Surf., A 2003, 220:9-27.
29. Menon V.B., Wasan D.T. Coalescence of water-in-shale oil emulsions. Sep. Sci. Technol. 1984, 19:555-574.
30. Eley D.D., Hey M.J., Lee M.A. Rheological studies of asphaltene films adsorbed at the oil/water interface. Colloids Surf. 1987, 24:173-182.
31. Eley D.D., Hey M.J., Symonds J.D. Emulsions of water in asphaltene-containing oils. 1. Droplet size distribution and emulsification rates. Colloids Surf. 1988, 32:87-101.
32. Eley D.D., Hey M.J., Symonds J.D. Emulsions of water in asphaltene-containing oils. 2. Rheology. Colloids Surf. 1988, 32:103-112.
33. E.J. Johansen, I.M. Sklärvö, T. Lund, J. Sjoblom, H. Söderlund, G. Boström, Water-in-crude oil emulsions from the Norwegian continental shelf Part I. Formation, characterization and stability correlations, Colloids Surf. 34 (1988/89) 353-370.
34. Neumann H.-J., Paczynska-Lahme B. Stability and demulsification of petroleum emulsions. Prog. Colloid Polym. Sci. 1997, 101:101-104.
35. Dickinson E. Food emulsions and foams: stabilization by particles. Curr. Opin. Colloid Interface Sci. 2010, 15:40-49.
36. Binks B.P., Lumsdon S.O. Influence of particle wettability on the type and stability of surfactant-free emulsions. Langmuir 2000, 16:8622-8631.
37. Vignati E., Piazza R., Lockhart T.P. Pickering emulsions: interfacial tension, colloidal layer morphology, and trapped-particle motion. Langmuir 2003, 19:6650-6656.
38. Dong L., Johnson D. Surface tension of charge-stabilized colloidal suspensions at the water-air interface. Langmuir 2003, 19:10205-10209.
39. Abend S., Lagaly G. Bentonites and double hydroxides as emulsifying agents. Clay Miner. 2001, 36:557-570.
40. Ashby N.P., Binks B.P. Pickering emulsions stabilised by Laponite clay particles. Phys. Chem. Chem. Phys. 2000, 2:5640-5646.
41. Gelot A., Friesen W., Hamza H.A. Emulsification of oil and water in the presence of finely divided solids and surface-active agents. Colloids Surf. 1984, 12:271-303.
42. Binks B.P., Lumsdon S.O. Pickering emulsions stabilized by monodisperse latex particles: effects of particle size. Langmuir 2001, 17:4540-4547.
43. Dinsmore A.D., Hsu M.F., Nikolaides M.G., Marquez M., Bausch A.R., Weitz D.A. Colloidosomes: selectively permeable capsules composed of colloidal particles. Science 2002, 298:1006-1009.
44. Amalvy J.I., Armes S.P., Binks B.P., Rodrigues J.A., Unali G.-F. Use of sterically-stabilised polystyrene latex particles as a pH-responsive particulate emulsifier to prepare surfactant-free oil-in-water emulsions. Chem. Commun. 2003, 1826-1827.
45. Amalvy J.I., Unali G.-F., Li Y., Granger-Bevan S., Armes S.P., Binks B.P., Rodrigues J.A., Whitby C.P. Synthesis of sterically stabilized polystyrene latex particles using cationic block copolymers and macromonomers and their application as stimulus-responsive particulate emulsifiers for oil-in-water emulsions. Langmuir 2004, 20:4345-4354.
46. Gautier F., Destribats M., Perrier-Cornet R., Dechézelles J.-F., Giermanska J., Héroguez V., Ravaine S., Leal-Calderon F., Schmitt V. Pickering emulsions with stimulable particles: from highly- to weakly-covered interfaces. Phys. Chem. Chem. Phys. 2007, 9:6455-6462.
47. Melle S., Lask M., Fuller G.G. Pickering emulsions with controllable stability. Langmuir 2005, 21:2158-2162.
48. 4 nanoparticles. Colloids Surf., A 2012, 412:20-28.
49. Wang H., Hobbie E.K. Amphiphobic carbon nanotubes as macroemulsion surfactants. Langmuir 2003, 19:3091-3093.
50. Laredj-Bourezg F., Chevalier Y., Boyron O., Bolzinger M.-A. Emulsions stabilized with solid organic particles. Colloids Surf., A 2012, 413:252-259.
