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Volumn 50, Issue 24, 2011, Pages 5532-5536

Dinuclear palladium(III) complexes with a single unsupported bridging halide ligand: Reversible formation from mononuclear palladium(II) or palladium(IV) precursors

Author keywords

chain compounds; dinuclear complexes; Kharasch reaction; N ligands; palladium

Indexed keywords

CHAIN COMPOUNDS; DINUCLEAR; DINUCLEAR COMPLEX; HALIDE LIGAND; KHARASCH REACTION; N LIGANDS; ONE-ELECTRON OXIDATION; REVERSIBLE FORMATION; TRIDENTATE LIGANDS;

EID: 79958067232     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201100928     Document Type: Article
Times cited : (47)

References (57)
  • 26
    • 79958050809 scopus 로고    scopus 로고
    • note
    • 4) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via.
  • 27
    • 79958044801 scopus 로고    scopus 로고
    • note
    • Coulometry measurements confirm that both oxidations correspond to one electron processes (see the Supporting Information).
  • 28
    • 79958048731 scopus 로고    scopus 로고
    • note
    • The presence of dimers 2 and 2b in solution was confirmed by ESI-MS and the lack of an EPR signal for the corresponding solutions at 77K or RT.
  • 29
    • 79958028101 scopus 로고    scopus 로고
    • note
    • + is the only halide abstraction product, then the theoretical yield of 2 is 67%.
  • 30
    • 79958054417 scopus 로고    scopus 로고
    • note
    • The high extinction coefficients of 2, b enable the unique visualization of mass-transport processes at the disk electrode during CV of 1, b (Supporting Information, FigureS15).
  • 37
    • 79958052290 scopus 로고    scopus 로고
    • note
    • No positional disorder along the Pd - (μ-X) - Pd axis was found for the bridging halide in the structures of either 2 (both at RT and 100K) or 2b, c (see the Supporting Information).
  • 38
    • 79958069529 scopus 로고    scopus 로고
    • note
    • III 1D chain is 5.21Å at 110K (Ref.[8a]).
  • 39
    • 79958053799 scopus 로고    scopus 로고
    • note
    • SQUID measurements of 2 showed a negligible magnetic susceptibility in the 2-320K range.
  • 40
    • 79958037149 scopus 로고    scopus 로고
    • No other absorption bands were seen in the range 700-2200nm
    • No other absorption bands were seen in the range 700-2200nm.
  • 43
    • 79958044507 scopus 로고    scopus 로고
    • note
    • IV complexes have been structurally characterized to date
  • 52
    • 79958049028 scopus 로고    scopus 로고
    • note
    • III intermediates have been detected to date
  • 57
    • 79958034784 scopus 로고    scopus 로고
    • note
    • 3Br.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.