Ordered mesoporous materials from metal nanoparticle-block copolymer self-assembly

Science

Volumn 320, Issue 5884, 2008, Pages 1748-1752

  Warren, Scott C ^a,b   Messina, Lauren C ^b   Slaughter, Liane S ^b   Kamperman, Marleen ^a   Zhou, Qin ^b   Gruner, Sol M ^a   DiSalvo, Francis J ^b   Wiesner, Ulrich ^a  

^a Cornell University   (United States)

^b Department of Obstetrics Gynecology   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; COPOLYMER; METAL NANOPARTICLE; NANOCOMPOSITE; PLATINUM;

CARBON; ELECTRICAL CONDUCTIVITY; METAL; PLATINUM; POROUS MEDIUM;

ARTICLE; CHEMICAL STRUCTURE; ELECTRIC CONDUCTIVITY; HYBRID; NUCLEAR MAGNETIC RESONANCE; PRIORITY JOURNAL; PYROLYSIS; SOLUBILITY; SYNTHESIS; THERMOGRAVIMETRY; TRANSMISSION ELECTRON MICROSCOPY;

EID: 46449110213     PISSN: 00368075     EISSN: 10959203     Source Type: Journal    
DOI: 10.1126/science.1159950     Document Type: Article

References (33)

1. A. Haryono, W. H. Binder, Small 2, 600 (2006).
2. A. C. Balazs, T. Emrick, T. P. Russell, Science 314, 1107 (2006).
3. M. Raney, U.S. Patent 1,628,190 (1927).
4. Y. N. C. Chan, R. R. Schrock, R. E. Cohen, Chem. Mater. 4, 24 (1992).
5. D. E. Fogg, L. H. Radzilowski, R. Blanski, R. R. Schrock, E. L. Thomas, Macromolecules 30, 417 (1997).
6. B. J. Kim, G. H. Fredrickson, C. J. Hawker, E. J. Kramer, Langmuir 23, 7804 (2007).
7. P. Buffat, J.-P. Borel, Phys. Rev. A 13, 2287 (1976).
8. R. Li, K. Sieradzki, Phys. Rev. Lett. 68, 1168 (1992).
9. J. Erlebacher, M. J. Aziz, A. Karma, N. Dimitrov, K. Sieradzki, Nature 410, 450 (2001).
10. G. S. Attard et al., Science 278, 838 (1997).
11. G. S. Attard, C. G. Göltner, J. M. Corker, S. Henke, R. H. Templer, Angew. Chem. Int. Ed. Engl. 36, 1315 (1997).
12. Y. Yamauchi, T. Yokoshima, T. Momma, T. Osaka, K. Kuroda, J. Mater. Chem. 14, 2935 (2004).
13. J. Jiang, A. Kucernak, Chem. Mater. 16, 1362 (2004).
14. D. Y. Zhao et al., Science 279, 548 (1998).
15. M. E. Davis, Nature 417, 813 (2002).
16. W. A. Lopes, H. M. Jaeger, Nature 414, 735 (2001).
17. J. Chai, D. Wang, X. Fan, J. M. Buriak, Nat. Nanotechnol. 2, 500 (2007).
18. S. C. Warren et al., J. Am. Chem. Soc. 128, 12074 (2006).
19. S. Sivaramakrishnan, P.-J. Chia, Y.-C. Yeo, L.-L. Chua, P. K. H. Ho, Nat. Mater. 6, 149 (2007).
20. R. B. Thompson, V. V. Ginzburg, M. W. Matsen, A. C. Balazs, Science 292, 2469 (2001).
21. S. C. Warren, F. J. DiSalvo, U. Wiesner, Nat. Mater. 6, 156 (2007).
22. S. Creutz, P. Teyssie, R. Jerome, Macromolecules 30, 6 (1997).
23. See SOM on Science Online.
24. E. Delamarche, B. Michel, H. Kang, C. Gerber, Langmuir 10, 4103 (1994).
25. M. J. Hostetler, A. C. Templeton, R. W. Murray, Langmuir 15, 3782 (1999).
26. B. J. Kim, J. Bang, C. J. Hawker, E. J. Kramer, Macromolecules 39, 4108 (2006).
27. M. Templin et al., Science 278, 1795 (1997).
28. C. Liang, K. Hong, G. A. Guiochon, J. W. Mays, S. Dai, Angew. Chem. Int. Ed. 43, 5785 (2004).
29. J. Lee et al., Nat. Mater. 7, 222 (2008).
30. A. C. Ferrari, J. Robertson, Phys. Rev. B 61, 14095 (2000).
31. J. Liu et al., Science 280, 1253 (1998).
32. For future uses in bulk, the material probably will be protected from impact and other damage. Brittleness will not be an issue in static thin-film geometries that are most relevant for applications.
33. The authors acknowledge support of this research by the U.S. Department of Energy (grant DE-FG02-03ER46072) and NSF through a single investigator award (DMR-0605856) as well as through the Cornell Center for Materials Research with funding from the Materials Research Science and Engineering Center program of NSF (cooperative agreement DMR 0520404). X-ray diffraction at the Cornell High Energy Synchrotron Source (CHESS) is supported by NSF under award DMR-0225180. S.C.W. acknowledges support from the Environmental Protection Agency Science to Achieve Results fellowship program. The authors thank H. Abruña for valuable discussions and M. Thomas, A. Burns, J. Lee, and A. Woll for assistance with single-particle electron diffraction, EDS, Raman spectroscopy, and SAXS experimental setup, respectively. A patent application has been submitted based on the findings in this work.