51. Schelero N., Lichtenfeld H., Zastrow H., Möhwald H., Dubois M., Zemb T. Single particle light scattering method for studying aging properties of Pickering emulsions stabilized by catanionic crystals. Colloids Surf., A 2009, 337:146-153.
52. Binks B.P., Clint J.H., Mackenzie G., Simcock C., Whitby C.P. Naturally occurring spore particles at planar fluid interfaces and in emulsions. Langmuir 2005, 21:8161-8167.
53. Dorobantu L.S., Yeung A.K.C., Foght J.M., Gray M.R. Stabilization of oil-water emulsions by hydrophobic bacteria. Appl. Environ. Microbiol. 2004, 70:6333-6336.
54. Wongkongkatep P., Manopwisedjaroen K., Tiposoth P., Archakunakorn S., Pongtharangkul T., Suphantharika M., Honda K., Hamachi I., Wongkongkatep J. Bacteria interface Pickering emulsions stabilized by self-assembled bacteria-chitosan network. Langmuir 2012, 28:5729-5736.
55. Ngai T., Behrens S.H., Auweter H. Novel emulsions stabilized by pH and temperature sensitive microgels. Chem. Commun. 2005, 331-333.
56. Bruggerand B., Richtering W. Magnetic, thermosensitive microgels as stimuli-responsive emulsifiers allowing for remote control of separability and stability of oil in water-emulsions. Adv. Mater. 2007, 19:2973-2978.
57. Tsuji S., Kawaguchi H. Thermosensitive Pickering emulsion stabilized by poly(N-isopropylacrylamide)-carrying particles. Langmuir 2008, 24:3300-3305.
58. Monteux C., Marlière C., Paris P., Pantoustier N., Sanson N., Perrin P. Poly(N-isopropylacrylamide) microgels at the oil-water interface: interfacial properties as a function of temperature. Langmuir 2010, 26:13839-13846.
59. Destribats M., Lapeyre V., Sellier E., Leal-Calderon F., Ravaine V., Schmitt V. Origin and control of adhesion between emulsion drops stabilised by thermally-sensitive soft colloidal particles. Langmuir 2012, 28:3744-3755.
60. Fujii S., Read E.S., Binks B.P., Armes S.P. Stimulus-responsive emulsifiers based on nanocomposite microgel particles. Adv. Mater. 2005, 17:1014-1018.
61. Gautier F., Destribats M., Perrier-Cornet R., Dechézelles J.F., Giermanska J., Héroguez V., Ravaine S., Leal-Calderon F., Schmitt V. Pickering emulsions with stimulable particles: from highly- to weakly-covered interfaces. Phys. Chem. Chem. Phys. 2007, 9:6455-6462.
62. Fujii S., Aichi A., Muraoka M., Kishimoto N., Iwahori K., Nakamura Y., Yamashita I. Ferritin as a bionano-particulate emulsifier. J. Colloid Interface Sci. 2009, 338:222-228.
63. van Rijn P., Mougin N.C., Franke D., Park H., Böker A. Pickering emulsion templated soft capsules by self-assembling cross-linkable ferritin-polymer conjugates. Chem. Commun. 2011, 47:8376-8378.
64. Hassander H., Johansson B., Törnell B. The mechanism of emulsion stabilization by small silica (Ludox) particles. Colloids Surf. 1989, 40:93-105.
65. Binks B.P., Whitby C.P. Nanoparticle silica-stabilised oil-in-water emulsions: improving emulsion stability. Colloids Surf., A 2005, 253:105-115.
66. Drelich A., Gomez F., Clausse D., Pezron I. Evolution of water-in-oil emulsions stabilized with solid particles: influence of added emulsifier. Colloids Surf., A 2010, 365:171-177.
67. Midmore B.R. Synergy between silica and polyoxyethylene surfactants in the formation of O/W emulsions. Colloids Surf., A 1998, 145:133-143.
68. Binks B.P., Rodrigues J.A., Frith W.J. Synergistic interaction in emulsions stabilized by a mixture of silica nanoparticles and cationic surfactant. Langmuir 2007, 23:3626-3636.
69. Binks B.P., Rodrigues J.A. Enhanced stabilization of emulsions due to surfactant-induced nanoparticle flocculation. Langmuir 2007, 23:7436-7439.
70. Ghouchi Eskandar N., Simovic S., Prestidge C.A. Synergistic effect of silica nanoparticles and charged surfactants in the formation and stability of submicron oil-in-water emulsions. Phys. Chem. Chem. Phys. 2007, 9:6426-6434.
