Palladium-catalyzed cross-coupling of aziridinylmetal species, generated by sulfinyl-magnesium exchange, with aryl bromides: Reaction optimization, scope, and kinetic investigations

Journal of Organic Chemistry

Volumn 78, Issue 3, 2013, Pages 844-854

  Hughes, Matthew ^a   Boultwood, Tom ^a   Zeppetelli, Gianfranco ^a   Bull, James A ^a  

^a IMPERIAL COLLEGE LONDON   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ARYL BROMIDES; ARYL GROUP; AZIRIDINES; C-C BONDS; CROSS-COUPLINGS; DIASTEREOISOMERS; ELECTRON-RICH; FUNCTIONALIZED; HIGH YIELD; KINETIC INVESTIGATIONS; PALLADIUM-CATALYZED CROSS-COUPLINGS; RATE DETERMINING STEP; REACTION OPTIMIZATION; REDUCTIVE ELIMINATION; TRANSMETALATION; ZINC CHLORIDE;

CATALYSIS; CHLORINE COMPOUNDS; MAGNESIUM; ORGANOMETALLICS; PALLADIUM COMPOUNDS; REACTION KINETICS;

METAL HALIDES;

ARYL BROMIDE; AZIRIDINE DERIVATIVE; BROMINE DERIVATIVE; MAGNESIUM; ORGANOMETALLIC COMPOUND; PALLADIUM; UNCLASSIFIED DRUG; ZINC CHLORIDE;

ARTICLE; CATALYSIS; CHEMICAL REACTION KINETICS; COVALENT BOND; CROSS COUPLING REACTION; DEGRADATION; DIASTEREOISOMER; ELECTRON; ELIMINATION REACTION; KINETICS; REACTION OPTIMIZATION; SUBSTITUTION REACTION;

EID: 84873353977     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo3027824     Document Type: Article

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