A DFT study of the ambiphilic nature of arylpalladium species in intramolecular cyclization reactions

Journal of Organic Chemistry

Volumn 76, Issue 6, 2011, Pages 1592-1598

  Fernández, Israel ^a   Solé, Daniel ^b   Sierra, Miguel A ^a  

^a UNIVERSIDAD COMPLUTENSE DE MADRID   (Spain)

^b UNIVERSITY OF BARCELONA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC COMPOUNDS; ATOMS; CARBONYLATION; COORDINATION REACTIONS; CYCLIZATION; DENSITY FUNCTIONAL THEORY; KETONES; REACTION INTERMEDIATES;

ARYLATION REACTIONS; ARYLATIONS; BARRIER ENERGY; CARBON ATOMS; CARBONYL GROUPS; DFT STUDY; ELECTRON WITHDRAWING GROUP; ELECTRON-WITHDRAWING EFFECTS; ELECTRONIC NATURES; ENOLATES; INTRAMOLECULAR CYCLIZATIONS; METALLACYCLES; NITROGEN ATOM; NUCLEOPHILIC ADDITIONS; NUCLEOPHILICITIES; PD CATALYST; REACTION PATHWAYS; SHORTER CHAINS; STRUCTURE-DEPENDENT REACTIVITY;

ADDITION REACTIONS;

ANILINE; CARBON; CARBON DIOXIDE; CARBONYL DERIVATIVE; HYDROGEN; KETONE DERIVATIVE; METAL; NITROGEN; PALLADAAMINOCYCLOBUTANE; PALLADIUM; UNCLASSIFIED DRUG;

ADDITION REACTION; ARTICLE; ARYLATION; ATOM; CATALYST; CYCLIZATION; DENSITY FUNCTIONAL THEORY; ELECTRON; ENERGY; NUCLEOPHILICITY; REACTION ANALYSIS;

EID: 84962348928     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo1020954     Document Type: Article

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