Fabrication and modification of ordered nanoporous structures from nanophase-separated block copolymer/metal salt hybrids

Langmuir

Volumn 28, Issue 50, 2012, Pages 17524-17529

  Sageshima, Yoshio ^a   Arai, Shigeo ^a   Noro, Atsushi ^a   Matsushita, Yushu ^a  

^a NAGOYA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

4-VINYLPYRIDINE; COORDINATION ABILITY; CYLINDRICAL NANOPORES; ENERGY DISPERSIVE X RAY SPECTROSCOPY; FACILE PREPARATION; HYBRID FILM; IRON CHLORIDES; METAL SALT; MORPHOLOGICAL OBSERVATIONS; NANO DOMAIN; NANO-POROUS FILMS; NANOPOROUS STRUCTURES; NANOPOROUS THIN FILMS; PORE WALL; SOLVENT-CASTING; TEM OBSERVATIONS; THERMAL-ANNEALING; TRANSMISSION ELECTRON MICROSCOPY TEM;

BLOCK COPOLYMERS; CHLORINE COMPOUNDS; IRON COMPOUNDS; METALS; NANOPORES; POLYSTYRENES; SAMARIUM; SEPARATION; THIN FILMS; TRANSMISSION ELECTRON MICROSCOPY; X RAY SPECTROSCOPY;

FILM PREPARATION;

EID: 84871310454     PISSN: 07437463     EISSN: 15205827     Source Type: Journal    
DOI: 10.1021/la3042023     Document Type: Article

References (50)

