What is the rate of the Csp2-Csp2 reductive elimination step? Revealing an unusually fast Ni-catalyzed negishi-type oxidative coupling reaction

Journal of the American Chemical Society

Volumn 131, Issue 29, 2009, Pages 9892-9893

  Jin, Liqun ^a   Zhang, Hua ^a   Li, Peng ^a   Sowa Jr , John R ^b   Lei, Aiwen ^a,c  

^a WUHAN UNIVERSITY   (China)

^b SETON HALL UNIVERSITY   (United States)

^c SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ARRHENIUS EQUATION; ARYLZINC REAGENTS; CATALYTIC CYCLES; DIRECT MEASUREMENT; NI CATALYSTS; OXIDATIVE COUPLING REACTIONS; OXIDATIVE COUPLINGS; QUANTITATIVE INVESTIGATION; RATE DETERMINING STEP; REACTION PROGRESS; REDUCTIVE ELIMINATION; ZERO ORDER KINETICS;

CHLORINE COMPOUNDS; NICKEL;

RATE CONSTANTS;

ARYLZINC; CHLORIDE; NICKEL; OXIDIZING AGENT; REAGENT; UNCLASSIFIED DRUG; ZINC DERIVATIVE;

AEROBIC METABOLISM; ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; COUPLING FACTOR; ELIMINATION REACTION; KINETICS; QUANTITATIVE ANALYSIS; REACTION ANALYSIS; REDUCTION;

EID: 67651236222     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja903833u     Document Type: Article

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