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Volumn 50, Issue 7, 2011, Pages 3071-3077

A study of the kinetics of La3+-promoted methanolysis of S-aryl methylphosphonothioates: Possible methodology for decontamination of EA 2192, the toxic byproduct of VX hydrolysis

Author keywords

[No Author keywords available]

Indexed keywords

LANTHANUM; ORGANOMETALLIC COMPOUND; PHOSPHOROTHIOIC ACID DERIVATIVE; THIOL DERIVATIVE;

EID: 79953166495     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic200007v     Document Type: Article
Times cited : (22)

References (33)
  • 4
    • 0032901947 scopus 로고    scopus 로고
    • For reviews, see
    • For reviews, see: Yang, Y.-C. Acc. Chem. Res. 1999, 32, 109
    • (1999) Acc. Chem. Res. , vol.32 , pp. 109
    • Yang, Y.-C.1
  • 15
    • 79953216640 scopus 로고    scopus 로고
    • Metal ion-catalyzed alcoholysis as a strategy for the high loading destruction of CW organophosphorus agents
    • Washington, DC, United States, August 16-20, 2009; American Chemical Society: Washington, DC,; INOR-396. CODEN: 69LVCL AN 2009:983730.
    • Durst, H. D.; Sumpter, K.; Brown, R. S.; Neverov, A. A.; Andrea, T. Metal ion-catalyzed alcoholysis as a strategy for the high loading destruction of CW organophosphorus agents Abstracts of Papers, 238th ACS National Meeting, Washington, DC, United States, August 16-20, 2009; American Chemical Society: Washington, DC, 2009; INOR-396. CODEN: 69LVCL AN 2009:983730.
    • (2009) Abstracts of Papers, 238th ACS National Meeting
    • Durst, H.D.1    Sumpter, K.2    Brown, R.S.3    Neverov, A.A.4    Andrea, T.5
  • 18
    • 0003650882 scopus 로고    scopus 로고
    • -16.77, neutral s spH is 8.4.
    • For the designation of pH in non-aqueous solvents, we use the nomenclature recommended by IUPAC: Compendium of Analytical Nomenclature. Definitive Rules 1997, 3 rd ed.; Blackwell, Oxford, U.K., 1998. The pH meter reading for an aqueous solution using an electrode calibrated with aqueous buffers is designated as w wpH. If the electrode is calibrated in water and the "pH" of the neat buffered methanol solution is then measured, the term ws pH is used, and if the electrode is calibrated in the same solvent and the "pH" reading is made, then the term s spH is used. In methanol, w spH-(-2.24) = s s pH, and since the autoprotolysis constant of methanol is 10-16.77, neutral s spH is 8.4.
    • (1998) Compendium of Analytical Nomenclature. Definitive Rules 1997
  • 19
    • 0030272334 scopus 로고    scopus 로고
    • Hyperquad 2000 is a computer program that applies nonlinear curve fitting to a titration by adjusting a series of formation constants (log β) for species input to a model, published in
    • Hyperquad 2000 is a computer program that applies nonlinear curve fitting to a titration by adjusting a series of formation constants (log β) for species input to a model, published in: Gans, P.; Sabatini, A.; Vacca, A. Talanta 1996, 43, 1739
    • (1996) Talanta , vol.43 , pp. 1739
    • Gans, P.1    Sabatini, A.2    Vacca, A.3
  • 27
    • 79953180333 scopus 로고    scopus 로고
    • Solution 4 is a patent-protected commercially available MICA solution for the decomposition of neutral organophosphate, phosphonate, phosphorothioate, and phosphorothionate esters as well as all OP-based chemical weapons of the G- and V-agent classes. Information regarding this solution can be obtained from Mr. Jason Hendry, Manager, Commercial Development, Parteq Innovations, Queen's University, Kingston, Ontario, Canada, K7L 3N6, e-mail: J. Hendry@parteqinnovations.com
    • Solution 4 is a patent-protected commercially available MICA solution for the decomposition of neutral organophosphate, phosphonate, phosphorothioate, and phosphorothionate esters as well as all OP-based chemical weapons of the G- and V-agent classes. Information regarding this solution can be obtained from Mr. Jason Hendry, Manager, Commercial Development, Parteq Innovations, Queen's University, Kingston, Ontario, Canada, K7L 3N6, e-mail: J. Hendry@parteqinnovations.com.
  • 33
    • 79953196795 scopus 로고    scopus 로고
    • a of the N,N-di- iso -propylaminoethanothiol is 9.54.
    • a of the N,N-di- iso -propylaminoethanothiol is 9.54.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.