Electrochemical Sensors: Fundamentals, Key Materials, and Applications

Solid State Electrochemistry I: Fundamentals, Materials and their Applications

Volumn , Issue , 2009, Pages 427-491

  Fergus, Jeffrey W ^a  

^a AUBURN UNIVERSITY   (United States)

Author keywords

Amperometric sensors; Gas sensors; High temperature sensors; Mixed potential sensors; Molten metal sensors; Potentiometric sensors; Solid electrolytes

Indexed keywords

EID: 84881280898     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1002/9783527627868.ch13     Document Type: Chapter

References (450)

1. Kiukkola, K. and Wagner, C. (1957) Measurements of galvanic cells involving solid electrolytes. J. Electrochem. Soc., 104 (6), 379-87.
2. Radhakrishnan, R., Virkar, A.V., Singhal, S.C., Dunham, G.C. and Marina, O.A. (2005) Design, fabrication and characterization of a miniaturized seriesconnected potentiometric oxygen sensor. Sens. Actuators B, 105 (2), 312-21.
3. Dubbe, A. (2003) Fundamentals of solid state ionic micro gas sensors. Sens. Actuators B, 88 ,138-48.
4. Azad, A.-M., Akbar, S., Mhaisalkar, S.G., Birkefeld, L.D. and Goto, K.S. (1992) Solid-state gas sensors: A review. J. Electrochem. Soc., 139 (12), 3690-704.
5. Yamazoe, N. and Miura, N. (1994) Environmental gas sensing. Sens. Actuators B, 20 ,95-102.
6. Mukundan, R. and Garzon, F. (2004) Electrochemical sensors for energy and transportation. Electrochem. Soc. Interface, 13 (2), 30-5.
7. Moos, R. (2005) A brief overview on automotive exhaust gas sensors based on electroceramics. Int. J. Appl. Ceram. Tech., 2 (5), 401-13.
8. Akbar, S., Dutta, P. and Lee, C. (2006) High-temperature ceramic gas sensors: A review. Int. J. Appl. Ceram. Technol., 3 (4), 302-11.
9. Ivers-Tiffee, E., Hardtl, K.H., Menesklou, W. and Riegel, J. (2001) Principles of solid state oxygen sensors for lean combustion gas control. Electrochim. Acta, 47 (5), 807-14.
10. Lundstróm, I. (1996) Approaches and mechanisms to solid state based sensing. Sens. Actuators B, 35, (1-3)11-9.
11. Lee, D.-D. and Lee, D.-S. (2001) Environmental gas sensors. IEEE Sensors J., 1 (3), 214-24.
12. Takeuchi, T. (1988) Oxygen sensors. Sens. Actuators B, 14 (2), 109-24.
13. Weppner, W. (1987) Solid-state electrochemical gas sensors. Sens. Actuators 12 ,107-19.
14. Weppner, W. (1992) Advanced principles of sensors based on solid state ionics. Mater. Sci. Eng., B15, 48-55.
15. Park, C.O., Akbar, S.A. and Weppner, W. (2003) Ceramic electrolytes and electrochemical sensors. J.Mater. Sci., 38 ,4639-60.
16. Zhuiykov, S. and Miura, N. (2005) Solidstate electrochemical gas sensors for emission control, in Materials for Energy Conversion Devices (eds C.C. Sorrell, S. Sugihara and J. Nowotny), Woodhead Publ. Ltd, Cambridge, UK, pp. 303-35.
17. Park, C.O. and Akbar, S.A. (2003) Ceramics for chemical sensors. J. Mater. Sci., 38 ,4611-37.
18. Yamazoe, N. and Miura, N. (1998) Potentiometric gas sensors for oxidic gases. J. Electroceram., 2 (4), 243-55.
19. Jacob, K.T., Swaminathan, K. and Sreedharan, O.M. (1989) Stability constraints in the design of galvanic cells using composite electrolytes and auxiliary electrodes. Solid State. Ionics, 34 ,167-73.
20. Miura, N., Lu, G. and Yamazoe, N. (2000) Progress in mixed-potential type devices based on solid electrolyte for sensing redox gases. Solid State Ionics, 136-7, 533-42.
21. Kotzeva, V.P. and Kumar, R.V. (1999) The response of yttria stabilized zirconia oxygen sensors to carbon monoxide gas. Ionics, 5, (3-4)220-6.
22. Fergus, J.W. (2007) Solid electrolyte based sensors for the measurement of CO and hydrocarbon gases. Sens. Actuators B, 122 ,683-93.
23. Garzon, R., Mukundan, R. and Brosha, E.L. (2001) Modeling the response of mixed potential electrochemical sensors. Proceedings of the Electrochemical Society, 2000-32; Solid-State Ionic Devices II Ceramic Sensors, The Electrochemical Society, Pennington, New Jersey, pp. 305-13.
24. Varamban, S.V., Ganesan, R. and Periaswami, G. (2005) Simultaneous measurement of emf and short circuit current for a potentiometric sensor using perturbation technique. Sens. Actuators B, 104 (1), 94-102.
25. Gibson, R.W., Kumar, R.V. and Fray, D.J. (1999) Novel sensors for monitoring high oxygen concentrations. Solid State Ionics, 121, (1-4)43-50.
26. Hills, M.P., Schwandt, C. andKumar, R.V. (2006)Aninvestigation of current reversal mode for gas sensing with a solid electrolyte. Int. J. Appl. Ceram. Technol., 3 (3), 200-9.
27. Zhuiykov, S. (2006) "In situ" diagnostics of solid electrolyte sensors measuring oxygen activity in melts by a developed impedance method. Meas. Sci. Technol., 17 ,1570-8.
28. Zhuiykov, S. (2005) Sensors measuring oxygen activity in melts: Development of impedance method for "in-situ" diagnostics and control electrolyte/liquidmetal electrode interface. Ionics, 11 ,352-61.
29. Zhuiykov, S., Nakano, T., Kunimoto, A., Yamazoe, N. and Miura, N. (2001) Potentiometric NOx sensor based on stabilized zirconia and NiCr2O4 sensing electrode operating at high temperatures. Electrochem. Commun., 3 (2), 97-101.
30. West, D.L., Montgomery, F.C. and Armstrong, T.R. (2006) 'Total NOx' sensing elements with compositionally identical oxide electrodes. J. Electrochem. Soc., 153 (2), H23-8.
31. West, D.L., Montgomery, F.C. and Armstrong, T.R. (2005) Electrically biased NOx sensing elements with coplanar electrodes. J. Electrochem. Soc., 152 (6), H74-9.
32. Woo, L.Y., Martin, L.P., Glass, R.S. and Gorte, R.J. (2007) Impedance characterization of a model Au/yttriastabilized zirconia/Au electrochemical cell in varying oxygen and NOx concentration. J. Electrochem. Soc., 154 (4), J129-35.
33. Reinhardt, G., Mayer, R. and Rósch, M. (2002) Sensing small molecules with amperometric sensors. Solid State Ionics, 150, (1-2)79-92.
34. Jasinski, G., Jasinski, P., Nowakowski, A. and Chachulski, B. (2006) Properties of a lithium solid electrolyte gas sensor based on reaction kinetics. Meas. Sci. Technol., 17 ,17-21.
35. Ueda, T., Plashnitsa, V.V., Elumalai, P. and Miura, N. (2007) Novel measuring method for detection of propene using zirconia-based amperometric sensor with oxide-based sensing electrode. Sens. Mater., 19 (6), 333-45.
36. Etsell, T.H. and Flengas, S.N. (1970) The electrical properties of solid oxide electrolyte. Chem. Rev., 70 (3), 339-76.
37. Mogensen, M., Lybye, D., Bonanos, N., Hendriksen, P.V. and Poulsen, F.W. (2004) Factors controlling the oxide ion conductivity of fluorite and perovskite structured oxides. Solid State Ionics, 174, (1-4)279-86.
38. Steele, B.C.H. (1992) Oxygen ion conductors and their technological applications.Mater. Sci. Eng., B13, 79-87.
39. Fergus, J.W. (2003) Doping and defect association in oxides for use in oxygen sensors. J. Mater. Sci., 38 (21), 4259-70.
40. 2 gas sensor. Sens. Actuators B, 115 (1), 455-9.
41. x (Me1=4Cu, Ti, Zr, Nb, Ta) compounds as solid electrolyte and behavior of their oxygen concentration cells. Sens. Actuators B, 109 (2), 307-14.
42. x oxideion conductor. Sens. Actuators B, 108, (1-2)335-40.
43. Pasciak, G., Prociow, K., Mielcarek, W., Bornicka, B. and Mazurek, B. (2001) Solid electrolytes for gas sensors and fuel cells application. J.Eur.Ceram.Soc., 21,1867-70.
44. Ramanarayanan, T.A. and Worrell, W.L. (1974) Limitations in the use of solid state electrochemical cells for hightemperature equilibrium measurements. Can. Metall. Q., 13 (2), 325-9.
45. Sridhar, K.R. and Blanchard, J.A. (1999) Electronic conduction in low oxygen partial pressure measurements using an amperometric zirconia oxygen sensor. Sens. Actuators B, 59 ,60-7.
46. Guo, X., Sun, Y.-Q. and Cui, K. (1996) Darkening of zirconia: A problem arising from oxygen sensors in practice. Sens. Actuators B, 31 ,139-45.