71. Ghouchi Eskandar N., Simovic S., Prestidge C.A. Interactions of hydrophilic silica nanoparticles and classical surfactants at non-polar oil-water interface. J. Colloid Interface Sci. 2011, 358:217-225.
72. Tan A., Simovic S., Davey A.K., Rades T., Prestidge C.A. Silica-lipid hybrid (SLH) microcapsules: a novel oral delivery system for poorly soluble drugs. J. Control. Release 2009, 134:62-70.
73. Cui Y., Threlfall M., van Duijneveldt J.S. Optimizing organoclay stabilized Pickering emulsions. J. Colloid Interface Sci. 2011, 356:665-671.
74. Akartuna I., Tervoort E., Studart A.R., Gauckler L.J. General route for the assembly of functional inorganic capsules. Langmuir 2009, 25:12419-12424.
75. Midmore B.R. Preparation of a novel silica-stabilized oil/water emulsion. Colloids Surf., A 1998, 132:257-265.
76. Midmore B.R. Effect of aqueous phase composition on the properties of a silica-stabilized W/O emulsion. J. Colloid Interface Sci. 1999, 213:352-359.
77. Binks B.P., Lumsdon S.O. Stability of oil-in-water emulsions stabilised by silica particles. Phys. Chem. Chem. Phys. 1999, 1:3007-3016.
78. Barthel H. Surface interactions of dimethylsiloxy group-modified fumed silica. Colloids Surf., A 1995, 101:217-226.
79. Ulrich G.D., Riehl J.W. Aggregation and growth of submicron oxide particles in flames. J. Colloid Interface Sci. 1982, 87:257-265.
80. Stiller S., Gers-Barlag H., Lergenmueller M., Pflücker F., Schulz J., Wittern K.P., Daniels R. Investigation of the stability in emulsions stabilized with different surface modified titanium dioxides. Colloids Surf., A 2004, 232:261-267.
81. Frelichowska J., Bolzinger M.-A., Chevalier Y. Pickering emulsions with bare silica. Colloids Surf., A 2009, 343:70-74.
82. Leunissen M.E., van Blaaderen A., Hollingsworth A.D., Sullivan M.T., Chaikin P.M. Electrostatics at the oil-water interface, stability, and order in emulsions and colloids. Proc. Natl. Acad. Sci. U.S.A. 2007, 104:2585-2590.
83. Wang H., Singh V., Behrens S.H. Image charge effects on the formation of Pickering emulsions. J. Phys. Chem. Lett. 2012, 3:2986-2990.
84. Abend S., Bonnke N., Gutschner U., Lagaly G. Stabilization of emulsions by heterocoagulation of clay minerals and layered double hydroxides. Colloid. Polym. Sci. 1998, 276:730-737.
85. Thieme J., Abend S., Lagaly G. Aggregation in Pickering emulsions. Colloid. Polym. Sci. 1999, 277:257-260.
86. Neuhäusler U., Abend S., Jacobsen C., Lagaly G. Soft X-ray spectromicroscopy on solid-stabilized emulsions. Colloid. Polym. Sci. 1999, 277:719-726.
87. Arditty S., Whitby C.P., Binks B.P., Schmitt V., Leal-Calderon F. Some general features of limited coalescence in solid-stabilized emulsions. Eur. Phys. J. E 2003, 11:273-281.
88. Frelichowska J., Bolzinger M.-A., Chevalier Y. Effects of solid particle content on properties of o/w Pickering emulsions. J. Colloid Interface Sci. 2010, 351:348-356.
89. Arditty S., Schmitt V., Giermanska-Kahn J., Leal-Calderon F. Materials based on solid-stabilized emulsion. J. Colloid Interface Sci. 2004, 275:659-664.
90. Arditty S., Schmitt V., Lequeux F., Leal-Calderon F. Interfacial properties in solid-stabilized emulsions. Eur. Phys. J. E 2005, 44:381-393.
91. Binks B.P., Kirkland M. Interfacial structure of solid-stabilised emulsions studied by scanning electron microscopy. Phys. Chem. Chem. Phys. 2002, 4:3727-3733.
92. Horozov T.S., Binks B.P. Particle-stabilized emulsions: a bilayer or a bridging monolayer?. Angew. Chem. Int. Ed. 2006, 45:773-776.
93. Destribats M., Ravaine S., Heroguez V., Leal-Calderon F., Schmitt V. Outstanding stability of poorly-protected Pickering emulsions. Prog. Colloid Polym. Sci. 2010, 137:13-18.
