메뉴 건너뛰기




Volumn , Issue 4, 1999, Pages 351-352

Evidence for a ruthenium dihydride species as the active catalyst in the RuCl2(PPh3)-catalyzed hydrogen transfer reaction in the presence of base

Author keywords

[No Author keywords available]

Indexed keywords

HYDROGEN; PHOSPHORUS DERIVATIVE; RUTHENIUM CHLORIDE; RUTHENIUM DERIVATIVE; RUTHENIUM DIHYDRIDE; UNCLASSIFIED DRUG;

EID: 0033590716     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a809236b     Document Type: Article
Times cited : (190)

References (43)
  • 7
    • 33845378909 scopus 로고
    • For reviews on hydrogen transfer reactions see: R. A. W. Johnstone, A. H. Wilby and I. D. Entwistle, Chem. Rev., 1985, 85, 129; P. A. Chaloner, M. A. Esterulas, F. Joo and L. A. Oro, Homogeneous Hydrogenation, Kluwer Academic Publishers, Dordrecht, The Netherlands, 1994, pp. 87-118; G. Zassinovich, G. Mestroni and S. Gladiali, Chem. Rev., 1992, 92, 1051; J. E. Bäckvall, R. L. Chowdhury, U. Karlsson and G.-Z. Wang, in Perspective in Coordination Chemistry, ed. A. F. Williams, C. Floriani and A. E. Merbach, Verlag Helvetica Chimica Acta, Basel, 1992, pp. 463-486.
    • (1985) Chem. Rev. , vol.85 , pp. 129
    • Johnstone, R.A.W.1    Wilby, A.H.2    Entwistle, I.D.3
  • 8
    • 0004189009 scopus 로고
    • Kluwer Academic Publishers, Dordrecht, The Netherlands
    • For reviews on hydrogen transfer reactions see: R. A. W. Johnstone, A. H. Wilby and I. D. Entwistle, Chem. Rev., 1985, 85, 129; P. A. Chaloner, M. A. Esterulas, F. Joo and L. A. Oro, Homogeneous Hydrogenation, Kluwer Academic Publishers, Dordrecht, The Netherlands, 1994, pp. 87-118; G. Zassinovich, G. Mestroni and S. Gladiali, Chem. Rev., 1992, 92, 1051; J. E. Bäckvall, R. L. Chowdhury, U. Karlsson and G.-Z. Wang, in Perspective in Coordination Chemistry, ed. A. F. Williams, C. Floriani and A. E. Merbach, Verlag Helvetica Chimica Acta, Basel, 1992, pp. 463-486.
    • (1994) Homogeneous Hydrogenation , pp. 87-118
    • Chaloner, P.A.1    Esterulas, M.A.2    Joo, F.3    Oro, L.A.4
  • 9
    • 4243378570 scopus 로고
    • For reviews on hydrogen transfer reactions see: R. A. W. Johnstone, A. H. Wilby and I. D. Entwistle, Chem. Rev., 1985, 85, 129; P. A. Chaloner, M. A. Esterulas, F. Joo and L. A. Oro, Homogeneous Hydrogenation, Kluwer Academic Publishers, Dordrecht, The Netherlands, 1994, pp. 87-118; G. Zassinovich, G. Mestroni and S. Gladiali, Chem. Rev., 1992, 92, 1051; J. E. Bäckvall, R. L. Chowdhury, U. Karlsson and G.-Z. Wang, in Perspective in Coordination Chemistry, ed. A. F. Williams, C. Floriani and A. E. Merbach, Verlag Helvetica Chimica Acta, Basel, 1992, pp. 463-486.
    • (1992) Chem. Rev. , vol.92 , pp. 1051
    • Zassinovich, G.1    Mestroni, G.2    Gladiali, S.3
  • 10
    • 0001951279 scopus 로고
    • ed. A. F. Williams, C. Floriani and A. E. Merbach, Verlag Helvetica Chimica Acta, Basel
    • For reviews on hydrogen transfer reactions see: R. A. W. Johnstone, A. H. Wilby and I. D. Entwistle, Chem. Rev., 1985, 85, 129; P. A. Chaloner, M. A. Esterulas, F. Joo and L. A. Oro, Homogeneous Hydrogenation, Kluwer Academic Publishers, Dordrecht, The Netherlands, 1994, pp. 87-118; G. Zassinovich, G. Mestroni and S. Gladiali, Chem. Rev., 1992, 92, 1051; J. E. Bäckvall, R. L. Chowdhury, U. Karlsson and G.-Z. Wang, in Perspective in Coordination Chemistry, ed. A. F. Williams, C. Floriani and A. E. Merbach, Verlag Helvetica Chimica Acta, Basel, 1992, pp. 463-486.
    • (1992) Perspective in Coordination Chemistry , pp. 463-486
    • Bäckvall, J.E.1    Chowdhury, R.L.2    Karlsson, U.3    Wang, G.-Z.4
  • 12
    • 0028335511 scopus 로고
    • J. P. Genêt, V. Ratovelomanana-Vidal and C. Pinel, Synlett, 1993, 478; P. Krasik and H. Alper, Tetrahedron, 1994, 50, 4347.
    • (1994) Tetrahedron , vol.50 , pp. 4347
    • Krasik, P.1    Alper, H.2
  • 14
    • 0002123299 scopus 로고    scopus 로고
    • S. Hashiguchi, A. Fujii, J. Takehera, T. Ikariya and R. Noyori, J. Am. Chem. Soc., 1995, 117, 7562; R. Noyori and S. Hashiguchi, Acc. Chem. Res., 1997, 30, 97.
    • (1997) Acc. Chem. Res. , vol.30 , pp. 97
    • Noyori, R.1    Hashiguchi, S.2
  • 25
    • 0344639403 scopus 로고    scopus 로고
    • note
    • 9b discussed the role of base in ruthenium-catalyzed hydrogen transfer and proposed a monohydride amide complex as the reactive intermediate (catalyst) in his system.
  • 26
    • 0000736411 scopus 로고
    • For related β-hydride elimination from iridium alkoxide complexes see: O. Blum and D. Milstein, J. Am. Chem. Soc., 1995, 117, 4582.
    • (1995) J. Am. Chem. Soc. , vol.117 , pp. 4582
    • Blum, O.1    Milstein, D.2
  • 27
    • 0345070002 scopus 로고    scopus 로고
    • note
    • 6 after removal of isopropanol.
  • 32
    • 37049141735 scopus 로고
    • R. O. Harris, N. K. Hota, L. Sadavoy and J. M. C. Yuen, J. Organomet. Chem., 1968, 54, 259; J. J. Levison and S. D. Robinson, J. Chem. Soc. A, 1970, 2947.
    • (1970) J. Chem. Soc. A , pp. 2947
    • Levison, J.J.1    Robinson, S.D.2
  • 34
  • 38
    • 0001081707 scopus 로고    scopus 로고
    • 2(COD)], with base and a secondary alcohol to give dihydride complexes was recently reported: S. P. Nolan, T. R. Belderrain and R. H. Grubbs, Organometallics, 1997, 16, 5569; see also ref. 20b.
    • (1997) Organometallics , vol.16 , pp. 5569
    • Nolan, S.P.1    Belderrain, T.R.2    Grubbs, R.H.3
  • 40
    • 0344639384 scopus 로고    scopus 로고
    • note
    • 2O atoms;
  • 43
    • 0345069977 scopus 로고    scopus 로고
    • note
    • 3b reported results, which suggest that ruthenium dihydride complex 3, is the active catalyst in hydrogen transfer reactions; see also ref. 18.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.