47. Patterson, J.W. (1971) Conduction domains for solid electrolytes. J. Electrochem. Soc., 118 (7), 1033-9.
48. Seetharaman, S. and Sichen, D. (1996) Development and application of electrochemical sensors for molten metals processing, in Emerging Separation Technologies for Metals II (ed. R.G. Bautista), The Minerals, Metals and Materials Society, Warrendale, PA, pp. 317-40.
49. Chueh, W.C., Lai, W. and Haile, S.M. (2008) Electrochemical behavior of ceria with selected metal electrodes. Solid State Ionics, 179 ,1036-41.
50. Réau, J.-M. and Portier, J. (1978) Fluorine ion conductors, in Solid Electrolytes: General Principles, Characterization, Materials, Applications (eds P. Hagenmuller and W. Van Gool), Academic Press, New York, pp. 313-33.
51. Fergus, J.W. (1997) The application of solid fluoride electrolytes in chemical sensors. Sens. Actuators B, 42 (2), 119-30.
52. 2- based oxygen sensor operative at low temperature. Sens. Actuators B, 46 ,169-73.
53. Eguchi, T. and Kuwano, J. (1995) Towards a room temperature, solid state, oxygen gas sensor. Mater. Res. Bull., 30 (11), 1351-7.
54. Siebert, E., Fouletier, J. and Kleitz, M. (1987) Oxygen sensing with solid electrolyte cells from room temperature up to 250 °C. J. Electrochem. Soc., 134 (6), 1573-8.
55. Farrington, G.C. and Briant, J.L. (1979) Fast ionic transport in solids. Science, 204 ,1371-9.
56. Bates, J.B., Wang, J.-C. and Dudney, N.J. (1982) Solid electrolytes - the beta aluminas. Phys. Today, 35 (7), 46-53.
57. Louey, R., Langberg, D.E., Swinbourne, D.R. and van Deventer, J.S.J. (2000) Solid Electrolyte - New Techniques in Metal Refining, Australasian Institute of Mining Metallurgy, Carlton, Australia, pp. 559-70.
58. Radzilowski, R.H. and Kummer, J.T. (1969) The preparation of nitrosonium b-alumina. Inorg. Chem., 8 (11), 2531-3.
59. 12. Mater. Res. Bull., 11 (2), 173-82.
60. Novoselov, A., Zhuravleva, M., Zakalyukin, R., Fomichev, V. and Zimina, G. (2008) Phase stability and ionic conductivity of solid solutions with NASICON structure. J. Am. Ceram. Soc., 91 (4), 1377-9.
61. 12: A simulation study. J. Phys. Chem. B, 106 ,7081-9.
62. Mazza, D. (2001) Modeling ionic conductivity in Nasicon structures. J. Solid State Chem., 156 ,154-60.
63. Fergus, J.W. (2006) Electrolytes for solid oxide fuel cells. J. Power Sources, 162, (1-2)30-40.
64. Bates, J.B., Brown, G.M., Kaneda, T., Brundage, W.E., Wang, J.C. and Engstrom, H. (1979) Properties of single crystal beta" aluminas, in Fast Ion Transport in Solids (eds P. Vashishta, J.N. Mundy and G.K. Shenoy), Elsevier North-Holland, New York, pp. 261-6.
65. Whittingham, M.S. and Huggins, R.A. (1971) Measurement of sodium ion transport in beta alumina using reversible solid electrodes. J. Chem. Phys., 54 (1), 414-16.
66. Bohnke, O., Ronchetti, S. and Mazza, D. (1999) Conductivity measurements on nasicon and nasicon-modified materials. Solid State Ionics, 122 ,127-6.
67. Kudo, T. (1997) Survey of types of solid electrolytes, in The CRC Handbook of Solid State Electrochemistry (eds P.J. Gellings and H.J.M., Bouwmeester), CRC Press, Boca Raton, FL, pp. 195-221.
68. 3 single crystals. Solid State Ionics, 100 ,153-5.
69. Maffei, N. and Kuriakose, A.K. (1999) A hydrogen sensor based on a hydrogen ion conducting solid electrolyte. Sens. Actuators B, 56 ,243-6.
70. Iwahara, H., Asakura, Y., Katahira, K. and Tanaka, M. (2003) Prospect of hydrogen technology using proton-conducting ceramics. Solid State Ionics, 168, (3-4)299-310.
71. Bonanos, N. (2001) Oxide-based protonic conductors: Point defects and transport properties. Solid State Ionics, 145 ,265-74.
72. Poulsen, F.W. (1989) Proton conduction in solids, in High Conductivity Solid Ionic Conductors: Recent Trends and Applications (ed. Y. Takahashi), World Scientific, Singapore, pp. 166-200.
73. Norby, T. (1989) Hydrogen defects in inorganic solids, in Selected Topics in High Temperature Chemistry: Defect Chemistry of Solids, Vol. 9 (eds Ø. Johannesen and A.G. Anderson), Elsevier, Amsterdam, pp. 101-42.
74. Norby, T. and Larring, Y. (1997) Concentration and transport of protons in oxides. Curr. Opin. Solid State Mater. Sci., 2 ,593-9.
75. Kreuer, K.-D. (1996) Proton conductivity: materials and applications. Chem. Mater., 8 ,610-41.
76. Kreuer, K.D. (1997) On the development of proton conducting materials for technological applications. Solid State Ionics, 97 ,1-15.
77. Alberti, G. and Casciola, M. (2001) Solid state protonic conductors, present main applications and future prospects. Solid State Ionics, 145 ,3-16.
78. Iwahara, H., Yajima, T.,Hibino, T., Ozaki, K. and Suzuki, H. (1993) Protonic conduction in calcium, strontium and barium zirconates. Solid State Ionics, 61 ,65-9.
79. Kurita, N., Fukatsu, N., Ito, K. and Ohashi, T. (1995) Protonic conduction domain of indium-doped calcium zirconate. J. Electrochem. Soc., 142 (5), 1552-9.
80. 3. J. Electrochem. Soc., 131 (1), 63-7.
81. 4 as a solid reference electrode. Electrochem. Solid-State Lett., 2 (4), 201-4.
82. 2 gas sensors based on solid electrolytes. Sens. Actuators B, 24-25, 600-2.
83. 2 gas sensors. Sens. Actuators B, 59 ,235-41.
84. Worrell,W.L. and Liu, Q.G. (1984) A new sulfur dioxide sensor using a novel two-phase solid-sulfate electrolyte. J. Electroanal. Chem., 168 ,355-62.
85. Eastman, C.D. and Etsell, T.H. (2006) Performance of a platinum thin film working electrode in a chemical sensor. Thin Solid Films, 515 ,2669-72.
86. Eastman, C.D. and Etsell, T.H. (2000) Thick/thin film sulfur oxide chemical sensor. Solid State Ionics, 136-137, 639-45.
87. 2 determination in air. Sens. Actuators B, 2 ,51-5.
88. 2 gas sensor based upon composite Nasicon/Sr-b-Al2O3 bielectrolyte. Mater. Res. Bull., 40 ,1802-15.
89. 3 bielectrolyte. Solid State Ionics, 179 ,1662-5.
90. Wang, L. and Kumar, R.V. (2004) Crosssensitivity effects on a new carbon dioxide gas sensor based on solid bielectrolyte. Meas. Sci. Technol., 15 ,1005-10.
91. 2 sensors. Sens. Actuators B, 13-14, 530-1.
92. 2. Solid State Ionics, 86-88, 1063-7.
93. x sensor incorporating a bi-electrolyte couple. Solid State Ionics, 161 ,155-63.
94. 2 in automobile exhaust emission. J. Mater. Sci., 38 (21), 4293-300.
95. 12 substrate for sensing CO2 gas. J. Mater. Sci., 40 (7), 1717-23.
96. Tamura, S., Hasegawa, I., Imanaka, N., Maekawa, T., Tsumiishi, T., Suzuki, K., Ishikawa, H., Ikeshima, A., Kawabata, Y., Sakita, N. and Adachi, G.-y. (2005) Carbon dioxide gas sensor based on trivalent cation and divalent oxide anion conducting solids with rare earth oxycarbonate based auxiliary electrode. Sens. Actuators B, 108, (1-2)359-63.
97. 2 detection without using a reference atmosphere, Proceedings of the Electrochemical Society, 2000-32; Solid-State Ionic Devices II Ceramic Sensors, The Electrochemical Society, Pennington, New Jersey, pp. 361-7.
98. 2//YSZ/Pt structure. Sens. Actuators B, 99, (1-2)141-8.
99. +-electrolyte//YSZ/Pt structure. Sens. Actuators B, 108, (1-2)346-51.
100. 2//YSZ/Pt electrochemical cell. Sens. Actuators B, 99, (1-2)113-17.
101. 4 auxiliary electrode. Sensors Lett., 3 (1), 27-30.
102. 3+ ionconducting solid electrolyte. Solid State Ionics, 179 ,1625-7.
103. Hasegawa, I., Tamura, S. and Imanaka, N. (2005) Solid electrolyte nitrogen monoxide gas sensor operating at intermediate temperature range. Sens. Actuators B, 108 ,314-18.
104. Imanaka, N.,Hasegawa, I. and Tamura, S. (2006) Nitrogen monoxide gas sensor operable as low as 250 °C. Sensors Lett., 4 (3), 340-3.
105. Imanaka, N. (2005) Novel multivalent cation conducting ceramics and their application. J. Ceram. Soc. Jpn., 113 (6), 387-93.
