Diastereotopos-differentiation in the Rh-catalyzed amination of benzylic methylene groups in the α-position to a stereogenic center

Journal of the American Chemical Society

Volumn 134, Issue 32, 2012, Pages 13524-13531

  Nörder, Anike ^a   Warren, Sarah A ^a   Herdtweck, Eberhardt ^a   Huber, Stefan M ^a   Bach, Thorsten ^a  

^a TECHNICAL UNIVERSITY OF MUNICH   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ANTIPERIPLANAR; BENZYLIC; C-H BOND; CARBON ATOMS; DEUTERATIONS; DFT CALCULATION; DIASTEREO-SELECTIVITY; HYDROGEN ATOM ABSTRACTION; KINETIC ISOTOPE EFFECTS; METHYLENE GROUPS; NITROGEN SOURCES; STEREOGENIC CENTERS; STERIC STRAINS; SYN SELECTIVITY; TETRALINS;

ATOMS; CARBON; CATALYSIS; DENSITY FUNCTIONAL THEORY; DEUTERIUM; EXPERIMENTS; HYDROGEN; RHODIUM; STEREOSELECTIVITY; SULFUR DIOXIDE;

AMINES;

BENZILIC ACID; BROMINE; CARBENE; CARBON; HYDROGEN; NITROGEN; OXIDIZING AGENT; RHODIUM; TETRALIN DERIVATIVE;

AMINATION; ARTICLE; CATALYSIS; CHIRALITY; CONTROLLED STUDY; DIASTEREOISOMER; STEREOCHEMISTRY; TRANSAMINATION;

EID: 84865117951     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja3066682     Document Type: Article

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