Reverse cope elimination of hydroxylamines and alkenes or alkynes: Theoretical investigation of tether length and substituent effects

Journal of the American Chemical Society

Volumn 134, Issue 4, 2012, Pages 2434-2441

  Krenske, Elizabeth H ^a,b   Davison, Edwin C ^c   Forbes, Ian T ^d   Warner, Jacqueline A ^c   Smith, Adrian L ^c   Holmes, Andrew B ^a,c,e   Houk, K N ^f  

^a UNIVERSITY OF MELBOURNE   (Australia)

^b Australian Research Council Centre of Excellence for Free Radical Chemistry and Biotechnology   (Australia)

^c UNIVERSITY OF CAMBRIDGE   (United Kingdom)

^d GLAXOSMITHKLINE   (United Kingdom)

^e CSIRO   (Australia)

^f UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CBS-QB3; CYCLIZATIONS; DENSITY FUNCTIONAL THEORY METHODS; INTRAMOLECULAR ADDITIONS; METHYL GROUP; QUANTUM-MECHANICAL CALCULATION; SUBSTITUENT EFFECT; TETHER LENGTHS; THEORETICAL INVESTIGATIONS; TRANSITION STATE;

ACTIVATION ENERGY; AMINES; CYCLIZATION; DENSITY FUNCTIONAL THEORY; EXPERIMENTS; FUNCTIONAL GROUPS; OLEFINS; QUANTUM THEORY; REACTION KINETICS; TETHERLINES;

ACETYLENE;

ALKENE; ALKYNE; HYDROXYLAMINE;

ARTICLE; CONTROLLED STUDY; CYCLIZATION; ELIMINATION REACTION;

ALKENES; ALKYNES; CYCLIZATION; HYDROXYLAMINES; MOLECULAR STRUCTURE; QUANTUM THEORY;

EID: 84863011885     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja211568k     Document Type: Article

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