A new route to supramolecular isomers via molecular templating: Nanosized molecular polygons of copper(I) 2-methylimidazolates

Journal of the American Chemical Society

Volumn 126, Issue 41, 2004, Pages 13218-13219

  Huang, Xiao Chun ^a   Zhang, Jie Peng ^a   Chen, Xiao Ming ^a  

^a SUN YAT SEN UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

COPPER 2 METHYLIMIDAZOLATE; COPPER COMPLEX; IMIDAZOLE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; CRYSTALLOGRAPHY; ISOMER; ISOMERISM; STRUCTURE ANALYSIS; SUPRAMOLECULAR CHEMISTRY; SYNTHESIS; THERMODYNAMICS;

EID: 6044263674     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja045249l     Document Type: Article

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21. 20): C 40.55, H 4.25, N 16.89; found: C 40.42, H 4.41, N 16.78. All of 1-3 are basically insoluble in common organic solvent; 1 and 2 are relatively stable compared to 3 that is oxidized in a few minutes upon exposure in air. Preliminary measurements of solids 1-3 showed photoluminescence at room temperature with the emission peaks at 495, 512, and 515 nm, respectively.
22. 2 = 0.0829, and S = 1.061 for all 4340 data.
23. 2 = 0.0978, and S = 1.035 for all 15355 data.
24. 2 = 0.1869, S = 0.994 for all 11807 data.