Lipase-catalysed transesterification of coconut oil with fusel alcohols in a solvent-free system

Food Chemistry

Volumn 134, Issue 1, 2012, Pages 89-94

  Sun, Jingcan ^a   Yu, Bin ^b   Curran, Philip ^b   Liu, Shao Quan ^a  

^a NATIONAL UNIVERSITY OF SINGAPORE   (Singapore)

^b Firmenich Asia Pte Ltd   (Singapore)

Author keywords

Coconut oil; Flavour esters; Fusel alcohols; Lipase; Solvent free system; Transesterification

Indexed keywords

COCONUT OIL; ENZYME LOADING; FUSEL ALCOHOLS; ISOBUTYL; LIPOZYME; LIPOZYME TL IM; MOLAR RATIO; NATURAL MATERIALS; OCTANOATE; OCTANOIC ACIDS; OPERATIONAL STABILITY; REACTION PARAMETERS; REACTION TEMPERATURE; SHAKING SPEED; SOLVENT-FREE SYSTEM; TRANSESTERIFICATION REACTION;

CATALYSIS; ENZYMES; ESTERIFICATION; ESTERS; LIPASES; LOADING; SOLVENTS; VEGETABLE OILS;

TRANSESTERIFICATION;

ALCOHOL; AMYLOCTANOIC ACID; COCONUT OIL; ENZYME; ETHYLOCTANOIC ACID; FLAVORING AGENT; FUSEL ALCOHOL; ISOBUTYLOCTANOIC ACID; LIPOZYME TL IM; OCTANOIC ACID DERIVATIVE; PROPYLOCTANOIC ACID; SOLVENT; TRIACYLGLYCEROL LIPASE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL REACTION; CONTROLLED STUDY; ENZYME ACTIVITY; FLAVOR; NONHUMAN; REACTION TIME; TEMPERATURE; TRANSESTERIFICATION; VELOCITY;

EID: 84862811322     PISSN: 03088146     EISSN: 18737072     Source Type: Journal    
DOI: 10.1016/j.foodchem.2012.02.070     Document Type: Article

References (30)