106. Imanaka, N., Oda, A., Tamura, S. and Adachi, G.-Y. (2004) Total nitrogen oxides gas sensor based on solid electrolytes with refractory oxide-based auxiliary electrode. J. Electrochem. Soc., 151 (5), H113-16.
107. Oda, A., Imanaka, N. and Adachi, G.-Y. (2003) New type of nitrogen oxide sensor with multivalent cation-and anionconducting solid electrolytes. Sens. Actuators B, 93 ,229-32.
108. 3+ ion conducting solid electrolyte. Sens. Actuators B, 130 (1), 46-51.
109. Tamura, S. and Imanaka, N. (2007) Nitrogen oxide gas sensor based on multivalent ion-conducting solids. Sens. Mater., 19 (6), 347-63.
110. Kaneko, H., Okamura, T., Taimatsu, H., Matsuki, Y. and Nishida, H. (2005) Performance of a miniature zirconia oxygen sensor with a Pd-PdO internal reference. Sens. Actuators B, 108, (1-2)331-4.
111. Spirig, J.V., Ramamoorthy, R., Akbar, S.A., Routbort, J.L., Singh, D. and Dutta, P.K. (2007) High temperature zirconia oxygen sensor with sealed metal/metal oxide internal reference. Sens.Actuators B, 124 (1), 192-201.
112. 2- based solid electrolyte and selection of reference electrode of oxygen sensor. Solid State Ionics, 86-88, 1027-31.
113. Li, F., Zhu, Z. and Li, L. (1994) A new way extending working-life of oxygen sensors in melt. Solid State Ionics, 70/71, 555-8.
114. Dimitrov, S., Ranganathan, S., Weyl, A. and Janke, D. (1993) New reference materials for electrochemical on-line sensors to measure steel bath composition. Steel Res., 64 (1), 63-70.
115. Weyl, A., Tu, S.W. and Janke, D. (1994) Sensors based on new oxide electrolyte and oxygen reference materials for online measurement in steel melts. Steel Res., 65 (5), 167-72.
116. Lou, T.-J., Kong, X.-H., Huang, K.-Q. and Liu, Q.-G. (2006) Solid reference electrode of metallurgical oxygen sensor. J. Iron Steel Res. Int., 13 (5), 18-20, 46.
117. Ramamoorthy, R., Akbar, S.A. and Dutta, P.K. (2006) Dependence of potentiometric oxygen sensing characteristics on the nature of electrodes. Sens. Actuators B, 113 (1), 162-8.
118. 3 reference electrode. J. Nucl. Mater., 335 (2), 260-3.
119. Kaneko, H., Okamura, T. and Taimatsu, H. (2003) Characterization of zirconia oxygen sensors with a molten internal reference for low-temperature operation. Sens. Actuators 93, (1-3)205-8.
120. Courouau, J.-L. (2004) Electrochemical oxygen sensors for on-line monitoring in lead-bismuth alloys: status of development. J. Nucl. Mater., 335 (2), 254-9.
121. Konys, J., Muscher, H., Voß, Z. and Wedemeyer, O. (2004) Oxygen measurements in stagnant lead-bismuth eutectic using electrochemical sensors. J. Nucl. Mater., 335 (2), 249-53.
122. Zhang, L., Fray, D.J., Dekeyser, J.C. and Schutter, F.D. (1996) Reference electrode of simple galvanic cells for developing sodium sensors for use in molten aluminum. Metall. Mater. Trans. B, 27 ,794-800.
123. Yao, P.C. and Fray, D.J. (1985) Sodium activity determinations in molten 99.5% aluminium using solid electrolytes. J. Appl. Electrochem., 15 ,379-86.
124. Dubbe, A. (2008) Influence of the sensitive zeolite material on the characteristics of a potentiometric hydrocarbon gas sensor. Solid State Ionics, 179 ,1645-7.
125. Schwandt, C. and Fray, D.J. (2006) The titanium/hydrogen system as the solidstate reference in high-temperature proton conductor-based hydrogen sensors. J. Appl. Electrochem., 36 ,557-65.
126. x/perovskite-type oxide as a solidreference electrode. J. Electrochem. Soc., 155 (5), J117-21.
127. Garzon, F.H., Mukundan, R., Lujan, R. and Brosha, E.L. (2004) Solid state ionic devices for combustion gas sensing. Solid State Ionics, 175, (1-4)487-90.
128. Chowdhury, A.K.M.S., Akbar, S.A., Kapileshwar, S. and Schorr, J.R. (2001) A rugged oxygen gas sensor with solid reference for high temperature applications. J. Electrochem. Soc., 148 (2), G91-4.
129. Rutman, J. and Riess, I. (2008) Reference electrodes for thin-film solid-state ionic devices. Solid State Ionics, 179, (1-6)108-12.
130. Davies, A., Fray, D.J. and Witek, S.R. (1995) Measurement of oxygen in steel using b alumina electrolytes. Ironmaking Steelmaking, 22 (4), 310-15.
131. Kumar, R.V. and Fray, D.J. (1994) Application of novel sensors in the measurement of very low oxygen potentials. Solid State Ionics, 70/71, 588-94.
132. Sun, J., Jin, C., Li, L. and Hong, Y. (2001) A novel electrochemical oxygen sensor for determination of ultra-low oxygen contents in molten metal. J. Univ. Sci. Technol. Beijing, 8 (2), 137-40.
133. Fergus, J.W. and Hui, S. (1995) Solid electrolyte sensor for measuring magnesium in molten aluminum.Metall. Mater. Trans. B, 26 ,1289-91.
134. Lisheng, X., Zhitong, S. and Changzhen, W. (1995) Activity of dissolved La in liquid Al. Scand. J. Metall., 24 ,86-90.
135. 2 sensors based on Na b-alumina solid electrolyte. J. Electroceram., 15 (2), 151-7.
136. 2 concentrations. J. Solid State Electrochem., 8 (2), 94-109.
137. 2-selective potentiometric sensor with open reference electrode. Solid State Ionics, 86-88, 1055-62.
138. 2 sensing properties of solid-electrolyte gas sensors. Sens. Mater., 19 (6), 365-76.
139. 2 at room temperature - modification with foreign substances. Sens. Actuators B, 76 ,639-43.
140. 2 sensing under ambient conditions. J. Mater. Sci., 38 (21), 4283-8.
141. 2. Sens. Actuators B, 71 ,173-8.
142. 2 sensor. Solid State Ionics, 86-88, 1107-10.
143. 2 using solid-state electrochemical sensor on sodium ionic conductors. Sens. Actuators B, 15-16, 166-70.
144. Chu, W.F., Leonhard, V., Erdmann, H. and Ilgenstein, M. (1991) Thick-film chemical sensors. Sens. Actuators B, 4 ,321-4.
145. 2 solid electrolyte sensor with screen printing, 48th Internationales Wissenschaftliches Kolloquium, Technische Universitát, Ilmenau, pp. 13-14.
146. 2 sensor based on Nabeta-alumina in the light of the electronic conductivity of the electrolyte. Sens. Actuators B, 21 ,79-82.
147. 2 glass. Electrochemistry (Tokyo, Japan), 73 (9), 791-7.
148. 2 sensor by using solid reference counter electrode. Sens. Actuators B, 108, (1-2)364-7.
149. Miura, N., Yao, S., Shimizu, Y. and Yamazoe, N. (1992) Carbon dioxide sensor using sodium ion conductor and binary carbonate auxiliary phase. J. Electrochem. Soc., 139 (5), 1384-8.
150. 2 sensors based on Nasicon as a solid electrolyte. Sens. Actuators B, 101, (1-2)47-56.
151. 3|NASICON|(Na-Ti-O) electrochemical cells. Solid State Ionics, 157, (1-4)357-63.
152. 3 auxiliary phase. Sens. Actuators B, 96 (3), 663-8.
153. 2 microsensor. J. Mater. Sci., 38 (21), 4289-92.
154. 2 sensors with high performance. Sens. Actuators B, 34 ,383-7.
155. 2 microsensor. Sens. Actuators B, 31 ,9-12.
156. Bang, Y.-I., Song, K.-D., Joo, B.-S.,Huh, J.-S., Choi, S.-D. and Lee, D.-D. (2004) Thin film micro carbon dioxide sensor using MEMS process. Sens. Actuators B, 102 ,1-6.
157. 2 sensor. J. Eur. Ceram. Soc., 25 (12), 2965-8.
158. 2 sensors with filter layers. Sens. Actuators B, 113 (1), 71-9.
159. 2 electrodes in open devices of potentiometric sensors. Solid State Ionics, 158, (3-4)297-308.
160. 3 auxiliary phases. J. Electroceram., 17 ,971-4.
161. 2 gas sensor. Solid State Ionics, 156 ,329-36.
162. 2. Solid State Ionics, 136-137, 647-53.
163. 2 sensors: influence of the working and reference electrodes relative size on the sensing properties. Sens. Actuators B, 107 (2), 695-7.
164. 2 with kernel ridge regression data analysis. Sens. Actuators B, 123 (2), 950-63.
165. 4 reference electrode. Sens. Actuators B, 76 ,591-9.
166. 3. Solid State Ionics, 79 ,349-3.
167. 2 sensors with lithium-ion conductor and Li transition metal complex oxide as solid reference electrode. J. Electrochem. Soc., 148 (8), H81-4.
168. x sensing in a diesel engine exhaust stream. Sens. Actuators B, 107 (2), 839-48.
169. 2 sensor and the role of electronic conductivity of the electrolyte. Sens. Actuators B, 105 (2), 119-23.
