A kinetic study on nucleophilic displacement reactions of aryl benzenesulfonates with potassium ethoxide: Role of K+ ion and reaction mechanism deduced from analyses of LFERs and activation parameters

Journal of Organic Chemistry

Volumn 78, Issue 2, 2013, Pages 490-497

  Um, Ik Hwan ^a   Kang, Ji Sun ^a   Shin, Young Hee ^a   Buncel, Erwin ^b  

^a Ewha Womans University   (South Korea)

^b QUEEN S UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION PARAMETER; ANHYDROUS ETHANOL; BENZENESULFONATES; CATALYTIC EFFECTS; CONCERTED MECHANISM; CYCLIC TRANSITIONS; ELECTRON WITHDRAWING GROUP; ELECTRON-DONATING GROUP; ELECTRONIC NATURES; ELECTROPHILICITY; ETHOXIDES; KINETIC DATA; KINETIC STUDY; LEAVING GROUPS; LINEAR FREE ENERGY RELATIONSHIPS; NUCLEOPHILIC DISPLACEMENT; NUCLEOPHILIC SUBSTITUTION REACTIONS; PSEUDO-FIRST-ORDER RATE CONSTANT; REACTION CENTER; REACTION MECHANISM; SECOND-ORDER RATE CONSTANTS;

CATALYSIS; ETHANOL; RATE CONSTANTS; SUBSTITUTION REACTIONS;

IONS;

2,4 DINITROPHENYL X SUBSTITUTED BENZENESULFONATE; ALCOHOL; ARYL BENZENESULFONATE; BENZENESULFONIC ACID DERIVATIVE; BRONSTED ACID; PHENYL BENZENESULFONATE; POTASSIUM DERIVATIVE; POTASSIUM ETHOXIDE; POTASSIUM ION; SULFONIC ACID DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL REACTION KINETICS; CONTROLLED STUDY; DISSOCIATION CONSTANT; ELECTRON TRANSPORT; ELECTRONICS; ELECTROPHILICITY; ENERGY RESOURCE; ION PAIR EXTRACTION; NUCLEOFUGALITY; NUCLEOPHILIC DISPLACEMENT REACTION; NUCLEOPHILICITY; PHASE TRANSITION; PSEUDOFIRST ORDER RATE CONSTANT; SPECTROPHOTOMETRY; SUBSTITUTION REACTION; TRANSITION STATE;

EID: 84872562127     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo302373y     Document Type: Article

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