1. E. Abilleira, H. Schlichtherle-Cerny, M. Virto, M. de Renobales, and L.J.R. Barron Volatile composition and aroma-active compounds of farmhouse Idiazabal cheese made in winter and spring International Dairy Journal 20 8 2010 537 544
2. E.H. Ahmed, T. Raghavendra, and D. Madamwar An alkaline lipase from organic solvent tolerant Acinetobacter sp. EH28: Application for ethyl caprylate synthesis Bioresource Technology 101 2010 3628 3634
3. R.G. Berger, U. Krings, and H. Zorn Biotechnological flavour generation A.J. Taylor, R. Linforth, Food Flavour Technology 1st ed. 2002 Wiley-Blackwell Oxford, UK 60 100
4. D. Bezbradica, D. Mijin, S. Siler-Marinkovic, and Z. Knezevic The effect of substrate polarity on the lipase-catalyzed synthesis of aroma esters in solvent-free systems Journal of Molecular Catalysis B: Enzymatic 45 3-4 2007 97 101
5. B. Cheirsilp, A. H-Kittikun, and S. Limkatanyu Impact of transesterification mechanisms on the kinetic modeling of biodiesel production by immobilized lipase Biochemical Engineering Journal 42 2008 261 269
6. R. Costa Rodrigues, G. Volpato, K. Wada, and M. Záchia Ayub Improved enzyme stability in lipase-catalyzed synthesis of fatty acid ethyl ester from soybean oil Applied Biochemistry and Biotechnology 152 2009 394 404
7. B.K. De, T. Chatterjee, and D.K. Bhattacharyya Synthesis of geranyl and citronellyl esters of coconut oil fatty acids through alcoholysis by Rhizomucor miehei lipase catalysis Journal of the American Oil Chemists Society 76 1999 1501 1504
8. V. Dossat, D. Combes, and A. Marty Continuous enzymatic transesterification of high oleic sunflower oil in a packed bed reactor: Influence of the glycerol production Enzyme and Microbial Technology 25 1999 194 200
9. V. Dossat, D. Combes, and A. Marty Lipase-catalysed transesterification of high oleic sunflower oil Enzyme and Microbial Technology 30 2002 90 94
10. W. Du, Y. Xu, and D. Liu Lipase-catalysed transesterification of soya bean oil for biodiesel production during continuous batch operation Biotechnology and Applied Biochemistry 38 2003 103 106
11. S. Hari Krishna, S. Divakar, S.G. Prapulla, and N.G. Karanth Enzymatic synthesis of isoamyl acetate using immobilized lipase from Rhizomucor miehei Journal of Biotechnology 87 2001 193 201
12. E. Hernandez-Martin, and C. Otero Different enzyme requirements for the synthesis of biodiesel: Novozym®435 and Lipozyme® TL IM Bioresource Technology 99 2008 277 286
13. A. Hinterholzer, and P. Schieberle Identification of the most odour-active volatiles in fresh, hand-extracted juice of Valencia late oranges by odour dilution techniques Flavour and Fragrance Journal 13 1 1998 49 55
14. M. Lubary, J. ter Horst, G. Hofland, and P. Jansens Lipase-catalyzed ethanolysis of milk fat with a focus on short-chain fatty acid selectivity Journal of Agricultural and Food Chemistry 57 2008 116 121
15. N. Nemestóthy, L. Gubicza, E. Fehér, and K. Bélafi-Bakó Biotechnological utilisation of fusel oil, a food industry by-product Food Technology and Biotechnology 46 2008 44 50
16. A. Ott, L.B. Fay, and A. Chaintreau Determination and origin of the aroma impact compounds of yogurt flavor Journal of Agricultural and Food Chemistry 45 3 1997 850 858
17. P. Park, and R. Goins In situ preparation of fatty acid methyl esters for analysis of fatty acid composition in foods Journal of Food Science 59 6 1994 1262 1266
18. Rychlik, M., Schieberle, P., & Grosch, W. (1998). Compilation of odor thresholds, odor qualities and retention indices of key food odorants. Garching, Germany: Deutsche Forschungsanstat für Lebensmittelchemie and Instit für Lebensmittelchemie der Technischen Universität München.
19. P. Sampranpiboon, R. Jiraratananon, D. Uttapap, X. Feng, and R.Y.M. Huang Pervaporation separation of ethyl butyrate and isopropanol with polyether block amide (PEBA) membranes Journal of Membrane Science 173 1 2000 53 59
20. P. Schnermann, and P. Schieberle Evaluation of key odorants in milk chocolate and cocoa mass by aroma extract dilution analyses Journal of Agricultural and Food Chemistry 45 3 1997 867 872
21. S. Shah, and M.N. Gupta Lipase catalyzed preparation of biodiesel from Jatropha oil in a solvent free system Process Biochemistry 42 3 2007 409 414
22. M.M. Soumanou, and U.T. Bornscheuer Improvement in lipase-catalyzed synthesis of fatty acid methyl esters from sunflower oil Enzyme and Microbial Technology 33 2003 97 103
23. J. Sun, B. Yu, P. Curran, and S.-Q. Liu Quantitative analysis of volatiles in transesterified coconut oil by headspace-solid-phase microextraction-gas chromatography-mass spectrometry Food Chemistry 129 4 2011 1882 1888
24. M. Szczesna Antczak, A. Kubiak, T. Antczak, and S. Bielecki Enzymatic biodiesel synthesis-key factors affecting efficiency of the process Renewable Energy 34 2009 1185 1194
25. S.M. van Ruth, B. Villegas, W. Akkermans, M. Rozijn, H. van der Kamp, and A. Koot Prediction of the identity of fats and oils by their fatty acid, triacylglycerol and volatile compositions using PLS-DA Food Chemistry 118 2010 948 955
26. Y. Wang, H. Wu, and M. Zong Improvement of biodiesel production by lipozyme TL IM-catalyzed methanolysis using response surface methodology and acyl migration enhancer Bioresource Technology 99 2008 7232 7237
27. B. Wang, and S. Xu Effects of different commercial lipases on the volatile profile of lipolysed milk fat Flavour and Fragrance Journal 24 6 2009 335 340
28. G. Yadav, and A. Trivedi Kinetic modeling of immobilized-lipase catalyzed transesterification of n-octanol with vinyl acetate in non-aqueous media Enzyme and Microbial Technology 32 2003 783 789
29. A.R.M. Yahya, W.A. Anderson, and M. Moo-Young Ester synthesis in lipase-catalyzed reactions Enzyme and Microbial Technology 23 7-8 1998 438 450
30. G. Zehentbauer, and G. Reineccius Determination of key aroma components of Cheddar cheese using dynamic headspace dilution assay Flavour and Fragrance Journal 17 4 2002 300 305