1. Leisbler, L. Theory of microphase separation in block co-polymers Macromolecules 1980, 13, 1602-1617
2. Walheim, S.; Schaffer, E.; Mlynek, J.; Steiner, U. Nanophase-separated polymer films as high-performance antireflection coatings Science 1999, 283, 520-522
3. Masuda, J.; Takano, A.; Nagata, Y.; Noro, A.; Matsushita, Y. Nanophase-separated synchronizing structure with parallel double periodicity from an undecablock terpolymer Phys. Rev. Lett. 2006, 97, 098301
4. Hashimoto, T.; Shibayama, M.; Kawai, H. Domain-boundary structure of styrene-isoprene block co-polymer films cast from solution 0.4. Molecular-weight dependence of lamellar microdomains Macromolecules 1980, 13, 1237-1247
5. Matsushita, Y.; Mori, K.; Saguchi, R.; Nakao, Y.; Noda, I.; Nagasawa, M. Molecular-weight dependence of lamellar domain spacing of diblock copolymers in bulk Macromolecules 1990, 23, 4313-4316
6. Bates, F. S.; Fredrickson, G. H. Block copolymer thermodynamics-theory and experiment Annu. Rev. Phys. Chem. 1990, 41, 525-557
7. Matsushita, Y.; Noro, A.; Iinuma, M.; Suzuki, J.; Ohtani, H.; Takano, A. Effect of composition distribution on microphase-separated structure from diblock copolymers Macromolecules 2003, 36, 8074-8077
8. Matsen, M. W. Polydispersity-induced macrophase separation in diblock copolymer melts Phys. Rev. Lett. 2007, 99, 148304
9. Lynd, N. A.; Meuler, A. J.; Hillmyer, M. A. Polydispersity and block copolymer self-assembly Prog. Polym. Sci. 2008, 33, 875-893
10. Noro, A.; Cho, D.; Takano, A.; Matsushita, Y. Effect of molecular weight distribution on microphase-separated structures from block copolymers Macromolecules 2005, 38, 4371-4376
11. Li, Z. B.; Kesselman, E.; Talmon, Y.; Hillmyer, M. A.; Lodge, T. P. Multicompartment micelles from ABC miktoarm stars in water Science 2004, 306, 98-101
12. Hayashida, K.; Dotera, T.; Takano, A.; Matsushita, Y. Polymeric quasicrystal: Mesoscopic quasicrystalline tiling in ABC star polymers Phys. Rev. Lett. 2007, 98, 195502
13. Hawker, C. J.; Russell, T. P. Block copolymer lithography: Merging "bottom-up" with "top-down" processes MRS Bull. 2005, 30, 952-966
14. Cheng, J. Y.; Ross, C. A.; Smith, H. I.; Thomas, E. L. Templated self-assembly of block copolymers: Top-down helps bottom-up Adv. Mater. 2006, 18, 2505-2521
15. Kim, J. K.; Yang, S. Y.; Lee, Y.; Kim, Y. Functional nanomaterials based on block copolymer self-assembly Prog. Polym. Sci. 2010, 35, 1325-1349
16. 3 particles embedded in the walls Angew. Chem., Int. Ed. 2003, 42, 1526-1530
17. Thurn-Albrecht, T.; Schotter, J.; Kastle, C. A.; Emley, N.; Shibauchi, T.; Krusin-Elbaum, L.; Guarini, K.; Black, C. T.; Tuominen, M. T.; Russell, T. P. Ultrahigh-density nanowire arrays grown in self-assembled diblock copolymer templates Science 2000, 290, 2126-2129
18. Cheng, J. Y.; Ross, C. A.; Chan, V. Z. H.; Thomas, E. L.; Lammertink, R. G. H.; Vancso, G. J. Formation of a cobalt magnetic dot array via block copolymer lithography Adv. Mater. 2001, 13, 1174
19. Fahmi, A. W.; Braun, H. G.; Stamm, M. Fabrication of metallized nanowires from self-assembled diblock copolymer templates Adv. Mater. 2003, 15 (14) 1201
20. Kim, B. S.; Qiu, J. M.; Wang, J. P.; Taton, T. A. Magnetomicelles: Composite nanostructures from magnetic nanoparticles and cross-linked amphiphilic block copolymers Nano Lett. 2005, 5, 1987-1991
21. Stoykovich, M. P.; Muller, M.; Kim, S. O.; Solak, H. H.; Edwards, E. W.; de Pablo, J. J.; Nealey, P. F. Directed assembly of block copolymer blends into nonregular device-oriented structures Science 2005, 308, 1442-1446
22. Kang, Y.; Walish, J. J.; Gorishnyy, T.; Thomas, E. L. Broad-wavelength-range chemically tunable block-copolymer photonic gels Nat. Mater. 2007, 6, 957-960
23. Cho, J. H.; Lee, J.; Xia, Y.; Kim, B.; He, Y. Y.; Renn, M. J.; Lodge, T. P.; Frisbie, C. D. Printable ion-gel gate dielectrics for low-voltage polymer thin-film transistors on plastic Nat. Mater. 2008, 7, 900-906
24. Warren, S. C.; Messina, L. C.; Slaughter, L. S.; Kamperman, M.; Zhou, Q.; Gruner, S. M.; DiSalvo, F. J.; Wiesner, U. Ordered mesoporous materials from metal nanoparticle-block copolymer self-assembly Science 2008, 320, 1748-1752
25. Kim, K. T.; Cornelissen, J.; Nolte, R. J. M.; van Hest, J. C. M. A polymersome nanoreactor with controllable permeability induced by stimuli-responsive block copolymers Adv. Mater. 2009, 21, 2787
26. Beck, J. S.; Vartuli, J. C.; Roth, W. J.; Leonowicz, M. E.; Kresge, C. T.; Schmitt, K. D.; Chu, C. T. W.; Olson, D. H.; Sheppard, E. W.; McCullen, S. B.; Higgins, J. B.; Schlenker, J. L. A new family of mesoporous molecular-sieves prepared with liquid-crystal templates J. Am. Chem. Soc. 1992, 114, 10834-10843
27. Zhao, D. Y.; Huo, Q. S.; Feng, J. L.; Chmelka, B. F.; Stucky, G. D. Nonionic triblock and star diblock copolymer and oligomeric surfactant syntheses of highly ordered, hydrothermally stable, mesoporous silica structures J. Am. Chem. Soc. 1998, 120, 6024-6036