170. 2 detection with lithium solid electrolyte sensors. Sens. Actuators B, 13-14, 476-9.
171. 2 gas sensor with lithium phosphorous oxynitride electrolyte. Sens. Actuators B, 76 ,591-9.
172. 2 sensor with Li-ion conducting electrolytes. Sens. Actuators B, 88 ,53-9.
173. 4 thin film electrolyte. Sensors, 5 (11), 465-72.
174. 4 solid electrolyte. Solid State Ionics, 177, (39-40)3485-90.
175. 3 glass ceramics based composite. Ionics, 10, (1-2)45-9.
176. 2 sensor prepared on small-volume ceramic tube substrate. Mater. Chem. Phys., 91, (2-3)338-42.
177. x (x1=42,3) gas sensor utilizing Ag-b-alumina as solid electrolyte. Sens. Actuators B, 31 ,209-12.
178. x (x1=42,3) gas sensors using Ag-b-alumina solid electrolyte. Solid State Ionics, 86-88, 1095-9.
179. 2 gas sensor with solid reference electrode. Key Eng. Mater., 280-283 (Pt 1, High-Performance Ceramics III), 323-6.
180. x (x1/42, 3). J. Appl. Electrochem., 18 ,245-51.
181. 4 auxiliary electrolytes. Sens. Actuators B, 93 ,209-13.
182. Jacob, K.T., Rao, D.B. and Nelson, H.G. (1978) Somestudies on a solid-state sulfur probe for coal gasification studies. J. Electrochem. Soc., 125 (5), 758-62.
183. Moos, R., Reetmeyer, B., Húrland, A. and Plog, C. (2006) Sensor for directly determining the exhaust gas recirculation rate - EGR sensor. Sens. Actuators B, 119 (1), 57-63.
184. + cation conducting, ceramic membrane. Sens. Actuators B, 77 ,287-92.
185. Imanaka, N., Yamamoto, T. and Adachi, G. (1999) Nitrogen monoxide sensing with nitrosonium ion conducting solid electrolytes. Electrochem. Solid-State Lett., 2 (8), 409-11.
186. Yao, S., Shimizu, Y., Miura, N. and Yamazoe, N. (1992) Use of sodium nitrate auxiliary electrode for solid electrolyte sensor to detect nitrogen oxides. Chem. Lett., 1587-90.
187. x measurements. J. Electrochem. Soc., 151 (4), H75-80.
188. x sensor based on surface modifications of the solid electrolyte, Proceedings of the Electrochemical Society, 2000-32; Solid-State Ionic Devices II Ceramic Sensors, The Electrochemical Society, Pennington, New Jersey, pp. 252-60.
189. x sensor operative at high temperature. Solid State Ionics, 79 ,338-43.
190. 3-metal oxide mixtures. Sens. Actuators B, 121 ,194-9.
191. 3 as an auxiliary electrode. Sens. Actuators 126 (2), 406-14.
192. 2 gas sensor with drift-detection electrode. IEEE Trans. Instrumentation and Measurement, 52 (3), 1494-500.
193. 2 sensor. Ceram. Eng. Sci. Proc., 25 (3), 471-6.
194. 2 sensor prepared by a sol-gel method. Sens. Actuators B, 80 ,28-32.
195. Yao, S., Shimizu, Y., Miura, N. and Yamazoe, N. (1993) Solid electrolyte carbon dioxide sensor using sodium ionic conductor and lithium carbonate-based auxiliary phase. Appl. Phys. A., 57 ,25-9.
196. 2 sensor combined with new materials operative at room temperature. Sens. Actuators B, 108, (1-2)352-8.
197. Lee, D.-D., Choi, S.-D. and Lee, K.-W. (1995) Carbon dioxide sensor using NASICON prepared by the sol-gel method. Sens. Actuators B, 24-25, 607-9.
198. 2 gas sensor with NASICON dispersed in a binary solid electrolyte system. Indian J. Phys., 79 (7), 725-6.
199. 2 sensing applications. Sens. Actuators B, 122 (2), 419-26.
200. 2 sensor using NASICON and Li-based binary carbonate electrode. Chem. Lett., 2069-72.
201. 2+ conducting solid electrolyte. Mater. Sci. Technol., 19 ,1478-82.
202. 2+ ion conducting solid electrolyte. J. Appl. Electrochem., 36 ,173-8.
203. 2+ conducting solid electrolyte. J. Electroanal. Chem., 543 ,109-14.
204. 24 as electrolyte. Solid State Ionics, 79 ,354-7.
205. 2 sensor operative at room temperature. Sens. Actuators B, 93, (1-3)243-9.
206. 4 (M1=4Li, Na, K; RE1=4rare earth) ceramics. J. Mater. Sci., 40 (1), 129-33.
207. 2 sensors using anion conductor and metal carbonate. Sens. Actuators B, 24-25, 260-5.
208. Miura, N., Yan, Y., Nonaka, S. and Yamazoe, N. (1995) Sensing properties and mechanism of a planar carbon dioxide sensor using magnesia-stabilized zirconia and lithium carbonate auxiliary phase. J. Mater. Chem., 5 (9), 1391-4.
209. 3 (Me1/4Li, Na, K)| yttria-stabilized zirconia electrode. J. Electrochem. Soc., 144 (3), 915-22.
210. 2 sensor studies by impedance spectroscopy. Physica B, 387 ,302-12.
211. 2 monitoring. Solid State Ionics, 152-153, 823-6.
212. Yan, Y., Shimizu, Y., Miura, N. and Yamazoe, N. (1992) Solid-state sensor for sulfur oxides based on stabilized zirconia and metal sulfate. Chem. Lett., 635-8.
213. 2 auxiliary phase. Sens. Actuators B, 20 ,81-7.
214. Yan, Y., Miura, N. and Yamazoe, N. (1996) Construction and working mechanism of sulfur dioxide sensor utilizing stabilized zirconia and metal sulfate. J. Electrochem. Soc., 143 (2), 609-13.
215. Zhuiykov, S. (2000) Development of dual sulfur oxides and oxygen solid state sensor for 'in situ' measurements. Fuel, 79 (10), 1255-65.
216. Matsubara, S., Tsutae, T., Nakamoto, K., Hirose, Y., Katayama, I. and Iida, T. (1995) Determination of aluminum concentration in molten zinc by the E.M.F. method using zirconia solid electrolyte. ISIJ Int., 35 (5), 512-18.
217. Li, F., Hongpeng, H., Liansheng, L., Lifen, L. and Daotze, L. (2000) A study of aluminum sensor for steel melt. Sens. Actuators B, 62 ,31-4.
218. Hong, Y.R., Li, F.S., Mao, Y.W., Li, L.S., Zhou, Y.Z. and Wang, P. (1990) A solid electrochemical ferro sensor for molten matter, in Solid State Ionic Materials (eds. B.V.R. Chowdary et al.), World Scientific Publishing, Singapore, pp. 375-9.
219. Okimura, T., Fukui, K. andMaruhashi, S. (1990) Development of zirconia electrolyte sensor with auxiliary electrode for the in situ measurement of dissolved silicon in molten iron. Sens.Actuators B, 1 ,203-9.
220. 2 solid electrolyte. Mater. Trans. JIM, 36 (10), 1255-62.
221. Kale, G.M., Davidson, A.J. and Fray, D.J. (1996) Solid-state sensor for measuring antimony in non-ferrous metals. Solid State Ionics, 86-88, 1101-5.
222. Larose, S., Dubreuil, A. and Pelton, A.D. (1991) Solid electrolyte probes for magnesium, calcium and strontium in molten aluminum. Solid State Ionics, 47 ,287-95.
223. Imanaka, N., Kamikawa, M. and Adachi, G.-y. (2002) A carbon dioxide gas sensor by combination of multivalent cation and anion conductors with a water-insoluble oxycarbonate-based auxiliary electrode. Anal. Chem., 74 (18), 4800-4.
224. Imanaka, N., Oda, A., Tamura, S., Adachi, G.-y., Maekawa, T., Tsumeishi, T. and Ishikawa, H. (2003) Carbon dioxide gas sensor suitable for in situ monitoring. Electrochem. Solid-State Lett., 7 (2), H12-14.
225. Imanaka, N., Kamikawa, M., Tamura, S. and Adachi, G. (2001) Carbon dioxide gas sensor with multivalent cation conducting solid electrolytes. Sens. Actuators B, 77, (1-2)301-6.
226. 2- ionconducting stabilized zirconia solid electrolytes. Electrochem. Solid-State Lett., 2 (11), 602-4.
227. 3 solid electrolyte. Sens. Actuators B, 73 ,205-10.
228. 1.9 electrolyte and platinum and gold electrodes. J. Electrochem. Soc., 147 (4), 1583-8.
229. Garzon, F.H., Munkundan, R. and Brosha, E.L. (2000) Solid-state mixed potential gas sensors: Theory, experiments and challenges. Solid State Ionics, 136-137, 633-8.
230. Mukundan, R., Brosha, E.L. and Garzon, F.H. (2002) Solid-state electrochemical sensors for automotive applications. Ceram. Trans., 130 (Chemical Sensors for Hostile Environments), 1-10.
231. Mukundan, R., Brosha, E.L., Brown, D.R. and Garzon, F.H. (1999) Ceria-electrolytebased mixed potential sensors for the detection of hydrocarbons and carbon monoxide. Electrochem. Solid-State Lett., 2 (12), 412-14.
