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For examples of decomposition of triazoline to the corresponding C-silylaziridine with silica gel, see refs 8e and 8f.
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40
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0042612189
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note
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See ref 7. For the rare examples where trans aziridines are the main isomers, see refs 7o and 7p.
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41
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0001443339
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Recently TBAT has been introduced and, being non-hygroscopic, non-basic, and soluble in a wide range of organic solvents, has proved to be very effective for Si-C bond cleavage. See: Pilcher, A. S.; DeShong, P. J. Org. Chem. 1996, 61, 6901.
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Full details will be reported elsewhere.
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