28. Zhao, D. Y.; Feng, J. L.; Huo, Q. S.; Melosh, N.; Fredrickson, G. H.; Chmelka, B. F.; Stucky, G. D. Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores Science 1998, 279, 548-552
29. Park, M.; Harrison, C.; Chaikin, P. M.; Register, R. A.; Adamson, D. H. Block copolymer lithography: Periodic arrays of similar to 10(11) holes in 1 square centimeter Science 1997, 276, 1401-1404
30. Zalusky, A. S.; Olayo-Valles, R.; Taylor, C. J.; Hillmyer, M. A. Mesoporous polystyrene monoliths J. Am. Chem. Soc. 2001, 123, 1519-1520
31. Huang, K.; Johnson, M.; Rzayev, J. Synthesis of degradable organic nanotubes by bottlebrush molecular templating ACS Macro Lett. 2012, 1, 892-895
32. Lee, J.; Orilall, M. C.; Warren, S. C.; Kamperman, M.; Disalvo, F. J.; Wiesner, U. Direct access to thermally stable and highly crystalline mesoporous transition-metal oxides with uniform pores Nat. Mater. 2008, 7, 222-228
33. Ndoni, S.; Vigild, M. E.; Berg, R. H. Nanoporous materials with spherical and gyroid cavities created by quantitative etching of polydimethylsiloxane in polystyrene-polydimethylsiloxane block copolymers J. Am. Chem. Soc. 2003, 125, 13366-13367
34. Chan, V. Z. H.; Hoffman, J.; Lee, V. Y.; Iatrou, H.; Avgeropoulos, A.; Hadjichristidis, N.; Miller, R. D.; Thomas, E. L. Ordered bicontinuous nanoporous and nanorelief ceramic films from self assembling polymer precursors Science 1999, 286, 1716-1719
35. Lee, J. S.; Hirao, A.; Nakahama, S. Polymerization of monomers containing functional silyl groups. 5. Synthesis of new porous membranes with functional groups Macromolecules 1988, 21, 274-276
36. Tang, C. B.; Lennon, E. M.; Fredrickson, G. H.; Kramer, E. J.; Hawker, C. J. Evolution of block copolymer lithography to highly ordered square arrays Science 2008, 322, 429-432
37. Guarini, K. W.; Black, C. T.; Yeuing, S. H. I. Optimization of diblock copolymer thin film self assembly Adv. Mater. 2002, 14, 1290
38. Yang, S. Y.; Ryu, I.; Kim, H. Y.; Kim, J. K.; Jang, S. K.; Russell, T. P. Nanoporous membranes with ultrahigh selectivity and flux for the filtration of viruses Adv. Mater. 2006, 18, 709
39. Sidorenko, A.; Tokarev, I.; Minko, S.; Stamm, M. Ordered reactive nanomembranes/nanotemplates from thin films of block copolymer supramolecular assembly J. Am. Chem. Soc. 2003, 125, 12211-12216
40. Nandan, B.; Gowd, E. B.; Bigall, N. C.; Eychmuller, A.; Formanek, P.; Simon, P.; Stamm, M. Arrays of inorganic nanodots and nanowires using nanotemplates based on switchable block copolymer supramolecular assemblies Adv. Funct. Mater. 2009, 19, 2805-2811
41. Kuila, B. K.; Stamm, M. Block copolymer-small molecule supramolecular assembly in thin film: A novel tool for surface patterning of different functional nanomaterials J. Mater. Chem. 2011, 21, 14127-14134
42. Maki-Ontto, R.; de Moel, K.; de Odorico, W.; Ruokolainen, J.; Stamm, M.; ten Brinke, G.; Ikkala, O. "Hairy tubes": Mesoporous materials containing hollow self-organized cylinders with polymer brushes at the walls Adv. Mater. 2001, 13, 117-121
43. du Sart, G. G.; Vukovic, I.; Vukovic, Z.; Polushkin, E.; Hiekkataipale, P.; Ruokolainen, J.; Loos, K.; ten Brinke, G. Nanoporous network channels from self-assembled triblock copolymer supramolecules Macromol. Rapid Commun. 2011, 32, 366-370
44. Vukovic, I.; Punzhin, S.; Vukovic, Z.; Onck, P.; De Hosson, J. T. M.; ten Brinke, G.; Loos, K. Supramolecular route to well-ordered metal nanofoams ACS Nano 2011, 5, 6339-6348
45. Noro, A.; Sageshima, Y.; Arai, S.; Matsushita, Y. Preparation and morphology control of block copolymer/metal salt hybrids via solvent-casting by using a solvent with coordination ability Macromolecules 2010, 43, 5358-5364
46. Ho, R. M.; Lin, T.; Jhong, M. R.; Chung, T. M.; Ko, B. T.; Chen, Y. C. Phase transformation in self-assembly of the gold/poly(4-vinylpyridine)- b -poly(ε-caprolactone) hybrid system Macromolecules 2005, 38, 8607-8610
47. Lee, D. H.; Kim, H. Y.; Kim, J. K.; Huh, J.; Ryu, D. Y. Swelling and shrinkage of lamellar domain of conformationally restricted block copolymers by metal chloride Macromolecules 2006, 39, 2027-2030
48. Lee, D. H.; Han, S. H.; Joo, W.; Kim, J. K.; Huh, J. Phase behavior of poly styrene-block-poly(4-vinylpyridine) copolymers coordinated by metal chloride Macromolecules 2008, 41, 2577-2583
49. Lin, T.; Li, C. L.; Ho, R. M.; Ho, J. C. Association strength of metal ions with poly(4-vinylpyridine) in organic/poly(4-vinylpyridine)- b -poly(ε-caprolactone) hybrids Macromolecules 2010, 43, 3383-3391
50. Noro, A.; Higuchi, K.; Sageshima, Y.; Matsushita, Y. Preparation and morphology of hybrids composed of a block copolymer and semiconductor nanoparticles via hydrogen bonding Macromolecules 2012, 45, 8013-8020