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Volumn 119, Issue 52, 1997, Pages 12779-12795

Mechanistic aspects of the alternating copolymerization of propene with carbon monoxide catalyzed by Pd(II) complexes of unsymmetrical phosphine - Phosphite ligands

Author keywords

[No Author keywords available]

Indexed keywords

CARBON MONOXIDE; COPOLYMER; LIGAND; PHOSPHINE DERIVATIVE; PHOSPHITE; PROPYLENE;

EID: 0031593022     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja973199x     Document Type: Article
Times cited : (190)

References (65)
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    • For papers on other improved activity with achiral catalyst systems, see for example: (a) Abu-Surrah, A. S.; Wursche, R.; Rieger, B.; Eckert, G.; Pechhold, W. Macromolecules 1996, 29, 4806. (b) Miliani, B.; Vicentini, L.; Sommazzi, A.; Garbassi, F.; Chiarparin, E.; Zangrando, E.; Mestroni, G. J. Chem. Soc., Dalton Trans. 1996, 3139.
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    • For a similar assignment, see ref 4b
    • For a similar assignment, see ref 4b.
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    • Migration of the methyl group is also suggested by theoretical studies, (a) Koga, N.; Morokuma, K. J. Am. Chem. Soc. 1986, 108, 6136. (b) Koga, N.; Morokuma, K. Chem. Rev. 1991, 91, 823.
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    • Migration of the methyl group is also suggested by theoretical studies, (a) Koga, N.; Morokuma, K. J. Am. Chem. Soc. 1986, 108, 6136. (b) Koga, N.; Morokuma, K. Chem. Rev. 1991, 91, 823.
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    • A carbon - carbon triple bond insertion into an acylpalladium bond
    • 3-Ni bond: (a) Musaev, D. G.; Froese, R. D. J.; Svensson, M.; Morokuma, K. J. Am. Chem. Soc. 1997, 119, 367. A carbon - carbon triple bond insertion into an acylpalladium bond: (b) Samsel, E. G.; Norton, J. R. J. Am. Chem. Soc. 1984, 106, 5505.
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    • 3-Ni bond: (a) Musaev, D. G.; Froese, R. D. J.; Svensson, M.; Morokuma, K. J. Am. Chem. Soc. 1997, 119, 367. A carbon - carbon triple bond insertion into an acylpalladium bond: (b) Samsel, E. G.; Norton, J. R. J. Am. Chem. Soc. 1984, 106, 5505.
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    • See the Experimental Section for computational details
    • See the Experimental Section for computational details.
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    • note
    • 23
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    • QCPE: Bloomington, IN
    • Allinger, N. L. mm3(92); QCPE: Bloomington, IN, 1992.
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    • Allinger, N.L.1


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