Elucidation of the Fe(iv)=O intermediate in the catalytic cycle of the halogenase SyrB2

Nature

Volumn 499, Issue 7458, 2013, Pages 320-323

  Wong, Shaun D ^a   Srnec, Martin ^a   Matthews, Megan L ^b,g   Liu, Lei V ^a   Kwak, Yeonju ^a   Park, Kiyoung ^a   Bell Iii, Caleb B ^a   Alp, E Ercan ^c   Zhao, Jiyong ^c   Yoda, Yoshitaka ^d   Kitao, Shinji ^e   Seto, Makoto ^e   Krebs, Carsten ^b   Bollinger, J Martin ^b   Solomon, Edward I ^a,f  

^a STANFORD UNIVERSITY   (United States)

^b PENNSYLVANIA STATE UNIVERSITY   (United States)

^c ARGONNE NATIONAL LABORATORY   (United States)

^d JAPAN SYNCHROTRON RADIATION RESEARCH INSTITUTE   (Japan)

^e KYOTO UNIVERSITY   (Japan)

^f SLAC NATIONAL ACCELERATOR LABORATORY   (United States)

^g SCRIPPS RESEARCH INSTITUTE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

FE (IV); IRON DERIVATIVE; OXIDOREDUCTASE; SYRB2 PROTEIN; UNCLASSIFIED DRUG;

CATALYSIS; ENZYME ACTIVITY; HYDROGEN; IRON; NEUROLOGY; SECONDARY METABOLITE;

ARTICLE; CATALYSIS; HALOGENATION; HYDROXYLATION; MOLECULAR MECHANICS; NUCLEAR RESONANCE VIBRATIONAL SPECTROSCOPY; PRIORITY JOURNAL; PSEUDOMONAS SYRINGAE; SENSITIVITY ANALYSIS; SPECTROSCOPY;

BIOCATALYSIS; HALOGENATION; HYDROXYLATION; IRON; OXIDOREDUCTASES; PSEUDOMONAS SYRINGAE;

EID: 84880420011     PISSN: 00280836     EISSN: 14764687     Source Type: Journal    
DOI: 10.1038/nature12304     Document Type: Article

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