94. Binks B.P., Whitby C.P. Silica particle-stabilized emulsions of silicone oil and water: aspects of emulsification. Langmuir 2004, 20:1130-1137.
95. Zhai X., Efrima S. Chemical and physical aspects of macroemulsions stabilized by interfacial colloids. J. Phys. Chem. 1996, 100:11019-11028.
96. Avendaño Juárez J., Whitby C.P. Oil-in-water Pickering emulsion destabilisation at low particle concentrations. J. Colloid Interface Sci. 2012, 368:319-325.
97. Kruglyakov P.M. Hydrophile-Lipophile Balance of Surfactants and Solid Particles. Physicochemical Aspects and Applications 2000, Elsevier, Amsterdam.
98. Kruglyakov P.M., Nushtayeva A.V. Phase inversion in emulsions stabilised by solid particles. Adv. Colloid Interface Sci. 2004, 108-109:151-158.
99. Binks B.P., Lumsdon S.O. Catastrophic phase inversion of water-in-oil emulsions stabilized by hydrophobic silica. Langmuir 2000, 16:2539-2547.
100. Binks B.P., Rodrigues J.A. Types of phase inversion of silica particle stabilized emulsions containing triglyceride oil. Langmuir 2003, 19:4905-4912.
101. Binks B.P., Lumsdon S.O. Effects of oil type and aqueous phase composition on oil-water mixtures containing particles of intermediate hydrophobicity. Phys. Chem. Chem. Phys. 2000, 2:2959-2967.
102. H. Barthel, B.P. Binks, A. Dyab, P. Fletcher, Multiple emulsions, Patent EP1350556 B1, US2003/0175317 A1 (2003).
103. Lee M.N., Chan H.K., Mohraz A. Characteristics of Pickering emulsion gels formed by droplet bridging. Langmuir 2012, 28:3085-3091.
104. Horozov T.S., Binks B.P., Gottschalk-Gaudig T. Effect of electrolyte in silicone oil-in-water emulsions stabilised by fumed silica particles. Phys. Chem. Chem. Phys. 2007, 9:6398-6404.
105. Whitby C.P., Fischer F.E., Fornasiero D., Ralston J. Shear-induced coalescence of oil-in-water Pickering emulsions. J. Colloid Interface Sci. 2011, 361:170-177.
106. Fenouillot F., Cassagnau P., Majesté J.-C. Uneven distribution of nanoparticles in immiscible fluids: morphology development in polymer blends. Polymer 2009, 50:1333-1350.
107. Elias L., Fenouillot F., Majesté J.-C., Cassagnau P. Morphology and rheology of immiscible polymer blends filled with silica nanoparticles. Polymer 2007, 48:6029-6040.
108. Elias L., Fenouillot F., Majesté J.-C., Martin G., Cassagnau P. Migration of nanosilica particles in polymer blends. J. Polym. Sci.: Part B: Polym. Phys. 2008, 46:1976-1983.
109. Elias L., Fenouillot F., Majesté J.-C., Alcouffe P., Cassagnau P. Immiscible polymer blends stabilized with nano-silica particles: rheology and effective interfacial tension. Polymer 2008, 49:4378-4385.
110. Simovic S., Prestidge C.A. Nanoparticle encapsulation of emulsion droplets. Int. J. Pharm. 2006, 324:92-100.
111. Simovic S., Prestidge C.A. Nanoparticle layers controlling drug release from emulsions. Eur. J. Pharm. Biopharm. 2007, 67:39-47.
112. Simovic S., Hui H., Song Y., Davey A.K., Rades T., Prestidge C.A. An oral delivery system for indomethicin engineered from cationic lipid emulsions and silica nanoparticles. J. Control. Release 2010, 143:367-373.
113. Fujii S., Okada M., Sawa H., Furuzono T., Nakamura Y. Hydroxyapatite nanoparticles as particulate emulsifier: fabrication of hydroxyapatite-coated biodegradable microspheres. Langmuir 2009, 25:9759-9766.
114. Maeda H., Okada M., Fujii S., Nakamura Y., Furuzono T. Pickering-type water-in-oil-in-water multiple emulsions toward multihollow nanocomposite microspheres. Langmuir 2010, 26:13727-13731.
115. Fujii S., Okada M., Nishimura T., Maeda H., Sugimoto T., Hamasaki H., Furuzono T., Nakamura Y. Hydroxyapatite-armored poly(e-caprolactone) microspheres and hydroxyapatite microcapsules fabricated via a Pickering emulsion route. J. Colloid Interface Sci. 2012, 374:1-8.