232. Vogel, A., Baier, G. and Schúle, V. (1993) Non-Nernstian potentiometric zirconia sensors: Screening of potential working electrode materials. Sens. Actuators B, 15-16, 147-50.
233. Thiemann, S., Hartung, R., Wulff, H., Klimke, J., Móbius, H.-H., Guth, U. and Schónauer, U. (1996) Modified Au-YSZ electrodes - preparation, characterization and electrode behaviour at higher temperatures. Solid State Ionics, 86-88, 873-6.
234. Lalauze, R., Visconte, E., Montanaro, L. and Pijolat, C. (1993) A new type of mixed potential sensor using a thick film of beta alumina. Sens. Actuators B, 13-14, 241-3.
235. Guillet, N., Lalauze, R. and Pijolat, C. (2004) Oxygen and carbon monoxide role on the electrical response of a non-Nernstian potentiometric gas sensor; proposition of a model. Sens. Actuators B, 98, (2-3)130-9.
236. x in exhausts. Sens. Actuators B, 35-36, 409-18.
237. Gópel, W., Reinhardt, G. and Rósch, M. (2000) Trends in the development of solid state amperometric and potentiometric high temperature sensors. Solid State Ionics, 136-137, 519-31.
238. Thiemann, S., Hartung, R., Guth, U. and Schónauer, U. (1996) Chemical modifications of Au-electrodes on YSZ and their influence on the non-Nernstian behavior. Ionics, 2, (5-6)463-7.
239. 3-a electrolyte with a platinum electrode for detection of hydrocarbons. Electrochem. Solid-State Lett., 4 (5), H9-11.
240. Hibino, T.,Hashimoto, A., Suzuki, M. and Sano, M. (2001) Mixed potentials at metalelectrode and proton-conducting electrolyte interfaces in hydrocarbonoxygen mixtures. J. Phys. Chem., 105 ,10648-52.
241. Narayanan, B.K., Akbar, S.A. and Dutta, P.K. (2002) A phosphate-based proton conducting solid electrolyte hydrogen gas sensor. Sens. Actuators B, 87 ,480-6.
242. Hashimoto, A.,Hibino, T., Mori, K.-T. and Sano, M. (2001) High-temperature hydrocarbon sensors based on a stabilized zirconia electrolyte and proton conductorcontaining platinum electrode. Sens. Actuators B, 81 ,55-63.
243. x sensors based on solid electrolytes. Sensors Update, 6 ,191-210.
244. Ménil, F., Coillard, V. and Lucat, C. (2000) Critical review of nitrogen monoxide sensors for exhaust gases of lean burn engines. Sens. Actuators B, 67 ,1-23.
245. x in car exhaust. Ceram. Eng. Sci. Proc., 26 (5), 3-13.
246. x-containing air. Sens. Actuators B, 113 ,316-19.
247. x reduction on platinum. J. Electrochem. Soc., 135 (5), 1294-301.
248. x sensors. Sens. Actuators B, 96, (1-2)46-52.
249. x decomposition mechanism on the electrodes of a zirconia-based amperometricNOx sensor. Sens. Actuators B, 93 ,214-20.
250. x sensor utilizing Pt and Au electrodes. Ceram. Trans., 130 (Chemical Sensors for Hostile Environments), 11-18.
251. 2 composite solid electrolyte. Int. J. Appl. Ceram. Technol., 3 (3), 210-17.
252. Guillet, N., Lalauze, R., Viricelle, J.-P., Pijolat, C. and Montanaro, L. (2002) Development of a gas sensor by thick film technology for automotive applications: Choice of materials - realization of a prototype. Mater. Sci. Eng. C, 21 ,97-103.
253. 7 proton conductor. Electrochem. Solid-State Lett., 9 (6), H48-51.
254. Di Bartolomeo, E. and Grilli, M.L. (2005) YSZ-based electrochemical sensors: From materials preparation to testing in the exhausts of an engine bench test. J. Eur. Ceram. Soc., 25 (12), 2959-64.
255. Di Bartolomeo, E., Kaabbuathong, N., Grilli, M.L. and Traversa, E. (2004) Planar electrochemical sensors based on tapecast YSZ layers and oxide electrodes. Solid State Ionics, 171, (3-4)173-81.
256. Di Bartolomeo, E., Grilli, M.L. and Traversa, E. (2004) Sensing mechanism of potentiometric gas sensors based on stabilized zirconia with oxide electrodes. J. Electrochem. Soc., 151 (5), H133-9.
257. Di Bartolomeo, E., Kaabbuathong, N., D'Epifanio, A., Grilli, M.L., Traversa, E., Aono, H. and Sadaoka, Y. (2004) Nanostructures perovskite oxide electrodes for planar electrochemical sensors using tape casted YSZ layer. J. Eur. Ceram. Soc., 24 ,1187-90.
258. 2 and CO environments. J. Electrochem. Soc., 150 (2), H33-7.
259. 3 electrode prepared by different chemical routes. Sens. Actuators B, 111-112, 91-5.
260. Grilli, M.L., Di Bartolomeo, E., Lunardi, A., Chevallier, L., Cordiner, S. and Traversa, E. (2005) Planar non-Nernstian electrochemical sensors: Field test in the exhaust of a spark ignition engine. Sens. Actuators B, 108, (1-2)319-25.
261. 2. J. Electrochem. Soc., 154 (7), J201-8.
262. 2. Sens. Actuators B, 65 ,125-7.
263. x sensors with semiconducting oxide electrodes. J. Am. Ceram. Soc., 87 (10), 1883-9.
264. x sensing elements for combustion exhausts. Sens. Actuators B, 111-112, 84-90.
265. x sensors using NiO sensing electrodes sintered at different temperatures. J. Electrochem. Soc., 152 (7), H95-101.
266. x sensing characteristics of mixedpotential-type zirconia sensor using NiO sensing electrode at high temperatures. Electrochem. Solid-State Lett., 8 (2), H9-11.
267. 2 sensor based on stabilized-zirconia tube and NiO sensing electrode. Sens. Actuators B, 114 ,903-9.
268. x sensor using Rhloaded NiO sensing electrode operating at high temperatures. Solid State Ionics, 177, (26-32)2305-11.
269. 2 sensor using stabilized zirconia and NiO sensing electrode at high temperature. Solid State Ionics, 176 ,2517-22.
270. Plachnitsa, V.V. and Miura, N. (2005) Effects of different additives on the sensing properties of NiO electrode used for mixed-potential-type YSZ-based gas sensors. Chemical Sensors, 21 (Suppl. B), 94-6.
271. 2 sensing performances by an additional second component to the nano-structured NiO sensing electrode of a YSZ-based mixed-potential-type sensor. Int. J. Appl. Ceram. Technol., 3 (2), 127-33.
272. x-reduction and -control under lean-burn conditions. Materialwiss. Werkstofftech., 38 (9), 725-33.
273. Hamamoto, K., Fujishiro, Y. and Awano, M. (2008) Gas sensing property of the electrochemical cell with a multilayer catalytic electrode. Solid State Ionics, 179 ,1648-51.
274. 2 sensors using NiO sensing electrodes sintered at different temperatures. Chemical Sensors, 21 (Suppl. A), 40-2.
275. x sensors. Ceram. Eng. Sci. Proc., 25 (3), 493-8.
276. 3 electrode morphology on the nitric oxide response of a stabilized zirconia sensor. Sens. Actuators B, 96 ,53-60.
277. x sensor by attachment of oxidation-catalyst electrode. Solid State Ionics, 75, (1-4)503-6.
278. 2 detection. J. Electrochem. Soc., 153 (11), H217-21.
279. -based potentiometric sensors and temperatureprogrammed reaction evaluation of the sensor elements. Sens. Actuators B, 123 (2), 915-21.
280. Szabo, N.F. and Dutta, P.K. (2004) Correlation of sensing behavior of mixed potential sensors with chemical and electrochemical properties of electrodes. Solid State Ionics, 171, (3-4)183-90.
281. x measurement with minimal CO interference utilizing a microporous zeolitic catalytic filter. Sens. Actuators B, 88 (2), 168-77.
282. Kading, S., Jakobs, S. and Guth, U. (2003) YSZ-cells for potentiometric nitric oxide sensors. Ionics, 9, (1-2)151-4.
283. Joo, J.H. and Choi, G.M. (2006) The effect of transition-metal addition on the nonequilibrium E.M.F.-type sensor. J. Electroceram., 17 ,1019-22.
284. Di Bartolomeo, E., Grilli, M.L., Antonias, N., Cordiner, S. and Traversa, E. (2005) Testing planar gas sensors based on yttriastabilized zirconia with oxide electrodes in the exhaust gases of a spark ignition engine. Sensor Lett., 3 (1), 22-6.
285. Westphal, D., Jakobs, S. and Guth, U. (2001) Gold-composite electrodes for hydrocarbon sensors based on YSZ solid electrolyte. Ionics, 7 (3), 182-6.
286. Zosel, J., Múller, R., Vashook, V. and Guth, U. (2004) Response behavior of perovskites and Au/oxide composites as HC-electrodes in different combustibles. Solid State Ionics, 175, (1-4)531-3.
287. Zosel, J.,Westphal, D., Jakobs, S.,Múller, R. and Guth, U. (2002) Au-oxide composites as HC-sensitive electrode materials for mixed potential gas sensors. Solid State Ionics, 152-153, 525-9.
288. x analysis in exhaust gases. Ionics, 105, (5-6)366-77.
