Rate determination of azide click reactions onto alkyne polymer brush scaffolds: A comparison of conventional and catalyst-free cycloadditions for tunable surface modification

Langmuir

Volumn 28, Issue 41, 2012, Pages 14693-14702

  Orski, Sara V ^a   Sheppard, Gareth R ^a   Arumugam, Selvanathan ^a   Arnold, Rachelle M ^a   Popik, Vladimir V ^a   Locklin, Jason ^a  

^a University of Georgia   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYST-FREE; CLICK REACTION; CYCLOADDITION REACTION; CYCLOADDITIONS; DIFFUSION LIMITED; DILUTE SOLUTION; FAST RATE; FUNCTIONALIZATIONS; FUNCTIONALIZED; N-HYDROXYSUCCINIMIDE; POLYMER BRUSHES; POLYMER LAYERS; POLYMER SCAFFOLDS; POST-POLYMERIZATION FUNCTIONALIZATION; PROPARGYL; PSEUDO-FIRST-ORDER; RATE EQUATIONS; RELATIVE RATES; RELATIVE RATIOS; SURFACE BOUNDS;

ACETYLENE; BRUSHES; CYCLOADDITION; DIFFUSION; RATE CONSTANTS; SCAFFOLDS; SCAFFOLDS (BIOLOGY);

POLYMERS;

ALKYNE; AZIDE; POLYMER;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; CLICK CHEMISTRY; COMPARATIVE STUDY; CYCLIZATION; POLYMERIZATION; SURFACE PROPERTY; SYNTHESIS;

ALKYNES; AZIDES; CATALYSIS; CLICK CHEMISTRY; CYCLIZATION; MOLECULAR STRUCTURE; POLYMERIZATION; POLYMERS; SURFACE PROPERTIES;

EID: 84867503814     PISSN: 07437463     EISSN: 15205827     Source Type: Journal    
DOI: 10.1021/la3032418     Document Type: Article

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