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Volumn 44, Issue 38, 2005, Pages 6214-6219

Ruthenium(II) trerdentate CNN complexes: Superlative catalysts for the hydrogen-transfer reduction of ketones by reversible insertion of a carbonyl group into the Ru-H bond

Author keywords

Homogeneous catalysis; Hydride; Hydrogenation; Orthometalation; Ruthenium

Indexed keywords

ALCOHOLS; CATALYSIS; HYDRIDES; HYDROGEN BONDS; HYDROGENATION; KETONES; SUBSTRATES;

EID: 25844443346     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200502118     Document Type: Article
Times cited : (216)

References (70)
  • 32
    • 25844503018 scopus 로고    scopus 로고
    • note
    • 2Ru: C 64.77, H 5.44, N 3.68; found: C 64.36, H 5.52, N 3.70.
  • 34
    • 25844524553 scopus 로고    scopus 로고
    • Kα radiation, λ = 1.54178 Å) equipped with KappaCCD detector. CCDC-265691 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
  • 36
    • 25844511085 scopus 로고    scopus 로고
    • note
    • For example, 1.97 g of the pharmaceutical intermediate 4-chlorobenzhydrol (90% yield) was obtained from 4-chlorobenzophenone in 2-propanol (NaOH 2 mol%) after 2 h at reflux and using 1 (0.076 mg from a standard solution) (ketone/ catalyst = 100 000:1).
  • 38
    • 25844520027 scopus 로고    scopus 로고
    • note
    • 2Ru: C 67.85, H 5.83, N 3.86; found: C 66.80, H 5.63, N 3.57.
  • 45
    • 25844446639 scopus 로고    scopus 로고
    • note
    • 2Ru: C 71.43, H 5.77, N 3.09; found: C 70.51, H 5.39, N 2.81.
  • 55
    • 25844432668 scopus 로고    scopus 로고
    • note
    • With acetic acid the formation of the corresponding ruthenium acetate has been established and it will be described elsewhere.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.