289. Hibino, T., Kakimoto, S. and Sano, M. (1999) Non-Nernstian behavior at modified Au electrodes for hydrocarbon gas sensing. J. Electrochem. Soc., 146 (9), 3361-6.
290. 11 electrode. Sens. Actuators B, 108, (1-2)374-8.
291. Li, X., Xiong, W. and Kale, G.M. (2005) Novel nanosized ITO electrode for mixed potential gas sensor. Electrochem. Solid-State Lett., 8 (3), H27-30.
292. Li, X. and Kale, G.M. (2006) Influence of thickness of ITO sensing electrode film on sensing performance of planar mixed potentialCOsensor. Sens.ActuatorsB, 120 (1), 150-5.
293. Li, X. and Kale, G.M. (2007) Influence of sensing electrode and electrolyte on performance of potentiometric mixedpotential gas sensors. Sens. Actuators B, 123 (1), 254-61.
294. 5.6 and ITO interface. Electrochem. Solid-State Lett., 9 (2),H12-15.
295. Chevallier, L., Grilli, M.L., Di Bartolomeo, E. and Traversa, E. (2006) Non-Nernstian planar sensors based onYSZwith Ta (10 at %)-doped nanosized titania as a sensing electrode for high-temperature applications. Int. J. Appl. Ceram. Technol., 3 (5), 393-400.
296. 2 electrode. Sens. Actuators B, 134 ,25-30.
297. Elumalai, P., Plashnitsa,V.V.,Ueda, T. and Miura, N. (2008) Sensing characteristics of mixed potential-type zirconia-based sensor using laminated-oxide sensing electrode. Electrochem. Commun., 10 (5), 745-8.
298. Li, N., Tan, T.C. and Zeng, H.C. (1993) High-temperature carbon monoxide potentiometric sensor. J. Electrochem. Soc., 140 (4), 1068-73.
299. Wu, N., Zhao, M., Zheng, J.-G., Jiang, C., Myers, B., Li, S. and Mao, S.X. (2005) Porous CuO-ZnO nanocomposite for sensing electrode of high-temperature CO solid-state electrochemical sensor. Nanotechnology, 16 (12), 2878-81.
300. Miura, N., Raisen, T., Lu, G. and Yamazoe, N. (1998) Highly selective CO sensor using stabilized zirconia and a couple of oxide electrodes. Sens. Actuators B, 47 ,84-91.
301. Hibino, T., Tanimoto, S., Kakimoto, S. and Sano, M. (1999) High-temperature hydrocarbon sensors based on a stabilized zirconia electrolyte and metal oxide electrodes. Electrochem. Solid-State Lett., 2 (12), 651-3.
302. Hibino, T., Hashimoto, A., Kakimoto, S. and Sano, M. (2001) Zirconia-based potentiometric sensors using metal oxide electrodes for detection of hydrocarbons. J. Electrochem. Soc., 148 (1), H1-5.
303. 3 electrode-attached zirconia galvanic cell. Sens. Actuators B, 40 ,29-32.
304. Brosha, E.L.,Mukundan, R., Brown, D.R. and Garzon, F. (2002) Mixed potential sensors using lanthanum manganate and terbium yttrium zirconium oxide electrodes. Sens.ActuatorsB, 87 (1), 47-57.
305. 3 and Tb-doped YSZ electrode, Proceedings of the Electrochemical Society, 2000-32; Solid-State Ionic Devices II Ceramic Sensors, The Electrochemical Society, Pennington, New Jersey, pp. 314-21.
306. 3-δ metal oxides. Sens. Actuators B, 69 ,171-82.
307. Brosha, E.L.,Mukundan, R., Brown, D.R., Garzon, F. and Visser, J.H. (2002) Development of ceramic mixed potential sensors for automotive applications. Solid State Ionics, 148, (1-2)61-9.
308. Mukundan, R., Brosha, E.L. and Garzon, F. (2003) Mixed potential hydrocarbon sensors based on a YSZ electrolyte and oxide electrodes. J. Electrochem. Soc., 150 (1-2), H279-84.
309. x sensing elements. Sens. Actuators B, 106 (2), 758-65.
310. x sensor. J. Electrochem. Soc., 153 (9), H171-80.
311. Mukundan, R., Teranishi, K., Brosha, E.L. and Garzon, F.H. (2007) Nitrogen oxide sensors based on yttria-stabilized zirconia electrolyte and oxide electrodes. Electrochem. Solid-State Lett., 10 (2), J26-9.
312. x sensors using thin film electrodes and electrolytes for stationary reciprocating engine type applications. Sens. Actuators 119 (2), 398-408.
313. x sensors combining stabilized zirconia with mixed-metal oxide electrodes. Sens. Actuators B, 52 ,169-78.
314. x by differential electrode equilibria, Proceedings of the Electrochemical Society, 2000-32; Solid-State Ionic Devices II Ceramic Sensors, The Electrochemical Society, Pennington, New Jersey, pp. 215-21.
315. 3. Physica B: Condensed Matter, 327, (2-4)279-82.
316. 3 structures. J. Electroceram., 13, (1-3)721-6.
317. 3 perovskite-type oxide and ionic conductors. J. Electrochem. Soc., 148 (9), H98-102.
318. Di Bartolomeo, E., Traversa, E., Baroncini, M., Kotzeva, V. and Kumar, R.V. (2000) Solid state ceramic sensors based on interfacing ionic conductors with semiconducting oxides. J. Eur. Ceram. Soc., 20 ,2691-9.
319. Zosel, J., Franke, D., Ahlborn, K.,Gerlach, F., Vashook, V. and Guth, U. (2008) Perovskite related electrode materials with enhanced no sensitivity for mixed potential sensors. Solid State Ionics, 179 ,1628-31.
320. x at high temperature. Sens. Actuators B, 93, (1-3)221-8.
321. 2 sensor incorporating mixed-oxide electrode. Sens. Actuators B, 114 ,101-8.
322. 2. Electrochem. Solid-State Lett., 8 (6), H49-53.
323. 4 electrode couple. Sens. Actuators B, 119 (2), 409-14.
324. x sensor based on stabilized zirconia and oxide electrode. J. Electrochem. Soc., 143 (2), L33-5.
325. x in hightemperature combustion-exhausts. Solid State Ionics, 86-87, 1069-73.
326. 2 based on stabilized zirconia and spinel-type oxide electrodes. J. Mater. Chem., 7 (8), 1445-9.
327. x sensors using zirconia solid electrolyte and zinc-family oxide sensing electrode. Solid State Ionics, 152-153, 801-7.
328. x sensing devices based on YSZ and oxide electrode aiming for monitoring car exhausts. Ceram. Int., 30 (7), 1135-9.
329. x detection at high temperature. Sens. Actuators B, 83, (1-3)222-9.
330. 4 sensing electrode. Electrochem. Solid-State Lett., 4 (9), H19-21.
331. 4 tubes: Synthesis and application to gas sensors with high sensitivity and low-energy consumption. Sens. Actuators B, 120 (2), 403-10.
332. 4/YSZ/Pt sensor. J. Electrochem. Soc., 154 (7), J190-5.
333. x sensors. J. Am. Ceram. Soc., 91 (6), 2024-31.
334. x sensor response mechanism. J. Electrochem. Soc., 155 (7), J198-204.
335. - based electrodes. J. Solid State Electrochem., 12 ,1573-7.
336. 3/YSZ/Pt potentiometric sensors. J. Electrochem. Soc., 153 (6), H115-21.
337. 2 sensor using a sodium-ionic conductor and a metalsulfide electrode. Int. J. Appl. Ceram. Technol., 3 (3), 193-9.
338. 2 sensor using metal-sulfide electrode. J. Mater. Sci., 38 (21), 4301-5.
339. x sensor based on mixed potential for automobiles in exhaust gases. JSAE Review, 22 (1), 49-55.
340. x sensor. Sens. Actuators B, 122 (2), 644-52.
341. Szabo, N.F., Du, H., Akbar, S.A., Soliman, A. and Dutta, P.K. (2002) Microporous zeolite modified yttria stabilized zirconia (YSZ) sensors for nitric oxide (NO) determination in harsh environments. Sens. Actuators B, 82, (2-3)142-9.
342. x sensor by using a Pt-loaded zeolite Y filter. Sens. Actuators B, 125 (1), 30-9.
343. Zosel, J., Ahlborn, K., Múller, R., Westphal, D., Vashook, V. and Guth, U. (2004) Selectivity of HC-sensitive electrode materials for mixed potential gas sensors. Solid State Ionics, 169, (1-4)115-19.
344. Hibino, T., Kuwahara, Y., Wang, S., Kakimoto, S. and Sano, M. (1998) Nonideal electromotive force of zirconia sensors for unsaturated hydrocarbon gases. Electrochem. Solid-State Lett., 1 (4), 197-9.
345. Brosha, E.L., Mukundan, R. and Garzon, F. (2003) The role of heterogeneous catalysis in the gas-sensing selectivity of high-temperature mixed potential sensors, Proceedings of the Electrochemical Society, 2002-26; Solid-State Ionic Devices III, The Electrochemical Society, Pennington, New Jersey, pp. 261-71.
346. Yagi, H. and Hideaki, K. (1995) Hightemperature humidity sensor using a limiting-current-type plane multi-oxygen sensor for direct firing system. Sens. Actuators B, B25, (1-3)701-4.
347. Yun, D.H., Kim, D.I. and Park, C.O. (1993) YSZ oxygen sensor for lean burn combustion control system. Sens. Actuators B, 13, (1-3)114-16.
