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Volumn 41, Issue 46, 2012, Pages 14046-14050

Structural and reactivity comparison of analogous organometallic Pd(iii) and Pd(iv) complexes

Author keywords

[No Author keywords available]

Indexed keywords

CHLORINE COMPOUNDS; LIGANDS; ORGANOMETALLICS; PALLADIUM;

EID: 84868651477     PISSN: 14779226     EISSN: 14779234     Source Type: Journal    
DOI: 10.1039/c2dt32127k     Document Type: Article
Times cited : (50)

References (36)
  • 23
    • 25144474992 scopus 로고    scopus 로고
    • The detailed characterization of the observed spectroscopic trends for complexes 1+-4+ is ongoing and will be reported elsewhere The PdIV species [(tBuN4)PdIVMeCl] 2+ can be generated electrochemically at low temperatures, yet it is unstable at RT (ref. 6) Only one other dicationic organometallic complex has been reported to date
    • A. R. Dick J. W. Kampf M. S. Sanford J. Am. Chem. Soc. 2005 127 12790
    • (2005) J. Am. Chem. Soc. , vol.127 , pp. 12790
    • Dick, A.R.1    Kampf, J.W.2    Sanford, M.S.3
  • 28
    • 77949784030 scopus 로고    scopus 로고
    • Thermolysis in the dark of PdIII complexes leads to unspecific decomposition and formation of methane. In addition, photolysis or thermolysis of PdII precursors leads to formation of methane and Pd black, along with small amounts of ethane or MeCl
    • D. Shabashov O. Daugulis J. Am. Chem. Soc. 2010 132 3965
    • (2010) J. Am. Chem. Soc. , vol.132 , pp. 3965
    • Shabashov, D.1    Daugulis, O.2
  • 32
    • 79952432473 scopus 로고    scopus 로고
    • During the reactivity studies for RN4PdIII/Pd IV complexes, the RN4PdIIMe(solv) or RN4PdII(solv)2 products are unstable and lead to formation of methane and other PdII products (see ESI)
    • J. M. Racowski M. S. Sanford Top. Organomet. Chem. 2011 35 61
    • (2011) Top. Organomet. Chem. , vol.35 , pp. 61
    • Racowski, J.M.1    Sanford, M.S.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.