Unusual complex formation and chemical reaction of haloacetate anion on the exterior surface of cucurbit[6]uril in the gas phase

Journal of the American Society for Mass Spectrometry

Volumn 23, Issue 10, 2012, Pages 1786-1793

  Choi, Tae Su ^a   Ko, Jae Yoon ^a   Heo, Sung Woo ^a   Ko, Young Ho ^a   Kim, Kimoon ^a   Kim, Hugh I ^a  

^a Pohang University of Science and Technology (POSTECH)   (South Korea)

Author keywords

Anionic complex; CB 6 ; Cucurbit 6 uril; Electrospray ionization; Halide; Haloacetate; Intramolecular SN2 reaction; Ion mobility spectrometry

Indexed keywords

ANIONIC COMPLEX; CB[6]; CUCURBIT[6]URIL; HALIDE; HALOACETATE; INTRAMOLECULAR SN2 REACTION; ION MOBILITY SPECTROMETRY;

BINDING ENERGY; DENSITY FUNCTIONAL THEORY; ELECTROSPRAY IONIZATION; GASES; MASS SPECTROMETRY; NEGATIVE IONS;

COMPLEXATION;

ACETIC ACID DERIVATIVE; ANION; BROMOACETIC ACID; CHLOROACETIC ACID; CUCURBIT[6]URIL; DICHLOROACETIC ACID; HALIDE; HALOACETATE ANION; IODOACETIC ACID; MACROCYCLIC COMPOUND; TRICHLOROACETIC ACID; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; COLLISIONALLY ACTIVATED DISSOCIATION; COMPLEX FORMATION; CONFORMATION; CONTROLLED STUDY; DENSITY FUNCTIONAL THEORY; ELECTROSPRAY MASS SPECTROMETRY; GAS; MOLECULAR INTERACTION; QUANTUM YIELD; SURFACE PROPERTY;

BRIDGED COMPOUNDS; CHLOROACETATES; COMPUTER SIMULATION; GASES; IMIDAZOLES; MODELS, MOLECULAR; SPECTROMETRY, MASS, ELECTROSPRAY IONIZATION; THERMODYNAMICS;

EID: 84868254692     PISSN: 10440305     EISSN: 18791123     Source Type: Journal    
DOI: 10.1007/s13361-012-0443-6     Document Type: Article

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