116. Aranberri I., Binks B.P., Clint J.H., Fletcher P.D.I. Synthesis of macroporous silica from solid-stabilised emulsion templates. J. Porous Mater. 2009, 16:429-437.
117. Simovic S., Heard P., Prestidge C.A. Hybrid lipid-silica microcapsules engineered by phase coacervation of Pickering emulsions to enhance lipid hydrolysis. Phys. Chem. Chem. Phys. 2010, 12:7162-7170.
118. Simovic S., Heard P., Hui H., Song Y., Peddie F., Davey A.K., Lewis A., Rades T., Prestidge C.A. Dry hybrid lipid-silica microcapsules engineered from submicron lipid droplets and nanoparticles as a novel delivery system for poorly soluble drugs. Mol. Pharm. 2009, 6:861-872.
119. Frelichowska J., Bolzinger M.-A., Valour J.-P., Mouaziz H., Pelletier J., Chevalier Y. Pickering w/o emulsions: drug release and topical delivery. Int. J. Pharm. 2009, 368:7-15.
120. Ghouchi Eskandar N., Simovic S., Prestidge C.A. Mechanistic insight into the dermal delivery from nanoparticle-coated submicron o/w emulsions. J. Pharm. Sci. 2010, 99:890-904.
121. Marku D., Wahlgren M., Rayner M., Sjöö M., Timgren A. Characterization of starch Pickering emulsions for potential applications in topical formulations. Int. J. Pharm. 2012, 428:1-7.
122. Frelichowska J., Bolzinger M.-A., Pelletier J., Valour J.-P., Chevalier Y. Topical delivery of lipophilic drugs from o/w Pickering emulsions. Int. J. Pharm. 2009, 371:56-63.
123. Ghouchi Eskandar N., Simovic S., Prestidge C.A. Nanoparticle coated submicron emulsions: sustained in-vitro release and improved dermal delivery of all-trans-retinol. Pharm. Res. 2009, 26:1764-1775.
124. Simovic S., Ghouchi-Eskandar N., Prestidge C.A. Pickering emulsions for dermal delivery. J. Drug Deliv. Sci. Technol. 2011, 21:123-133.
125. Ghouchi Eskandar N., Simovic S., Prestidge C.A. Chemical stability and phase distribution of all-trans-retinol in nanoparticle coated emulsions. Int. J. Pharm. 2009, 376:186-194.
126. Kalashnikova I., Bizot H., Cathala B., Capron I. New Pickering emulsions stabilized by bacterial cellulose nanocrystals. Langmuir 2011, 27:7471-7479.
127. Kalashnikova I., Bizot H., Cathala B., Capron I. Modulation of cellulose nanocrystals amphiphilic properties to stabilize oil/water interface. Biomacromolecules 2012, 13:267-275.
128. Tzoumakia M.V., Moschakis T., Kiosseoglou V., Biliaderis C.G. Oil-in-water emulsions stabilized by chitin nanocrystal particles. Food Hydrocoll. 2011, 25:1521-1529.
129. Arditty S., Schmitt V., Giermanska-Kahn J., Leal-Calderon F. Materials based on solid-stabilized emulsions. J. Colloid Interface Sci. 2004, 275:659-664.
130. Leal-Calderon F., Schmitt V. Solid-stabilized emulsions. Curr. Opin. Colloid Interface Sci. 2008, 13:217-227.
131. Negrete-Herrera N., Letoffe J.-M., Putaux J.-L., David L., Bourgeat-Lami E. Aqueous dispersions of silane-functionalized laponite clay platelets. A first step toward the elaboration of water-based polymer/clay nanocomposites. Langmuir 2004, 20:1564-1571.
132. Negrete-Herrera N., Putaux J.-L., David L., Bourgeat-Lami E. Polymer/laponite composite colloids through emulsion polymerization: influence of the clay modification level on particle morphology. Macromolecules 2006, 39:9177-9184.
133. Sheibat-Othman N., Bourgeat-Lami E. Use of silica particles for the formation of organic-inorganic particles by surfactant-free emulsion polymerization. Langmuir 2009, 25:10121-10133.
134. 2-stabilized Pickering emulsion polymerization. Adv. Mater. 2007, 19:2286-2289.
135. Schmid A., Armes S.P., Leite C.A.P., Galembeck F. Efficient preparation of polystyrene/silica colloidal nanocomposite particles by emulsion polymerization using a glycerol-functionalized silica sol. Langmuir 2009, 25:2486-2494.
