Efficient preparation of β-branched γ,δ-unsaturated esters through copper-catalyzed allylic alkylation of ketene silyl acetal

Synthesis

Volumn 44, Issue 9, 2012, Pages 1304-1307

  Li, Dong ^a   Ohmiya, Hirohisa ^a   Sawamura, Masaya ^a  

^a HOKKAIDO UNIVERSITY   (Japan)

Author keywords

, unsaturated esters; allylic alkylation; copper; ketene silyl acetal; regioselectivity

Indexed keywords

ALLYLIC ALKYLATION; ALLYLIC PHOSPHATES; ANTI-SELECTIVITY; CHIRALITY TRANSFER; KETENE SILYL ACETAL; PRODUCT YIELDS; UNSATURATED ESTERS;

ALLYLATION; CATALYSIS; ESTERIFICATION; ESTERS; REGIOSELECTIVITY;

COPPER;

ALLYL COMPOUND; COPPER; ESTER; ETHYL 3 METHYL 7 PHENYL 4 HEPTENOATE; ETHYL 3 METHYL 7 TRIISOPROPYLSILYLOXY 4 HEPTENOATE; GAMMA UNSATURATED ESTER; KETENE DERIVATIVE; KETENE SILYL ACETAL; UNCLASSIFIED DRUG;

ALKYLATION; ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CATALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHIRALITY; CLAISEN REARRANGEMENT; ENANTIOMER; ENANTIOSELECTIVITY; GAS CHROMATOGRAPHY; GEOMETRY; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS;

EID: 84862781526     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0031-1289712     Document Type: Article

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