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For reviews on hydrogen transfer reactions see: R. A. W. Johnstone, A. H. Wilby and I. D. Entwistle, Chem. Rev., 1985, 85, 129; P. A. Chaloner, M. A. Esterulas, F. Joo and L. A. Oro, Homogeneous Hydrogenation, Kluwer Academic Publishers, Dordrecht, The Netherlands, 1994, pp. 87-118; G. Zassinovich, G. Mestroni and S. Gladiali, Chem. Rev., 1992, 92, 1051; J. E. Bäckvall, R. L. Chowdhury, U. Karlsson and G.-Z. Wang, in Perspective in Coordination Chemistry, ed. A. F. Williams, C. Floriani and A. E. Merbach, Verlag Helvetica Chimica Acta, Basel, 1992, pp. 463-486.
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0344639403
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note
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9b discussed the role of base in ruthenium-catalyzed hydrogen transfer and proposed a monohydride amide complex as the reactive intermediate (catalyst) in his system.
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0000736411
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For related β-hydride elimination from iridium alkoxide complexes see: O. Blum and D. Milstein, J. Am. Chem. Soc., 1995, 117, 4582.
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0345070002
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note
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6 after removal of isopropanol.
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33845280331
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37049079211
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D. J. Cole-Hamilton and D. Morton, J. Chem. Soc., Chem. Commun., 1988, 1154; D. Morton, D. J. Cole-Hamilton, I. D. Utuk, M. Paneque-Sosa and M. Lopez-Poveda, J. Chem. Soc., Dalton Trans., 1989, 489.
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0001081707
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2(COD)], with base and a secondary alcohol to give dihydride complexes was recently reported: S. P. Nolan, T. R. Belderrain and R. H. Grubbs, Organometallics, 1997, 16, 5569; see also ref. 20b.
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Nolan, S.P.1
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0023993606
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2 (analogous to 2) and isopropanol in the presence of KOH: M. A. Esteruelas, E. Sola, L. A. Oro, H. Werner and U. Meyer, J. Mol. Catal., 1988, 45, 1.
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40
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-
0344639384
-
-
note
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2O atoms;
-
-
-
-
42
-
-
0000001369
-
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For related calculations (Hartree-Fock) on 8 (X = Cl) and 9 (X = Cl) see: H. Itagaki, N. Koga, K. Morokuma and Y. Saito, Organometallics, 1993, 12, 1648.
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Itagaki, H.1
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43
-
-
0345069977
-
-
note
-
3b reported results, which suggest that ruthenium dihydride complex 3, is the active catalyst in hydrogen transfer reactions; see also ref. 18.
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