Carbon dioxide: A waste product in the catalytic cycle of α-ketoglutarate dependent halogenases prevents the formation of hydroxylated by-products

Journal of Physical Chemistry B

Volumn 113, Issue 1, 2009, Pages 12-14

  De Visser, Sam P ^a   Latifi, Reza ^a,b  

^a UNIVERSITY OF MANCHESTER   (United Kingdom)

^b SHARIF UNIVERSITY OF TECHNOLOGY   (Iran)

Author keywords

[No Author keywords available]

Indexed keywords

ABSTRACTING; BYPRODUCTS; CARBON DIOXIDE; CHLORINE; DENSITY FUNCTIONAL THEORY; ENERGY CONVERSION; HALOGENATION; HYDROGEN; HYDROXYLATION; MATERIALS HANDLING; REACTION KINETICS;

CATALYTIC CYCLES; DENSITY FUNCTIONAL; EXPERIMENTAL DATUM; HIGH-VALENT IRONS; HYDROGEN ABSTRACTIONS; HYDROXYL RADICALS; KETOGLUTARATE; KINETIC ISOTOPE EFFECTS; LOW ENERGIES; OXO SPECIES; REACTION BARRIERS; SPIN STATE; TRAPPING MECHANISMS; TWO-STATE REACTIVITIES; WASTE PRODUCTS;

SPIN DYNAMICS;

2 OXOGLUTARIC ACID; ALPHA-KETOGLUTARIC ACID; CARBON DIOXIDE; IRON; OXIDOREDUCTASE;

CATALYSIS; CHEMISTRY; HALOGENATION; HYDROXYLATION; LETTER; SYNTHESIS; THERMODYNAMICS;

CARBON DIOXIDE; CATALYSIS; HALOGENATION; HYDROXYLATION; IRON; KETOGLUTARIC ACIDS; OXIDOREDUCTASES; THERMODYNAMICS;

EID: 61749086210     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp8097632     Document Type: Article

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