An antiferromagnetic {Mn 8} ring supported by planar multidentate ligands

Science China Chemistry

Volumn 55, Issue 6, 2012, Pages 973-977

  Newton, Graham N ^a   Shiga, Takuya ^a   Oshio, Hiroki ^a  

^a UNIVERSITY OF TSUKUBA   (Japan)

Author keywords

antiferromagnetic ring complex; magnetism; manganese; planar ligands

Indexed keywords

ANTIFERRO-MAGNETIC INTERACTIONS; ANTIFERROMAGNETIC RING; ANTIFERROMAGNETICS; MACROCYCLICS; MANGANESE CHLORIDE; METAL CENTERS; MULTIDENTATE LIGANDS; POLYNUCLEAR COMPLEXES; PYRAZOLES; TYPE STRUCTURES;

ANTIFERROMAGNETIC MATERIALS; ANTIFERROMAGNETISM; CHLORINE COMPOUNDS; MAGNETISM; MANGANESE; MANGANESE COMPOUNDS;

LIGANDS;

EID: 84862550875     PISSN: 16747291     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11426-012-4548-3     Document Type: Conference Paper

References (34)

1. G. Christou D. Gatteschi D.N. Hendrickson R. Sessoli 2000 Single molecule magnets MRS Bull 25 66 71 10.1557/mrs2000.226 1:CAS:528:DC%2BD3cXosl2qurk%3D
2. Gatteschi D, Sessoli R, Villain J. Molecular Nanomagnets. New York: Oxford University Press, 2006, and references therein
3. P. Gütlich A. Hauser H. Spiering 1994 Thermal and optical switching of iron(II) complexes Angew Chem Int Ed 33 2024 2054 10.1002/anie.199420241 (Pubitemid 24987674)
4. O. Kahn C.J. Martinez 1998 Spin-transition polymers: From molecular materials toward memory devices Science 279 44 48 10.1126/science.279.5347.44 1:CAS:528:DyaK1cXjt1OjsQ%3D%3D (Pubitemid 28079148)
5. P. Gütlich Y. Garcia T. Woike 2001 Photoswitchable coordination compounds Coord Chem Rev 219-221 839 879 10.1016/S0010-8545(01)00381-2 (Pubitemid 32936593)
6. T. Sato K. Nishi S. Iijima M. Kojima N. Matsumoto 2009 One-step and two-step spin-crossover iron(II) complexes of ((2-methylimidazol-4-yl) methylidene) histamine Inorg Chem 48 7211 7229 10.1021/ic9006197 1:CAS:528:DC%2BD1MXotFKmsL8%3D
7. O. Sato T. lyoda A. Fujishima K. Hashimoto 1996 Photoinduced magnetization of a cobalt-iron cyanide Science 272 704 705 10.1126/science.272. 5262.704 1:CAS:528:DyaK28Xislamsbc%3D (Pubitemid 126594768)
8. O. Sato Y. Einaga T. Iyoda A. Fujishima K. Hashimoto 1997 Reversible photoinduced magnetization J Electrochem Soc 144 L11 L13 10.1149/1.1837356 1:CAS:528:DyaK2sXhtFemsr8%3D
9. 2} J Am Chem Soc 126 6222 6223 10.1021/ja039451k 1:CAS:528:DC%2BD2cXjsVOhsbw%3D (Pubitemid 38657036)
10. C.P. Berlinguette A. Dragulescu-Andrasi A. Sieber H.U. Güdel C. Achim K.R. Dunbar 2005 A charge-transfer-induced spin transition in a discrete complex: The role of extrinsic factors in stabilizing three electronic isomeric forms of a cyanide-bridged Co/Fe cluster J Am Chem Soc 127 6766 6779 10.1021/ja043162u 1:CAS:528:DC%2BD2MXjtlWktL4%3D (Pubitemid 40664184)
11. M. Shatruk A. Dragulescu-Andrasi K.E. Chambers S.A. Stoian E.L. Bominaar C. Achim K.R. Dunbar 2007 Properties of prussian blue materials manifested in molecular complexes: Observation of cyanide linkage isomerism and spin-crossover behavior in pentanuclear cyanide clusters J Am Chem Soc 129 6104 6116 10.1021/ja066273x 1:CAS:528:DC%2BD2sXksFSnsr0%3D (Pubitemid 46786802)
12. R.E.P. Winpenny 2002 Serendipitous assembly of polynuclear cage compounds J Chem Soc, Dalton Trans 1 1 10 10.1039/b107118c (Pubitemid 35187154)
13. H. Oshio N. Hoshino T. Ito M. Nakano 2004 Single molecule magnets of ferrous cubes: Structurally controlled magnetic anisotropy J Am Chem Soc 126 8805 8812 10.1021/ja0487933 1:CAS:528:DC%2BD2cXlsFKrsr0%3D (Pubitemid 38960802)
14. O. Waldmann 2005 Magnetic molecular wheels and grids-the need for novel concepts in "zero-dimensional" magnetism Coord Coord Chem Rev 249 2550 2566 10.1016/j.ccr.2004.12.019 1:CAS:528:DC%2BD2MXht1Gnt73E (Pubitemid 41643999)
15. M. Ruben J. Rojo F.J. Romero-Salguero L.H. Uppadine J.M. Lehn 2004 Grid-type metal ion architectures: Functional metallosupramolecular arrays Angew Chem Int Ed 43 3644 3662 10.1002/anie.200300636 1:CAS:528:DC%2BD2cXmtVKrt74%3D (Pubitemid 39257513)