136. Song X., Zhao Y., Wang H., Du Q. Fabrication of polymer microspheres using titania as a photocatalyst and Pickering stabilizer. Langmuir 2009, 25:4443-4449.
137. Teixeira R.F.A., McKenzie H.S., Boyd A.A., Bon S.A.F. Pickering emulsion polymerization using laponite clay as stabilizer to prepare armored "soft" polymer latexes. Macromolecules 2011, 44:7415-7422.
138. Voorn D.J., Ming W., van Herk A.M. Polymer-clay nanocomposite latex particles by inverse Pickering emulsion polymerization stabilized with hydrophobic montmorillonite platelets. Macromolecules 2006, 39:2137-2143.
139. Zhang K., Wu W., Guo K., Chen J., Zhang P. Synthesis of temperature-responsive poly(N-isopropyl acrylamide)/poly(methyl methacrylate)/silica hybrid capsules from inverse Pickering emulsion polymerization and their application in controlled drug release. Langmuir 2010, 26:7971-7980.
140. Tiarks F., Landfester K., Antonietti M. Silica nanoparticles as surfactants and fillers for latexes made by miniemulsion polymerization. Langmuir 2001, 17:5775-5780.
141. Cauvin S., Colver P.J., Bon S.A.F. Pickering stabilized miniemulsion polymerization: preparation of clay armored latexes. Macromolecules 2005, 38:7887-7889.
142. Zhang M., Gao G., Li C.-Q., Liu F.-Q. Titania-coated polystyrene hybrid microballs prepared with miniemulsion polymerization. Langmuir 2004, 20:1420-1424.
143. 2/polystyrene nanocomposite particles via miniemulsion polymerization. Langmuir 2005, 21:2124-2128.
144. Bon S.A.F., Colver P.J. Pickering miniemulsion polymerization using laponite clay as a stabilizer. Langmuir 2007, 23:8316-8322.
145. Beck J.S., Vartuli J.C., Roth W.J., Leonowicz M.E., Kresge C.T., Schmitt K.D., Chu C.T-W., Olson D.H., Sheppard E.W., McCullen S.B., Higgins J.B., Schlenkert J.L. A new family of mesoporous molecular sieves prepared with liquid crystal templates. J. Am. Chem. Soc. 1992, 114:10834-10843.
146. Barg S., Binks B.P., Wang H., Koch D., Grathwohl G. Cellular ceramics from emulsified suspensions of mixed particles. J. Porous Mater. 2012, 19:859-867.
147. 4 ceramics based on particle-stabilized foams. J. Porous Mater. 2012, 19:883-888.
148. Neirinck B., Fransaer J., Van der Biest O., Vleugels J. A novel route to produce porous ceramics. J. Eur. Ceram. Soc. 2009, 29:833-836.
149. Menner A., Verdejo R., Shaffer M., Bismarck A. Particle-stabilized surfactant-free medium internal phase emulsions as templates for porous nanocomposite materials: poly-Pickering-foams. Langmuir 2007, 23:2398-2403.
150. Colver P.J., Bon S.A.F. Cellular polymer monoliths made via Pickering high internal phase emulsions. Chem. Mater. 2007, 19:1537-1539.
151. Menner A., Ikem V., Salgueiro M., Shaffer M.S.P., Bismarck A. High internal phase emulsion templates solely stabilised by functionalised titania nanoparticles. Chem. Commun. 2007, 4274-4276.
152. Ikem V.O., Menner A., Bismarck A. High internal phase emulsions stabilized solely by functionalized silica particles. Angew. Chem. Int. Ed. 2008, 47:8277-8279.
153. Ikem V.O., Menner A., Horozov T.S., Bismarck A. Highly permeable macroporous polymers synthesized from Pickering medium and high internal phase emulsion templates. Adv. Mater. 2010, 22:3588-3592.
154. Ikem V.O., Menner A., Bismarck A. Tailoring the mechanical performance of highly permeable macroporous polymers synthesized via Pickering emulsion templating. Soft Matter 2011, 7:6571-6577.
155. Destribats M., Faure B., Birot M., Babot O., Schmitt V., Backov R. Tailored silica macrocellular foams: combining limited coalescence-based Pickering emulsion and sol-gel process. Adv. Funct. Mater. 2012, 22:2642-2654.
156. Simovic S., Heard P., Prestidge C.A. Hybrid lipid-silica microcapsules engineered by phase coacervation of Pickering emulsions to enhance lipid hydrolysis. Phys. Chem. Chem. Phys. 2010, 12:7162-7170.