348. Logothetis, E.M., Visser, J.H., Soltis, R.E. and Rimai, L. (1992) Chemical and physical sensors based on oxygen pumping with solid-state electrochemical cells. Sens. Actuators B, 9 ,183-9.
349. Katahira, K.,Matsumoto, H., Iwahara, H., Koide, K. and Iwamoto, T. (2001) A solid electrolyte hydrogen sensor with an electrochemically-supplied hydrogen standard. Solid State Ionics, 73 ,130-4.
350. 2 and NO monitoring in exhaust gases. Sens. Actuators B, 70 ,25-9.
351. x detection. Solid State Ionics, 107 ,213-16.
352. Ueda, T., Plashnitsa, V.V., Nakatou, M. and Miura, N. (2007) Zirconia-based amperometric sensor usingZnOsensingelectrode for selective detection of propene. Electrochem. Commun., 9 ,197-200.
353. x sensors with platinum-loaded zeolite Y electrodes. Sens. Actuators B, 123 (2), 929-36.
354. Miura, N., Lu, G., Ono, M. and Yamazoe, N. (1999) Selective detection of NO by using an amperometric sensor based on stabilized zirconia and oxide electrode. Solid State Ionics, 117, (3-4)283-90.
355. Coillard, V., Juste, L., Lucat, C. and Ménil, F. (2000) Nitrogen-monoxide sensing with a commercial zirconia lambda gauge biased in amperometric mode. Meas. Sci. Technol., 11 ,212-20.
356. Coillard, V., Debéda, H., Lucat, C. and Ménil, F. (2001) Nitrogen monoxide detection with a planar spinel coated amperometric sensor. Sens. Actuators B, 78 ,113-18.
357. 3 electrolyte for monitoring exhaust gas. Mater. Manuf. Processes, 21 ,225-8.
358. 3-based solid electrolyte for monitoring exhaust gas. Sens. Actuators B, 108, (1-2)309-13.
359. 3-based oxide ion conducting electrolyte. Electrochem. Solid-State Lett., 8 (5), H46-8.
360. Ishihara, T., Fukuyama, M., Kabemura, K., Nishiguchi, H. and Takita, Y. (2003) Hydrocarbon sensor for monitoring exhaust gas using oxygen pumping current, Proceedings of the Electrochemical Society, 2002-26; Solid-State Ionic Devices III, The Electrochemical Society, Pennington, New Jersey, pp. 287-98.
361. Ishihara, T., Fukuyama, M., Dutta, A., Kabemura, K., Nishiguchi, H. and Takita, Y. (2003) Solid state amperometric hydrocarbon sensor for monitoring exhaust gas using oxygen pumping current. J. Electrochem. Soc., 150 (10), H241-5.
362. Can, Z.Y., Narita, H., Mizusaki, H. and Tagawa, H. (1995) Detection of carbon monoxide by using zirconia oxygen sensor. Solid State Ionics, 79 ,344-8.
363. Somov, S.I. and Guth, U. (1998) Aparallel analysis of oxygen and combustibles in solid electrolyte amperometric cells. Sens. Actuators B, B47, (1-2)131-8.
364. 3-based perovskite oxide electrolyte for detecting hydrocarbon in exhaust gas. A bimetallic anode for improving sensitivity at low temperatures. Chem. Mater., 16 (24), 5198-204.
365. x in an atmospheric environment. Electrochem. Solid-State Lett., 2 (7), 349-51.
366. Somov, S.I., Reinhardt, G., Guth, U. and Gópel, W. (2000) Multi-electrode zirconia electrolyte amperometric sensors. Solid State Ionics, 136-137, 543-7.
367. x and combustible gases in exhausts at high temperatures. Sens. Actuators B, 65 ,76-8.
368. Somov, S., Reinhardt, G., Guth, U. and Gópel, W. (2000) Tubular amperometric high-temperature sensors: simultaneous determination of oxygen, nitrogen oxides and combustible components. Sens. Actuators B, 65 ,68-9.
369. 3-δ as oxygen permeable membranes for exhaust gas sensors. Solid State Ionics, 146, (1-2)163-74.
370. x-sensors. J. Eur. Ceram. Soc, 21, (10-11)1971-5.
371. x. Solid State Ionics, 140, (1-2)97-103.
372. Shoemaker, E.L., Vogt, M.C., Dudek, F.J. and Turner, T. (1997) Gas microsensors using cyclic voltammetry with a cermet electrochemical cell. Sens. Actuators B, 42 ,1-9.
373. Jasinski, G., Jasinski, P., Chachulski, B. and Nowakowski, A. (2005) Lisicon solid electrolyte electrocatalytic gas sensor. J. Eur. Ceram. Soc., 25 ,2969-72.
374. 3 electrodes. Sens. Actuators B, 76 ,483-8.
375. 3 composite electrodes. J. Electrochem. Soc., 154 (3), J97-104.
376. 4 sensing electrode operating at high temperature. Electrochem. Commun., 4 (4), 284-7.
377. x. J. Electroceram., 17 ,979-86.
378. x-sensor with spinel-type SE for high temperature applications. Sens. Actuators B, 127 ,224-30.
379. 3 sensor for CO detection at high temperature. Sens. Actuators B, 110 (1), 49-53.
380. Nakatou, M. and Miura, N. (2005) Detection of combustible hydrogencontaining gases by using impedancemetric zirconia-based watervapor sensor. Solid State Ionics, 176 ,2511-15.
381. Nakatou, M. and Miura, N. (2006) Detection of propene by using new-type impedancemetric zirconia-based sensor attached with oxide sensing-electrode. Sens. Actuators B, 120 (1), 57-62.
382. Docquier, N. and Candel, S. (2002) Combustion control and sensors: A review. Prog. Energy Combust. Sci., 28 (2), 107-50.
383. MacLean, H.L. and Lave, L.B. (2003) Evaluating automobile fuel/propulsion system technologies. Prog. Energy Combust. Sci., 29 ,1-69.
384. Szabo, N., Lee, C., Trimboli, J., Figueroa, O., Ramamoorthy, R., Midlam-Mohler, S., Soliman, A., Verweij, H., Dutta, P. and Akbar, S. (2003) Ceramic-based chemical sensors, probes and field-tests in automobile engines. J.Mater. Sci., 38 (21), 4239-45.
385. Wang, D.Y. and Detwiler, E. (2006) Exhaust oxygen sensor dynamic study. Sens. Actuators B, 120 ,200-6.
386. Burgard, D.A., Dalton, T.R., Bishop, G.A., Starkey, J.R. and Stedman, D.H. (2006) Nitrogen dioxide, sulfur dioxide, and ammonia detector for remote sensing of vehicle emissions. Rev. Sci. Instrum., 77, 014101-1--014101.
387. Walsh, P.M., Gallagher, R.J. and Henry, V.I. (2001) The glass furnace combustion and melting user research facility, Ceramic Engineering and Science Proceedings, 161st Conference on Glass Problems, 2000, The American Ceramic Society, Westerville, Ohio, Vol. 22, pp. 231-46.
388. Akbar, S.A. (2003) Ceramic sensors for the glass industry. Ceramic Engineering and Science Proceedings, 163rd Conference on Glass Problems, 2002, The American Ceramic Society, Westerville, Ohio, Vol. 24, pp. 91-100.
389. Saji, K., Kondo, H., Takahashi, H., Futata, H., Angata, K. and Suzuki, T. (1993) Development of a thin-film oxygen sensor for combustion control of gas appliances. Sens. Actuators B, 14, (1-3)695-6.
390. Kubler, H. (1992) Oxygen sensor for control of wood combustion: A review. Wood Fiber Sci., 24 (2), 141-6.
391. Burgermeister, A., Benisek, A. and Sitte, W. (2004) Electrochemical device for the precise adjustment of oxygen partial pressures in a gas stream. Solid State Ionics, 170, (1-2)99-104.
392. Solimene, R.,Marzocchella, A., Passarelli, G. and Salatino, P. (2006) Assessment of gas-fluidized beds mixing and hydrodynamics by zirconia sensors. AIChE J., 52 (1), 185-98.
393. Subbarao, E.C. and Maiti, H.S. (1988) Oxygen sensors and pumps. Adv. Ceram., 24 (Sci. Technol. Zirconia 3), 731-47.
394. Ramamoorthy, R., Dutta, P.K. and Akbar, S.A. (2003) Oxygen sensors: Materials, methods, designs and applications. J. Mater. Sci., 38 (21), 4271-82.
395. Goto, K.S. (1988) Solid State Electrochemistry and Its Application to Sensors and Electronic Devices, Elsevier, Amsterdam, pp. 266-73.
396. Lee, J.-H. (2003) Review on zirconia airfuel ratio sensors for automotive applications. J. Mater. Sci., 38 (21), 4247-57.
397. Riegel, J., Neumann, H. and Wiedenmann, H.-M. (2002) Exhaust gas sensors for automotive emission control. Solid State Ionics, 152-153, 783-800.
398. st century: What are the prospects for sensors? Sens. Actuators B, 121 (2), 639-51.
399. Zosel, J., De Blauwe, F. and Guth, U. (2001) Chemical sensors for automotive application. Adv. Eng. Mater., 3 (10), 797-801.
400. 2 in process gas streams. Sens. Actuators B, 10 ,161-8.