16. II [2×2] grid triggered by temperature, pressure, and light Angew Chem Int Ed 39 2504 2507 10.1002/1521-3773(20000717) 39:14<2504::AID-ANIE2504>3.0.CO;2-B 1:CAS:528:DC%2BD3cXltFCqs7k%3D (Pubitemid 30602527)
17. O. Waldmann S. Carretta P. Santini R. Koch A.G.M. Jansen G. Amoretti R. Caciuffo L. Zhao L.K. Thompson 2004 Quantum magneto-oscillations in a supramolecular Mn(II)-[3×3] grid Phys Rev Lett 92 096403 10.1103/PhysRevLett.92.096403 1:STN:280:DC%2BD2c7pvVeqsg%3D%3D
18. L.N. Dawe K.V. Shuvaev L.K. Thompson 2009 Magnetic [n×n] (n = 2-5) grids by directed self-assembly Inorg Chem 48 3323 3341 10.1021/ic801078h 1:CAS:528:DC%2BD1MXktVGlsbc%3D
19. 4]: Quantum tunneling of magnetization under static and pulse magnetic field Chem Eur J 13 8445 8453 10.1002/chem.200700714 1:CAS:528:DC%2BD2sXht1ansLrL (Pubitemid 47610568)
20. T. Shiga T. Matsumoto M. Noguchi T. Onuki N. Hoshino G.N. Newton M. Nakano H. Oshio 2009 Cobalt antiferromagnetic ring and grid single-molecule magnet Chem Asian J 4 1660 1663 10.1002/asia.200900216 1:CAS:528: DC%2BD1MXhtlGis7rN
21. G.N. Newton T. Onuki T. Shiga M. Noguchi T. Matsumoto J.S. Mathieson M. Nihei M. Nakano L. Cronin H. Oshio 2011 Mapping the sequential self-assembly of heterometallic clusters: from helix to grid Angew Chem Int Ed 50 4844 4848 10.1002/anie.201007388 1:CAS:528:DC%2BC3MXlvVekt7s%3D
22. 2] squares Inorg Chem 49 368 370 10.1021/ic902052f 1:CAS:528:DC%2BD1MXhsFGhtLvO
23. 10: A molecular ferric wheel J Am Chem Soc 112 9629 9630 10.1021/ja00182a027 1:CAS:528: DyaK3cXmsVelsLY%3D
24. S. Parsons G.A. Solan R.E.P. Winpenny C. Benelli 1996 Ferric wheels and cages: Decanuclear iron complexes with carboxylato and pyridonato ligands Angew Chem Int Ed 35 1825 1828 10.1002/anie.199618251 (Pubitemid 27082337)
25. H. Amiri A. Lascialfari Y. Furukawa F. Borsa G.A. Timco R.E.P. Winpenny 2010 Comparison of the magnetic properties and the spin dynamics in heterometallic antiferromagnetic molecular rings Phys Rev B 82 144421 10.1103/PhysRevB.82.144421
26. A. Caneschi A. Cornia A.C. Fabretti S. Foner D. Gatteschi R. Grandi L. Schenetti 1996 Synthesis, crystal structure, magnetism, and magnetic anisotropy of cyclic clusters comprising six iron(III) ions and entrapping alkaline ions Chem Eur J 2 1379 1387 10.1002/chem.19960021109 1:CAS:528:DyaK28XntFeltLY%3D (Pubitemid 27027499)
27. O. Waldmann T. Guidi S. Carretta C. Mondelli A.L. Dearden 2003 Elementary excitations in the cyclic molecular nanomagnet Cr8 Phys Rev Lett 91 237202 10.1103/PhysRevLett.91.237202 1:STN:280:DC%2BD3sngtlCjsw%3D%3D
28. O. Waldmann C. Dobe H. Mutka A. Furrer H.U. Gudel 2005 Néel-vector tunneling in antiferromagnetic molecular clusters Phys Rev Lett 95 057202 10.1103/PhysRevLett.95.057202 1:STN:280:DC%2BD2MvisFGqtA%3D%3D (Pubitemid 41506172)
29. Affronte M, Carretta S, Timco GA, Winpenny REP. A ring cycle: studies of heterometallic wheels. Chem Commun, 2007, 1789-1797 (Pubitemid 46699183)
30. C.S. Campos-Fernandez R. Clérac J.M. Koomen D.H. Russell K.R. Dunbar 2001 Fine-tuning the ring-size of metallacyclophanes: A rational approach to molecular pentagons J Am Chem Soc 123 773 774 10.1021/ja002960r 1:CAS:528:DC%2BD3MXht12jtw%3D%3D (Pubitemid 32106033)
31. X.C. Huang J.P. Zhang X.M. Chen 2004 A new route to supramolecular isomers via molecular templating: Nanosized molecular polygons of copper( I) 2-methylimidazolates J Am Chem Soc 126 13218 13219 10.1021/ja045249l 1:CAS:528:DC%2BD2cXnvVaht7Y%3D (Pubitemid 39382737)
32. Eiden F, Shweiger HD. 11H,12H-[1]Benzopyrano[2,3-b]benzopyran-11,12- dione. Synthesis, 1974. 511-513
33. A. Teixidor A. Llobet L. Eschriche J. Casabó 1985 Transition metal complexes with 1,3-bis-(2-hydroxyphenyl)-1,3-propanedione Polyhedron 4 215 219 10.1016/S0277-5387(00)84492-7 1:CAS:528:DyaL2MXitFCit7w%3D
34. A.M.S. Silva L.M.P.M. Almeida J.A.S. Cavaleiro C. Foces-Foces A.L. Llamas-Saiz C. Fontenas N. Jagerovic J. Elguero 1997 Synthesis and molecular structure of new O/N/O ligands: Bis-phenol-pyridine and bis-phenol-pyrazole Tetrahedron 53 11645 11658 10.1016/S0040-4020(97)00733-3 1:CAS:528: DyaK2sXlvVSqsLg%3D (Pubitemid 27351443)