401. Turkdogan, E.T. (2001) Novel concept of disposable emf sensor for in situ measurements of solute contents of liquid metals in metal-refining processes. Scand. J. Metall., 30 ,193-203.
402. Kale, G.M. and Kurchania, R. (1999) Online electrochemical sensors in molten metal processing technology: A review. Ceram. Trans., 92 (Electrochemistry of Glass and Ceramics), 195-220.
403. Iwase, M. (1988) Zirconia electrochemical sensors for monitoring oxygen, silicon, sulfur, aluminum, and phosphorous in iron and steel. Adv. Ceram., 24 (Sci. Technol. Zirconia 3), 871-8.
404. Janke, D. (1990) Recent development of solid ionic sensors to control iron and steel bath composition. Solid State Ionics, 40/41, 764-9.
405. Liu, Q. (1996) The development of high temperature electrochemical sensors for metallurgical processor. Solid State Ionics, 86-88, 1037-43.
406. McLean, A. (1990) Sensor aided process control in iron and steelmaking. Solid State Ionics, 40/41, 737-42.
407. 2 gas mixtures through stabilized zirconia. Metall. Trans. B, 12 ,517-24.
408. Oberg, K.E., Friedman, L.M., Boorstein, W.M. and Rapp, R.A. (1973) Electrochemical deoxidation of induction stirred copper melts. Metall. Trans., 4 ,75-82.
409. Fischer, W.A. and Janke, D. (1972) Electrolytic deoxidation of liquid metals at 1600 °C. Scr. Metall., 6 ,923-8.
410. Hasham, Z., Pal, U., Chou, K.C. and Worrell, W.L. (1995) Deoxidation of molten steel using a short-circuited solid electrochemical cell. J. Electrochem. Soc., 142 (2), 469-75.
411. Iwase, M., Ichise, E. and Jacob, K.T. (1984) Mixed ionic and electronic conduction in zirconia and its application in metallurgy. Adv. Ceram., 12 (Sci Technol Zirconia 2), 646-59.
412. Scaife, P.H., Swinkels, D.A.J. and Richards, S.R. (1976) Characterisation of zirconia electrolytes for oxygen probes used in steelmaking. High Temp. Sci., 8 ,31-47.
413. Liu, Q., An, S. and Qiu,W. (1999) Study on thermal expansion and thermal shock resistance of MgO-PSZ. Solid State Ionics, 121 ,61-5.
414. 3-FSZ coating for low oxygen determination in liquid steel. Solid State Ionics, 70/71, 563-8.
415. 2 electrolytes using EMF method. Solid State Ionics, 73 ,41-8.
416. Caproni, E., Carvalho, F.M.S. and Muccillo, R. (2008) Development of zirconia-magnesia/zirconia-yttria composite solid electrolytes. Solid State Ionics, 179 ,1652-4.
417. Etsell, T.H. and Alcock, C.B. (1981) Nonisothermal probe for continuous measurement of oxygen in steel. Solid State Ionics, 3/4, 621-6.
418. Ramasesha, S.K. and Jacob, K.T. (1989) Studies on nonisothermal solid state galvanic cells - effect of gradients on EMF. J. Appl. Electrochem., 19 ,394-400.
419. Hong, Y.R., Jin, C.J., Li, L.S. and Sun, J.L. (2002) An application of the electrochemical sulfur sensor in steelmaking. Sens. Actuators B, 87 ,13-17.
420. Swetnam, M.A., Kumar, R.V. and Fray, D.J. (2006) Sensing of sulfur in molten metal using strontium b-alumina. Metall. Mater. Trans. B, 37 ,381-8.
421. Fray, D.J. (2003) The use of solid electrolytes in the determination of activities and the development of sensors. Metall. Mater. Trans. B, 34 ,589-94.
422. Hong, Y.R., Li, L.S., Li, F.X., Zhang, Q.X. and Mao, Y.W. (1998) An electrochemical nitrogen sensor for iron and steel melts. Sens. Actuators B, 53 ,54-7.
423. 3-based solid electrolyte probe sensing hydrogen content in molten aluminum. Solid State Ionics, 59 ,167-9.
424. Yajima, T., Koide, K., Takai, H., Fukatsu, N. and Iwahara, H. (1995) Application of hydrogen sensor using proton conductive ceramics as a solid electrolyte to aluminum casting industries. Solid State Ionics, 79 ,333-57.
425. Fukatsu, N. and Kurita, N. (2005) Hydrogen sensor based on oxide proton conductors and its application to metallurgical engineering. Ionics, 11 ,54-65.
426. Schwandt, C. and Fray, D.J. (2000) Hydrogen sensing in molten aluminum using a commercial electrochemical probe. Ionics, 6, (3-4)222-9.
427. Gee, R. and Fray, D.J. (1978) Instantaneous determination of hydrogen content in molten aluminum and its alloys. Metall. Trans. B, 9 ,427-30.
428. 2Othrough single-phase, two-phase and multi-phase mixed proton, oxygen and electron hole conductors. Solid State Ionics, 140 ,275-83.
429. Róg, G., Dudek, M., Kozłowska-Róg, A. and Bućko, M. (2002) Calcium zirconate, properties and application to the solid oxide galvanic cells. Electrochim. Acta, 47 ,4523-9.
430. Kurita, N., Fukatsu, N., Miyamoto, S., Sato, F., Nakai, H., Irie, K. and Ohashi, T. (1996) The measurement of hydrogen activities in molten copper using oxide protonic conductor. Metall. Mater. Trans. B, 27 ,929-35.
431. Katahira, K., Koide, K. and Iwamoto, T. (2000) Structure and performance evaluation of hydrogen sensor for molten copper under industrial conditions, in Second International Conference on Processing Materials for Properties (eds B. Mishra and C. Yamauchi), The Minerals, Metals & Materials Society, Warrendale PA,, pp. 347-52.
432. Tominaga, H., Yajima, K. and Nishiyama, S. (1981) Application of oxygen probes for controlling oxygen content in molten copper. Solid State Ionics, 3/4, 571-4.
433. Jacob, K.T. and Ramasesha, S.K. (1989) Design of temperature-compensated reference electrodes for non-isothermal galvanic sensors. Solid State Ionics, 34 ,161-6.
434. Heinz, M., Koch, K. and Janke, D. (1989) Oxygen activities in Cr-containing Fe and Ni-based melts. Steel Res., 60 (6), 246-54.
435. Kurchania, R. and Kale, G.M. (2001) Measurement of oxygen potentials in Ag-Pb system employing oxygen sensor. Metall. Mater. Trans. B, 32 (3), 417-21.
436. Konys, J., Muscher, H., Voß, Z. and Wedemeyer, O. (2001) Development of oxygen meters for the use in leadbismuth. J. Nucl. Mater., 296 ,289-94.
437. Vargas-García, R., Romero-Serrano, A., Angeles-Hernandez, M., Chavez-Alcala, F. and Bomez-Yañez, C. (2002) Pt electrode-based sensor prepared by metal organic chemical vapor deposition for oxygen activity measurements in glass melts. Sens. Mater., 14 (1), 47-56.
438. Brisley, R.J. and Fray, D.J. (1983) Determination of the sodium activity in aluminum and aluminum silicon alloys using sodium beta alumina.Metall. Trans. B, 14 ,435-40.
439. Dekeyser, J.C., De Schutter, F., Van der Poorten, C. and Zhang, L. (1995) An electrochemical sensor for aluminum melts. Sens. Actuators B, 24-25, 273-5.
440. Doughty, G., Fray, D.J., Van der Poorten, C. and Dekeyser, J. (1996) β-Alumina for controlling the rate of sodium addition to aluminum alloys. Solid State Ionics, 86-88, 193-6.
441. 2-AgCl system. Solid State Ionics, 93 ,165-70.
442. Fray, D.J. (1990) Developments in on-line sensing in molten metals using solid electrolytes. ATB Metallurgie, 3 ,63-8.
443. Fray, D.J. (1996) The use of solid electrolytes as sensors for applications in molten metals. Solid State Ionics, 86-88, 1045-54.
444. Kale, G.M.,Wang, L. and Hong, Y. (2004) High-temperature sensor for in-line monitoring of Mg and Li in molten Al employing ion-conducting ceramic electrolytes. Int. J. Appl. Ceram. Technol., 1 (2), 180-7.
445. Dubreuil, A.A. and Pelton, A.D. (1999) Probes for the continuous monitoring of sodium and lithium in molten aluminum, in LightMetals 1985 (ed. H.O. Bohner), The Minerals, Metals & Materials Society, Warrendale, PA, pp. 1197-205.
446. Dekeyser, J.D. and De Schutter, F. (1992) An electrochemical lithium sensor for aluminum-lithium melts, in Aluminum-Lithium (eds M. Peters and P.J. Winkler), DGM Informations GmbH, pp. 831-6.
447. Yao, P.C. and Fray, D.J. (1985) Determination of the lithium content of molten aluminum using a solid electrolyte. Metall. Trans. B, 16 ,41-6.
448. Tiwari, B.L. (1987) Thermodynamic properties of liquid Al-Mg alloys measured by the EMF method. Metall. Trans. A, 18 ,1645-51.
449. Belton, G.R. and Rao, Y.K. (1969) A galvanic cell study of activity in Mg-Al liquid alloys. Trans. Metall. Soc. AIME, 245 ,2189-93.
450. Tsyplakova, M.M. and Strelets, Kh.L. (1969) Study of the thermodynamic properties of the magnesium-aluminum system. J. Appl. Chem. USSR, 42 (11), 2354-9.